The Whitesides Research Group

## Publications

## Publications 1962-1969

<table><tr><th>30.</th><th>"The reaction of Copper(I) Hydride with Organocopper(I) Compounds", Whitesides, G. M., San
Filippo, 3., Jr. , Stedronsky, E. R. and Casey, C. P., J. Am. Chem. Soc., 1969,  91,6542.6544.</th></tr><tr><td>29.</td><td>"Pseudorotation in (CH3)2NPF4", Whitesides, G. M. and Mitchell, H. L., J. Am. Chem. Soc., 1969, 
91,  5384-5386. </td></tr><tr><td>28.</td><td>"1H-13C Spin-Spin Coupling in Transition Metal Hydride Complexes', Whitesides, G. M. and
Maglio, G., J. Am. Chem. Soc., 1969,  91,4980.4986.</td></tr><tr><td>27.</td><td>"Reaction of Lithium Dialkyl- and Diarylcuprates with Organic Halides", Whitesides, G. M., Fischer,
W. P., Jr., San Filippo, J., Jr., Bashe, R. W. and House, H. O., J. Am. Chem. Soc., 1969,  91,  4871-
4882. </td></tr><tr><td>26.</td><td>'The Reaction of threo(CH3)3CCHDCHDFe(CO)2-p-05H5 with Triphenylphosphine", Whitesides, G.
M. and Boschetto, D. J., J. Am. Chem. Soc., 1969,  91,4313-4314.</td></tr><tr><td>25.</td><td>"The Cydotrimerization of 2-Butyne-1,1,1-d3 by Transition Metal Catalysts", Whitesides, G. M. and
Ehmann, W. J., J. Am. Chem. Soc., 1969,  91,3800-3807.</td></tr><tr><td>24.</td><td>"Irradiation of cis,cis-1,5-Cyclooctadiene in the Presence of Copper(I) Chloride", Whitesides, G.
M., Goe, G. L. and Cope, A. C., J. Am. Chem. Soc., 1969,91, 2608.2616. </td></tr><tr><td>23.</td><td>'Vanadium Nuclear Spin-Lattice Relaxation in p-Tropyliumvanadium(-I)-Tricarbonyl", Whitesides,
G. M. and Mitchell, H. L., J. Am. Chem. Soc., 1969,91, 2245-2250. </td></tr><tr><td>22.</td><td>"Hindered Rotation in Substituted Paracyclophanes", Whitesides, G. M., Pawson, B. A. and Cope,
A.C., J. Am. Chem. Soc., 1968,  90,639.644.</td></tr><tr><td>21.</td><td>"The Cyclotrimerization of 2-Butyne-1,1,1-d3 by Triphenyltris(tetra-hydrofuran)chromium(III)",
Whitesides, G. M. and Ehmann, W. J., J. Am. Chem. Soc., 1967, .A9, 804-805.</td></tr><tr><td>20.</td><td>"trans, trans-1,5-Cyclooctadiene", Whitesides, G. M., Goe, G. L. and Cope, A. C., J. Am. Chem.
Soc.,  1967,89,7136.7137.</td></tr><tr><td>19.</td><td>"Pseudorotation in o-Isopropylphenylbis(p,p'-bitolyl)phosphorane", Whitesides, G. M. and Bunting,
W. M., J. Am. Chem. Soc., 1967,89,6801-6802.</td></tr><tr><td>18.</td><td>"Oxidative Coupling using Copper(I) Ate Complexes", Whitesides, G. M., San Filippo, 3., Jr., Casey,
C. P. and Panek, E. 3., J. Am. Chem. Soc., 1967,89, 5302-5303. </td></tr><tr><td>17.</td><td>"Cydic Polyolefins. XLV. cis,trans-1,5-Cyclooctadiene", Cope, A. C., Howell, C. F., Bowers, 3., Lord,
R. C. and Whitesides, G. M., J. Am. Chem. Soc., 1967,  89,4024-4027.</td></tr><tr><td>16.</td><td>"A Nuclear Magnetic Resonance Study of s-Cyclopentadienyl(triethylphosphine)copper(I)",
Whitesides, G. M. and Fleming, J. S., J. Am. Chem. Soc., 1967,89,2855-2859.</td></tr><tr><td>15.</td><td>"The Chemistry of Carbanions. XIII. The NMR Spectra of Various Methyl-magnesium Derivatives:
Related Substances", House, H. O., Latham, R. A. and Whitesides, G. M., 2 Org. Chem., 1967,32,
2481-2496. </td></tr></table>

## Publications 1962-1969 (cont.)

<table><tr><th>14.</th><th>"Conformational Isomerism in 1-Substituted Derivatives of 3,3-Dimethylbutane", Whitesides, G.
M., Sevenair, 3. P. and Goetz, R. W., J. Am. Chem. Soc., 1967, 85; 1135-1144.</th></tr><tr><td>13.</td><td>'The Stereochemistry of the Thermal Decomposition of Vinylic Copper(I) and Silver(I)
Organometallic Compounds", Whitesides, G. M. and Casey, C. P., J. Am. Chem. Sec, 1966, 88,
4541-4543. </td></tr><tr><td>12.</td><td>'The Chemistry of Carbanions. XII. The Role of Copper in the Conjugate Addition of
Organometallic Reagents", House, H. 0., Respess, W. L. and Whitesides, G. M., J. Org. Chem.,
1966, 31, 3128.3144.</td></tr><tr><td>11.</td><td>"Nuclear Magnetic Resonance Spectroscopy: The Configurational Stability of Primary Grignard
Reagents. Structure and Medium Effects", Whitesides, G. M. and Roberts, J. D., J. Am. Chem.
Sac., 1965, 87, 4878-4888.</td></tr><tr><td>10.</td><td>"Nuclear Magnetic Resonance Spectroscopy: Temperature Dependence of the Spectrum of
Fluorocyclooctatetraene", Gwynn, D. E., Whitesides, G. M. and Roberts, 3. D., J. Am. Chem. Soc.,
1965, 87, 2862-2864.</td></tr><tr><td>9.</td><td>"Magnetic Resonance Spectroscopy: The Configurational Stability of Primary Grignard Reagents.
3,3-Dimethylbutylmagnesium Chloride", Whitesides, G. M., Witanowski, M. and Roberts, J. D., J.
Am. Chem. Soc, 1965, 87, 2854.2862.</td></tr><tr><td>8. </td><td>"Nuclear Magnetic Resonance Spectroscopy: The Effect of Solvent on Magnetic Nonequivalence
Arising from Molecular Asymmetry", Whitesides, G. M., Grocki, J. J., Holtz, D., Steinberg, H. and
Roberts, 3. D., 1 Am. Chem. Soc, 1965, 87, 1058-1064.</td></tr><tr><td>7.</td><td>"Nuclear Magnetic Resonance Spectroscopy: The Effect of Structure on Magnetic Nonequivalence
Due to Molecular Asymmetry", Whitesides, G. M., Holtz, D. and Roberts, J. D., J. Am. Chem. Sac,
1964, 86, 2628-2634.</td></tr><tr><td>6.</td><td>"Long-Range Proton Spin-Spin Coupling in Dimethyl Sulfone", Whitesides, G. M. and Roberts, J.
D., J. Phys. Chem., 1964, 68,1583.1584.</td></tr><tr><td>5.</td><td>"Relative Signs of the 31P-1H and 31P-C-1H Nuclear Magnetic Resonance Coupling Constants",
Whitesides, G. M., Beauchamp, J. C. and Roberts, J. D., J. Am. Chem. Soc., 1963, 85, 2665-2666.</td></tr><tr><td>4.</td><td>'The Configurational Stability of Primary Grignard Reagents", Whitesides, G. M., Kaplan, F. and
Roberts, J. D., 1 Am. Chem. Soc., 1963, 85, 2167-2168.</td></tr><tr><td>3.</td><td>"Nuclear Magnetic Resonance Spectroscopy. Structure and Dynamic Character of Allylic Grignard
Reagents", Whitesides, G. M., Nordlander, J. E. and Roberts, J. D., Disc. Farad. Soc., 1962, 34,
185-190. </td></tr><tr><td>2.</td><td>"Nuclear Magnetic Resonance Spectroscopy: g,g-Dimethylallylmagnesium Bromide", Whitesides,
G. M., Nordlander, J. E. and Roberts, J. D., J. Am. Chem. Soc., 1962, 84, 2010-2011.</td></tr><tr><td>1.</td><td>"Nuclear Magnetic Resonance Spectroscopy: Abnormal Splitting of Ethyl Groups due to Molecular
Asymmetry, III", Whitesides, G. M., Kaplan, F., Nagarajan, K. and Roberts, J. D., Proc. Nat. Acad.
Sol US4, 1962, 48, 1112-1114.</td></tr></table>

## Publications 1962-1969 (cont.)

The Whitesides Research Group

# Publications

# Publications (cont.)

## Publications 1970-1979

<table><tr><th>108.</th><th>"Conversion of the Adenosine Moieties of RNA to ATP for Use in Cofactor Recycling", Leuchs, H.
)., Lewis, J. M., Rios-Mercadillo, V. M. and Whitesides, G. M., J. Am. Chem. Soc, 1979, 101,
5829-5830. </th></tr><tr><td>107.</td><td>"Large-Scale Enzymatic Synthesis of sn-Glycerol 3-Phosphate", Rios-Mercadillo, V. M. and
Whitesides, G. M., J. Am. Chem. Soc., 1979, 101, 5828.5829.</td></tr><tr><td>106.</td><td>"A Basis for Orbital Symmetry Rules", Metieu, H., Ross, J. and Whitesides, G. M., Angew. Chem.
hit. Ed. Engl., 1979, .18, 377.392.</td></tr><tr><td>105.</td><td>"Preparation and Magnetic Filtration of Polyacrylamide Gel Beads Containing a Ferrofluid and
Covalently Immobilized Proteins", Adalsteinsson, 0., Lamotte, A., Baddour, R. F., Colton, C. K.,
Pollak, A. and Whitesides, G. M., J. Mot. Cat, 1979, 6, 199.225.</td></tr><tr><td>104.</td><td>"Polyacrylamide Gel Entrapment of Adenylate Kinase", Whitesides, G. M., Lamotte, A. L.,
Adalsteinsson, 0., Baddour, R. F., Chmurny, A. C. and Colton, C. K., J. Hot Cat, 1979, 6, 177-
198. </td></tr><tr><td>103.</td><td>"Conversion of CH2=CHR to CH2=CR'R by Reaction with Cp2TiCl2/AIR'3", Barber, J. J., Willis, C.
and Whitesides, G. M., J. Org. Chem., 1979, 44, 3603-3606.</td></tr><tr><td>102.</td><td>"Water-Soluble Complexes of tert-Phosphines and Rhodium(I) as Homogenous Catalysts", Nuzzo,
R. G., Feitler, D. and Whitesides, G. M., J. Am. Chem. Soc., 1979, 101, 3683.3685.</td></tr><tr><td>101.</td><td>"SN2 Displacement and Reductive Coupling of Ketones with Olefins in N,N-Diethylacetamide and
N-Ethylpyrrolidone", Sowinski, A. F. and Whitesides, G. M., J. Org. Chem., 1979, 44, 2369-2376.</td></tr><tr><td>100.</td><td>'Thermal Generation of Bis(triethylphosphine)-3,3-dimethylplatinacyclobutane from Dineopentylbis
(triethylphosphine)platinum(II)", Foley, P. and Whitesides, G. M., J. Org. Chem., 1979, 101, 2732-
2733. </td></tr><tr><td>99.</td><td>"An Improved Synthesis of Diammonium Acetyl Phosphate", Lewis, J. M., Haynie, S. L. and
Whitesides, G. M., J. Org. Chem., 1979, 44, 864.865.</td></tr><tr><td>98.</td><td>"Hydrogenation of Oriented Monolayers of w-Unsaturated Fatty Adds Supported on Platinum",
Richard, M. A., Deutch, J. and Whitesides, G. M., J. Am. Chem. Soc, 1978, 1046613-6625.</td></tr><tr><td>97.</td><td>"Oxidative Addition and Reductive Elimination Reactions Involving Platinum Metallocycles", Young,
G. B. and Whitesides, G. M., J. Am. Chem. Soc, 1978, 100, 5808-5815.</td></tr><tr><td>96.</td><td>"Generalized Affinity Chromatography: Enzyme-Sulfonamide Conjugates Can Be Isolated by
Adsorption on Immobilized Carbonic Anhydrase", Horowitz, R. and Whitesides, G. M., J. Am.
diem. Soc., 1978, 100,4632.4633.</td></tr><tr><td>95.</td><td>"Bis(2-diphenylphosphinoethyDamine: A Flexible Synthesis of Functionalized Chelating
Diphosphines", Wilson, M. E., Nuzzo, R. G. and Whitesides, G. M., J. Am. Chem. Sac, 1978, 100,
2269.2270. </td></tr><tr><td>94. </td><td>"Conversion of a Protein to a Homogeneous Asymmetric Hydrogenation Catalyst by Site-Specith
Modification with a Diphosphinerhodium(I) Moiety", Wilson, M. E. and Whitesides, G. M., J. AM</td></tr></table>

# Publications (cont.)

## Publications 1970-1979 (cont.)

Chem. Soc., 1978, 100, 306-307.

<table><tr><th>93.</th><th>"Large-Scale Enzyme-Catalyzed Synthesis of ATP from Adenosine and Acetyl Phosphate:
Regeneration of ATP from AMP", Baughn, R. L., Adalsteinsson, 0. and Whitesides, G. M., J. Am.
Chem. Soc., 1978,100, 304-306. </th></tr><tr><td>92.</td><td>"Immobilization of Synthetically Useful Enzymes by Condensation Polymerization", Pollak, A.,
Baughn, R. L., Adalsteinsson, 0. and Whitesides, G. M., J. Am. Chem. Soc., 1978,  100,  302-304. </td></tr><tr><td>91.</td><td>"Large-Scale ATP-Requiring Enzymatic Phosphorylation of Creatine Can Be Driven by Enzymatic
ATP Regeneration", Shih, Y.-S. and Whitesides, G. M., J. Org. Chem., 1977,  42,  4165-4166. </td></tr><tr><td>90.</td><td>'The Stereochemistry of the Peters Reaction (RSO2HgX6RHgX)", Costa, L. C. and Whitesides, G.
M., J. Organometal. Chem., 1977,139,151-163.</td></tr><tr><td>89.</td><td>-The Location and Mobility of Functional Groups at the Surface of Oxidized, Low-Density
Polyethylene Film", Rasmussen, J. R., Bergbreiter, D. E. and Whitesides, G. M., J. Am. Chem.
Soc.,1977, 99,4746-4756.</td></tr><tr><td>88.</td><td>Low-Density "Introduction, Modification, and Characterization of Functional Groups on the Surface of
Polyethylene Film", Rasmussen, J. R., Stedronsky, D. R. and Whitesides, G., M., 1 Am.
Chem. Soc., 1977,  99,4736-4745.</td></tr><tr><td>87.</td><td>"Vinylic Radicals are Intermediates in the Oxidation of Vinylic Lithium Reagents to Lithium
Enolates by Dioxygen, but not by Lithium tert-Butyl peroxide", Panek, E. 3., Kaiser, L. R. and
Whitesides, G. M., J. Am. Chem. Soc., 1977, 99, 3708-3713.</td></tr><tr><td>86.</td><td>"Propane-1,3-di(magnesium halide)", Costa, L. C. and Whitesides, G. M., .1. Am. Chem. Soc.,
1977,99, 2390.2391. </td></tr><tr><td>85.</td><td>"Large-Scale Enzymatic Synthesis with Cofactor Regeneration: Glucose-6-Phosphate", Pollak, A.,
Baughn, R. L. and Whitesides, G. M., J. Am. Chem. Soc., 1977,  99,  2366-2367. </td></tr><tr><td>84.</td><td>"Rates of Thiol-Disulfide Interchange Reactions between Mono- and Dithiols and Ellman's
Reagent", Whitesides, G. M., Ulbum, J. E. and Szajewski, R. P., J. Org. Chem., 1977,  42,332-338.</td></tr><tr><td>83.</td><td>"Covalent Immobilization of Adenylate Kinase and Acetate Kinase in Polyacrylamide Gels: Enzymes
for ATP Regeneration", Whitesides, G. M., Lamotte, A., Adalsteinsson, 0. and Colton, C. L., in
Methods in Enzymology, K. Mosbach, Ed., Academic Press, New York, 1976,44: 887-897.</td></tr><tr><td>82.</td><td>"Affinity Chromatography", Whitesides, G. M. and Nishikawa, A. H., in Applications of Biochemical
Systems in Organic Chemistry, Part 2, J. B. Jones, D. Perlman and C. J. Sih, Eds., John Wiley &amp;
Sons,  New York, 1976,929-968.</td></tr><tr><td>81.</td><td>"Large-Scale Organic Synthesis Using Cell-Free Enzymes", Whitesides, G. M., in Applications of
Biochemical Systems in Organic Chemistry, Part 2, J. B. Jones, D. Perlman and C. J. Sih, Eds.,
John Wiley &amp; Sons, New York, 1976,901-927.</td></tr><tr><td>80.</td><td>"Synthesis and Reactions of Dicyclopentadienyltitanium(N) Metallocycles", McDermott, J. X.,
Wilson, M. E. and Whitesides, G. M., J. Am. Chem. Soc., 1976,  98,6529-6536.</td></tr><tr><td>79.</td><td>"Thermal Decomposition of Bis(phosphine)platinum(II) Metallocycles", McDermott, J. X., White, J.
F. and Whitesides, G. M., 1. Am. Chem. Soc., 1976,98,6521.6528.</td></tr><tr><td>78.</td><td>"High-Gradient Magnetic Filtration of Small Particles of Ferro-, Ferri-, and Paramagnetic Catalysts
and Catalyst Supports", Hill, C. L., Lamotte, A., Althoff, W., Brunie, 3. C. and Whitesides, G. M., J. 
Cat.,  1976,  43,  53-60. </td></tr><tr><td>77.</td><td>"Convenient Preparations of a 1,2,3,4,5-Pentamethylcyclopentadiene and 1-Ethyl-2,3,4,5-
Tetramethylcydopentadiene", Feitler, D. and Whitesides, G. M., Inorg. Chem., 1976,  IS,446-449.</td></tr><tr><td>76. </td><td>"Organic Synthesis Using Enzymes in Two-Phase Aqueous Polymer Systems", Pollak, A. and</td></tr></table>

# Publications (cont.)

## Publications 1970-1979 (cont.)

Whitesides, G. M., J. Am. Chem. Soc., 1976, 98, 289-291.

<table><tr><th></th><th></th></tr><tr><td>75.</td><td>"Reaction of a,w-diGrignard Reagents with Silver(I) Salts Forms Carbocyclic Rings", Whitesides, G.
M. and Gutowski, F. 0., J. Org. Chem., 1976, 41, 2882-2885.</td></tr><tr><td>74.</td><td>"Magnetic Filtration of Small Heterogenous Catalyst Particles: Preparation of Ferrimagnetic
Catalyst Supports", Whitesides, G. M., Hill, C. L and Brunie, 3. C. I. E., Peuoess Res. bevel, 1976,
15, 226.227.</td></tr><tr><td>73.</td><td>"Olefins by Reaction of Lithium Dipropenylcuprates with Alkyl Halides: trans-2-Undecene",
Linstrumelle, G., Krieger, J. K. and Whitesides, G. M., Org. Syn., 1976, 55, 103-106.</td></tr><tr><td>72.</td><td>'The Oxidation of Terminal Olefins to Methyl Ketones by Jones' Reagent is Catalyzed by Mercury
(II)", Rogers, H. R., McDermott). X. and Whitesides, G. M., 1 Org. Chem., 1975, 40, 3577-3580.</td></tr><tr><td>71.</td><td>"The Reaction of n-Butyllithium and 2,2,6,6-Tetramethylpiperdine Nitroxyl", Whitesides, G. M. and
Newirth, T. L., J. Org. Chem., 1975, 40, 3448-3450.</td></tr><tr><td>70.</td><td>"A Dynamic NMR Study of Fluorine Exchange in Liquid SF4", Klemperer, W. G., Krieger, J. K.,
McCreary, M. D., Muetterties, E. L., Traficante, D. D. and Whitesides, G. M., J. Am. Chem. Soc.,
1975, 97, 7023.7030.</td></tr><tr><td>69.</td><td>"Large-Scale Synthesis of Diammonium Acetyl Phosphate", Whitesides, G. M., Siegel, M. and
Garrett, P., .1 Org. Chem., 1975, 40, 2516-2519.</td></tr><tr><td>68.</td><td>"Mechanisms of Thermal Decomposition of Transition Metal Organometallic Compounds",
Whitesides, G. M., in Organotransition-Metal Chemistry, Y. Ishii and M. Tsutsui, Eds., Plenum
Press, New York, 1975, 223-227.</td></tr><tr><td>67.</td><td>"The Synthesis of Fatty Acids Using Organocopper(I) Ate Complexes Derived from Grignard
Reagents", Bergbreiter, D. E. and Whitesides, G. M., J. Org. Chem., 1975, 40, 779-782.</td></tr><tr><td>66.</td><td>"Generation and Utilization of Copper(I) Ate Complexes from Diastereomeric and Enantiomeric
Alkylmercury Reagents", Bergbreiter, D. E. and Whitesides, G. M., J. Am. aem. Soc., 1974, 96,
4937-4944. </td></tr><tr><td>65.</td><td>"Pseudorotation in Arylbis(4,4'-dimethyl-2,2'-biphenylylene)phosphoranes", Whitesides, G. M.,
Eisenhut, M. and Bunting, W. M., 1 Am. Chem. Soc., 1974, 96, 5398-5407.</td></tr><tr><td>64.</td><td>"Pseudorotation in XPF4", Eisenhut, M., Mitchell, H. L., Traficante, D. D., Kaufman, R. J., Deutch,
J. M. and Whitesides, G. M., J, Am. Chem. Soc., 1974, 96, 5385.5397.</td></tr><tr><td>63.</td><td>"Copper(I) Alkoxides: Synthesis, Reactions, and Thermal Decomposition", Whitesides, G. M.,
Sadowski, J. S. and Lilbum, J., J. Am. Chem. Soc., 1974, 96, 2829-2835.</td></tr><tr><td>62.</td><td>"Preparation and Reactions of a Titanium(IV) Metallocycle Formation of Cyclopentanone from
Ethylene and Carbon Monoxide", McDermott, J. X. and Whitesides, G. M., J. Am. Chem Soc.,
1974, 96, 947-948.</td></tr><tr><td>61.</td><td>"Enzymatic Regeneration of ATP from AMP and ADP. Part II: Enzyme Immobilization and Reactor
Development", Whitesides, G. M., Chmurny, A., Garrett, P., Lamotte, A. and Cotton, C. K., in
Enzyme Engineering, K. E. Pye and L. B. Wingard, Eds., Plenum Press, New York, 1974, 217-222.</td></tr><tr><td>60.</td><td>"Enzymatic Regeneration of ATP from AMP and ADP. Part I: Thermodynamics, Kinetics, and
Process Development", Gardner, C. R., Colton, C. K., Langer, R. S., Hamilton, B. K., Archer, M. C.
and Whitesides, G. M., in Enzyme Engineering, K. E. Pye and L. B. Wingard, Eds., Plenum Press,
New York, 1974, 209.216.</td></tr><tr><td>59.</td><td>"Kinetics of Formation of Alkyl Grignard Reagents: Evidence for Rate-Determining Electron
Transfer", Rogers, R. J., Mitchell, H. L. and Whitesides, G. M., 1 Org. Chem., 1974, 39, 857-858.</td></tr><tr><td>58. </td><td>"The Stereoselective Synthesis of 1-Substituted Organometallic Derivatives of 3,3.Dimethylbutane-</td></tr></table>

# Publications (cont.)

## Publications 1970-1979 (cont.)

1,2-d2", Bock, P. L. and Whitesides, G. M., J. Am. Chem. Soc., 1974, 96, 2826-2829.

<table><tr><th>57.</th><th>"The Stereochemistry of Reactions at Carbon-Transition Metal s-Bonds. (CH3)3CCHDCHDFe(CO)
2C5H5", Bock, P. L., Boschetto, D. J., Rasmussen, J. R., Demers, J. P. and Whitesides, G. M., J.
Am. Chem. Soc., 1974, 96, 2814-2825.</th></tr><tr><td>56.</td><td>'The Preparation and Thermal Decomposition of n-Alkyl(tri-n-butyl-phosphine)silver(1) Reagents",
Whitesides, G. M., Bergbreiter, D. and Kendall, P. E., J. Am. Chem. Soc., 1974, 96, 2806-2813.</td></tr><tr><td>55.</td><td>'The Determination of Enantiomeric Purity Using Chiral Lanthanide Shift Reagents", McCreary, M.
D., Lewis, D. W., Wernidc D. L. and Whitesides, G. M., J. Am. Chem. Soc., 1974, 96, 1038-1054.</td></tr><tr><td>54.</td><td>"Reactions of Alkylmercuric Halides with Sodium Borohydride in the Presence of Molecular
Oxygen", Hill, C. L. and Whitesides, G. M., J. Am. Chem. Soc., 1974, 96, 870-876.</td></tr><tr><td>53.</td><td>"Selectivity in Organic Group Transfer in Reactions and Mixed Lithium Diorganocuprates",
Mandeville, W. H. and Whitesides, G. M., J. Org. Chem., 1974, 39, 4O0-405.</td></tr><tr><td>52.</td><td>"The Mechanism of Reaction of Carbon Monoxide with Phenyllithium", Trzupek, L. S., Newirth, T.
L, Kelly, E. G., Sbarbati, N. E. and Whitesides, G. M., J. Am. Chem. Soc., 1973, 95, 8118-8133.</td></tr><tr><td>51.</td><td>"Inversion of Configuration in the Bromination of Vinylic Mercurials", Casey, C. P., Whitesides, G.
M. and Kurth, J., 1 Org. Chem., 1973, 38, 3406-3410.</td></tr><tr><td>50.</td><td>"The Preparation and Thermal Decomposition of Platinum(II) Metallocycles", McDermott, 3. X.,
White, 3. F. and Whitesides, G. M., J. Am. Chem. Soc., 1973, 95, 4451-4452.</td></tr><tr><td>49.</td><td>"Reactions of Transition Metal Peroxides with n-Butyllithium", Regen, S. L. and Whitesides, G. M.,
J. Organornetal Chem., 1973, 59, 293.297.</td></tr><tr><td>48.</td><td>'The Mechanism of Interchange of the Syn and Anti protons of Tetra(trihaptoallyl)zirconium(N)",
Krieger, 3. K., Deutch, J. M. and Whitesides, G. M., Inorg. Chem., 1973, 12, 1535-1545.</td></tr><tr><td>47.</td><td>"ESR Study of the Radical Ions of 1,2,3,4-Tetramethylnapthalene", Gerson, F., Peake, B. M. and
Whitesides, G. M., Org. Mag. Res., 1972, 4, 361-363.</td></tr><tr><td>46.</td><td>"Free Radical Intermediates in the Reaction of Neophyllithium with Oxygen", Panek, E. J. and
Whitesides, G. M., J. Am. Chem. Soc., 1972, 94, 8768-8675.</td></tr><tr><td>45.</td><td>'The Stereochemistry of the Conjugate Addition of Derivatives of endo-2-Norbornylcopper(I) to
Mesityl Oxide", Whitesides, G. M. and Kendall, P. E., J. Org. Chem., 1972, 37, 3718-3725.</td></tr><tr><td>44.</td><td>"Preparation of Deuterated Organic Compounds from Activated Organic Halides by Reduction with
Zinc", Trzupek, L. S., Stedronsky, E. R. and Whitesides, G. M., J. Org. Chem., 1972, 3Z 3300-
3303. </td></tr><tr><td>43.</td><td>"Nitrogen and Boron Spin-Lattice Relaxation in Borazole", Whitesides, G. M., Regen, S. L., Lisle, J.
B. and Mays, R., J. Phys. Chem., 1972, 76, 2871-2877.</td></tr><tr><td>42.</td><td>"Mechanism of Thermal Decomposition of Di-n-butylbis(triphenyl-phosphine)platinum(II)",
Whitesides, G. M., Gaasch, 3. F. and Stedronsky, E. R., J. Am. Chem. Soc., 1972, 94, 5258.5270.</td></tr><tr><td>41.</td><td>"The Catalytic Oxidation of Vicinal Diols to a-Diketones", Regen, S. L. and Whitesides, G. M., J.
Org. Chem., 1972, 37, 1832-1833.</td></tr><tr><td>40.</td><td>"Radical Intermediates in the Thermal Decomposition of Neophyl(tri-n-butylphosphine)silver(I)",
Whitesides, G. M., Panek, E. 3. and Stedronsky, E. R., J. Am. Chem. Soc., 1972, 94, 232.240.</td></tr><tr><td>39.</td><td>'The Determination of Enantiomeric Purity Using Chiral Lanthanide Shift Reagents", Whitesides, G.
M. and Lewis, D. W., J. Am. Chem. Soc., 1971, 93, 5914-5916.</td></tr><tr><td>38. </td><td>"Analysis of the 1H NMR Spectrum of Di-n-butyl-2,2-d2 bis(triphenylphos-phine)platinum(II)",</td></tr></table>

# Publications (cont.)

## Publications 1970-1979 (cont.)

Whitesides, G. M. and Gaasch, J. F., J. Organometal.Chem., 1971, 33, 241-246.

37. "The Stereochemistry of Reactions Occurring at Iron-carbon s-Bonds", Whitesides, G. M. and Boschetto, D. 3., J. Am. Chem. Soc., 1971, 93, 1529-1531.

36. 'The Thermal Decomposition of Vinylic Copper(I) and Silver(I) Organometallic Compounds", Whitesides, G. M., Casey, C. P. and Krieger, 3. K., J. Am. Chem. Soc., 1971, 93, 1379-1389.

35. 'Trisp-(t-butylhydroxymethylene)-d-camphoratoleuropium(111): a Reagent for Determining Enantiomeric Purity", Whitesides, G. M. and Lewis, D. W., J. Am. Chem. Sx., 1970, 92, 6979- 6980.

34. "The Mechanism of Reduction of Alkylmercuric Halides by Metal Hydrides", Whitesides, G. M. and San Filippo, J., Jr., J. Am. Chem. Soc., 1970, 92, 6611-6624.

33. 'The Mechanism of Formation of 1,2,3,4-Tetramethylnapthalene from 2-Butyne and Triphenyltris (tetrahydrofuran)chromium(III)", Whitesides, G. M. and Ehmann, W. J., J. Am. Chem. Soc., 1970, 92, 5625-5640.

32. "(pbd)p Bonding in Phenyltrichloro-tin, -germane, and -silane", Whitesides, G. M., Selgestad, J. G., Thomas, S. P., Andrews, D. W., Morrison, B. A., Panek, E. J. and San Filippo, 3., Jr., J. Organometal. Chem., 1970, 22, 365-374.

31. "The Mechanism of Thermal Decomposition of n-Butyl(tri-n-butylphosphine)copper(I)", Whitesides, G. M., Stedronsky, E. R., Casey, C. P. and San Filippo, 3., Jr., J. Am. Chem. Soc., 1970, 91, 1426-1427.

# Publications (cont.)

## Publications 1970-1979 (cont.)

The Whitesides Research Group

# Publications

# Publications (cont.)

## Publications 1980-1989

<table><tr><th>273.</th><th>"Preparation of Cytidine 5'-Monophospho-N-Acetylneuraminic Acid (CMP-NeuAc) and Uridine 5'-
Diphosphoglucuronic Acid (UDP-GlcUA); Syntheses of a-2,6-Sialyllactosamine, a-2,6-Sialyllactose,
and Hyaluronic Add", Simon, E. S., Toone, E. J., Ostroff, G., Bednarski, M. D. and Whitesides, G.
M., in Methods Enzymol.: Complex Carbohydrates, Part F, V. Ginsburg, Ed., 1989, 179,275.287.</th></tr><tr><td>272.</td><td>"The Synthesis of Aldose Sugars from Half-protected Dialdehydes Using Rabbit Muscle Aldolase",
Borysenko, C. W., Spaltenstein, A., Straub, J. A. and Whitesides, G. M., J. Am. aem. Soc., 1989,
III, 9275.9276.</td></tr><tr><td>271.</td><td>"Hemagglutinins from Two Influenza Virus Variants Bind to Sialic Acid Derivatives with Millimolar
Dissociation Constants: A 500 MHz Proton Nuclear Magnetic Resonance Study", Sauter, N. K.,
Bednarski, M. D., Wurzburg, B. A., Hanson, J. E., Whitesides, G. M., Skehel, J. 3. and Wiley, D. C.,
Biochemistry, 1989, 28, 8388-8396.</td></tr><tr><td>270.</td><td>"Lactate Dehydrogenase-Catalyzed Regeneration of NAD from NADH for Use in Enzyme-Catalyzed
Synthesis", Chenault, H. K. and Whitesides, G. M., Elloorg. Chem., 1989, 17, 400-409.</td></tr><tr><td>269.</td><td>"Preparation of Phosphoenolpyruvate from D-(-)-3-Phosphoglyceric Acid for Use in Regeneration
of ATP", Simon, E. S., Grabowski, S. and Whitesides, G. M., 1 Am. Chem. Soc., 1989, ill, 8920-
8921. </td></tr><tr><td>268.</td><td>"Enzyme-Catalyzed Synthesis of Carbohydrates", Toone, E. J., Simon, E. S., Bednarski, M. D. and
Whitesides, G. M., Tet. Rep., 1989, 45, 5365-5422.</td></tr><tr><td>267.</td><td>"The Physical-Organic Chemistry of Surfaces, and Its Relevance to Molecular Recognition",
Whitesides, G. M. and Biebuyck, H., in Molecular Recognition: Chemical and Biochemical
Problems, S. M. Roberts, Ed., Royal Society of Chemistry, Cambridge, 1989, 78, 270.285.</td></tr><tr><td>266.</td><td>"A New, General Method for the Determination of Binding Constants: Photoacoustic Titration of
Dansylamide with Carbonic Anhydrase", Jain, A., Marzluff, E. M., Jacobsen, 3. R., Whitesides, G.
M. and Grabowski, 2 1, J. Chem. Soc. Chem. Comm., 1989,1557-1559.</td></tr><tr><td>265.</td><td>"Orthogonal Systems for Self-Assembled Monolayers: Alkanethiols on Gold and Alkane Carboxylic
Acids on Alumina", Laibinis, P. E., Hickman, 3. 3., Wrighton, M. S. and Whitesides, G. M., Science,
1989, 245, 845-847.</td></tr><tr><td>264.</td><td>"Combining Spontaneous Molecular Assembly with Microfabrication to Pattern Surfaces: Selective
Binding of Isonitrile to Platinum Microwires and Characterization by Electrochemistry and Surface
Spectroscopy", Hickman, 3. 3., Zou, C., Ofer, D., Harvey, P., Wrighton, M. S., Laibinis, P. E., Bain,
C. D. and Whitesides, G. M., J. Am. Chem. Soc., 1989, 111, 7271-7272.</td></tr><tr><td>263.</td><td>"Synthesis without Cells", Simon, E. S., Akiyama, A. and Whitesides, G. M., in A Revolution in
Biotechnology, J. L. Marx, Ed., ICSUPress, Cambridge, 1989, 15-27.</td></tr><tr><td>262.</td><td>"Modelling Organic Surfaces with Self-Assembled Monolayers", Bain, C. D. and Whitesides, G. M.,
Angew. Chem. Int. Ed. Engl., 1989, 28, 506-516.</td></tr><tr><td>261.</td><td>'The Mechanism of Formation of Grignard Reagents: Trapping of Free Alkyl Radical Intermediates
by Reaction with Tetramethylpiperidine-N-oxyl", Root, K. S., Hill, C. L., Lawrence, L. M. and
Whitesides, G. M., J. Am. Chem. Soc., 1989, 111, 5405-5412.</td></tr></table>

# Publications (cont.)

## Publications 1980-1989 (cont.)

<table><tr><th>260.</th><th>w-Mercaptocarboxylic "A Study by Contact Angle of the Acid-Base Behavior of Monolayers Containing
Acids Adsorbed on Gold: An Example of Reactive Spreading", Bain, C. D. and
Whitesides, G. M., Langmuir, 1989, 5, 1370-1378.</th></tr><tr><td>259.</td><td>"Formation of Monolayers by the Coadsorption of Thiols on Gold: Variation in the Length of the
Alkyl Chain", Bain, C. D. and Whitesides, G. M., J. Am. Chem. Soc., 1989, .111, 7164-7175.</td></tr><tr><td>258.</td><td>"Formation of Monolayers by the Coadsorption of Thiols on Gold: Variation in the Head Group, Tail
Group, and Solvent", Bain, C. D., Evall, J. and Whitesides, G. M., J. Am. Chem. Soc., 1989, 111,
7155-7164. </td></tr><tr><td>257.</td><td>"Kinetic Resolution of Unnatural and Rarely Occurring Amino Acids: Enantioselective Hydrolysis of
N-Acyl Amino Acids Catalyzed by Acylase N, Chenault, H. K., Dahmer, J. and Whitesides, G. M., J.
Am. Chem. Soc., 1989, 111, 6354.6364.</td></tr><tr><td>256.</td><td>"D-Lactate Dehydrogenase: Substrate Specificity and Use as a Catalyst in the Synthesis of
Homochiral 2-Hydroxy Acids", Simon, E. S., Plante, R. and Whitesides, G. M., App/. Biochem.
Biotech., 1989, 22, 169-179.</td></tr><tr><td>255.</td><td>"Structure and Reactivity of Alkylsiloxane Monolayers Formed by Reaction of Alkyltrichlorosilanes
on Silicon Substrates", Wasserman, S. R., Tao, Y.-T. and Whitesides, G. M., Langmuir, 1989, 5,
1074-1087. </td></tr><tr><td>254.</td><td>"Monolayers of 11-Trichlorosilylundecyl Thioacetate: A System that Promotes Adhesion between
Silicon Dioxide and Evaporated Gold", Wasserman, S. R., Biebuyck, H. and Whitesides, G. M., 1.
Mater. Res, 1989, 4, 886-891.</td></tr><tr><td>253.</td><td>"The Structure of Self-Assembled Monolayers of Alkylsiloxanes on Silicon: A Comparison of Results
from Ellipsometry and Low-Angle X-Ray Reflectivity", Wasserman, S. R., Whitesides, G. M.,
Tidswell, I. M., Ocko, B. M., Pershan, P. S. and Axe, J. 0., J. Am. Chem. Soc., 1989, 111, 5852-
5861. </td></tr><tr><td>252.</td><td>"Comparison of Self-Assembled Monolayers on Gold: Coadsorption of Thiols and Disulfides", Bain,
C. D., Biebuyck, H. A. and Whitesides, G. M., Langmuir, 1989, 5, 723-727.</td></tr><tr><td>251.</td><td>"Attenuation Lengths of Photoelectrons in Hydrocarbon Films", Bain, C. D. and Whitesides, G. M.,
1 Phys. Chem., 1989, 93, 1670-1673.</td></tr><tr><td>250.</td><td>"Characterization and Stability of Cyclic Disulfides and Cyclic Dimeric Bis(disulfides)", Houk, 3. and
Whitesides, G. M., Tetrahedron, 1989, 45, 91-102.</td></tr><tr><td>249.</td><td>"Rabbit Muscle Aldolase (RAMA) as a Catalyst in Organic Synthesis", Bednarski, M. D., Simon, E.
S., Bischofberger, N., Fessner, W.-D., Kim, M.-3., Lees, W., Saito, T., Waldmann, H. and
Whitesides, G. M., 1 Am. Chem. Soc., 1989, .1.11, 627.635.</td></tr><tr><td>248.</td><td>"Enzymatic Baeyer-Villiger Type Oxidations of Ketones Catalyzed by Cyclohexanone Oxygenase",
Abril, 0., Ryerson, C. C., Walsh, C. and Whitesides, G. M., Bioorg. Chem., 1989, /7, 41-52.</td></tr><tr><td>247.</td><td>"Oxidation of 2-Propanol to Acetone by Dioxygen on a Platinized Electrode under Open-Circuit
Conditions", DiCosimo, R. and Whitesides, G. M., J. Phys. Chem., 1989, 93, 768-775.</td></tr><tr><td>246.</td><td>"Liquid-Phase Oxidation of 2-Propanol to Acetone by Dioxygen Using Supported Platinum
Catalysts", Nicoletti, J. W. and Whitesides, G. M., J. Phys. them., 1989, 93, 759-767.</td></tr><tr><td>245.</td><td>"A Combined Chemical-Enzymatic Synthesis of 3-Deoxy-D-arabino-heptulosonic Acid 7-
Phosphate", Turner, N. J. and Whitesides, G. M., J. Am. Chem. Soc., 1989, III, 624.627.</td></tr><tr><td>244.</td><td>"Enzymatic Methods for the Preparation of Acetyl-CoA and Analogs", Billhardt, U.-M., Stein, P. and
Whitesides, G. M., Bioorg. Chem., 1989, .17, 1-12.</td></tr><tr><td>243. </td><td>"Formation of Monolayer Films by the Spontaneous Assembly of Organic Thiols from Solution onto</td></tr></table>

# Publications (cont.)

## Publications 1980-1989 (cont.)

<table><tr><th></th><th>Gold", Bain, C. D., Troughton, E. B., Tao, Y.-T., Evall, J., Whitesides, G. M. and Nuzzo, R. G., J.
Am. Chem. Soc., 1989, 111, 321.335.</th></tr><tr><td>242.</td><td>"The Anthranilate Amide of 'Polyethylene Carboxylic Acid' Shows an Exceptionally Large Change
with pH in Its Wettability by Water", Wilson, M. and Whitesides, G. M., J. Am. Chem. Soc., 1988,
110, 8718.8719.</td></tr><tr><td>241.</td><td>"Poly(3-n-butyl-2,5-diethynylenethiophenylene): A Soluble Polymer Containing Diacetylene Units
and Its Conversion to a Highly-Cross-Linked Organic Solid", Callstrom, M. R., Neenan, T. X. and
Whitesides, G. M., Macromolecules, 1988, 21, 3528-3530.</td></tr><tr><td>240.</td><td>"Hyper-Goss-Linked Organic Solids: Preparation from Poly(aryldiacetylenes) and Preliminary
Measurements of their Young's Modulus, Hardness and Thermal Stability", Neenan, T. X.,
Callstrom, M. R., Scarmoutzos, L. M., Stewart, K. R. and Whitesides, G. M., Macromolecules,
1988, 21, 3525.3528.</td></tr><tr><td>239.</td><td>"Formation of Two-Component Surfaces by the Spontaneous Assembly of Monolayers on Gold
from Solutions Containing Mixtures of Organic Thiols", Bain, C. D. and Whitesides, G. M., J. Am.
Chem. Soc., 1988, 110, 6560.6561.</td></tr><tr><td>238.</td><td>"Materials for Advanced Electronic Devices", Whitesides, G. M., in Biotechnology and Materials
Science: Chemistry for the Future, M. A. Good, Ed., American Chemical Society, Washington,
1988, 85-99.</td></tr><tr><td>237.</td><td>"Depth Sensitivity of Wetting: Monolayers of w-Mercaptoethers on Gold", Bain, C. D. and
Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 5897-5898.</td></tr><tr><td>236.</td><td>"Organic Chemistry in Two Dimensions: Surface-Functionalized Polymers and Self-Assembled
Monolayer Films", Whitesides, G. M. and Ferguson, G. S., Chemtracts, 1988, 1, 171-187.</td></tr><tr><td>235.</td><td>"Cofactor Regeneration for Enzyme-Catalyzed Synthesis", Chenault, H. K., Simon, E. S. and
Whitesides, G. M., in Biotechnology &amp; Genetic Engineering Reviews, G. E. Russell, Ed., Intercept,
Wimborne, 1988, 6, 221-270.</td></tr><tr><td>234.</td><td>"Correlation between Wettability and Structure in Monolayers in Alkanethiols Adsorbed on Gold",
Bain, C. D. and Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 3665-3666.</td></tr><tr><td>233.</td><td>"Synthesis of CMP-NeuAc from N-Acetylgluoosamine: Generation of aP from CMP using
Adenylate Kinase", Simon, E. S., Bednarski, M. D. and Whitesides, G. M., J. Am. Chem. Soc. ,
1988, 110, 7159-7163.</td></tr><tr><td>232.</td><td>"Synthesis of Analogs of 1,3-Dihydroxyacetone Phosphate and Glyceraldehyde-3-phosphate for
Use in Studies of Fructose-1,6-Diphosphate Aldolase", Bischofberger, N., Waldmann, H., Saito, T.,
Simon, E. S., Lees, W., Bednarski, M. D. and Whitesides, G. M., Journal of Organic Chemistry,
1988, 53, 3457.3465.</td></tr><tr><td>231.</td><td>"Intermolecular Activation of C-D Bonds in Benzene-d6 by trans-Neopentyl
(trifluoromethanesulfonato)bis(trimethylphosphine)platinum(I1)", Brainard, R. L., Nutt, W. R., Lee,
T. R. and Whitesides, G. M., Organornetallics, 1988, 7, 2379-2386.</td></tr><tr><td>230.</td><td>"Enzymes as Catalysts in Organic Synthesis", Akiyama, A., Bednarski, M., Kim, M.-J., Simon, E. S.,
Waldmann, H. and Whitesides, G. M., Chemtedi, 1988, 627-634.</td></tr><tr><td>229.</td><td>"Molecular-Level Control over Surface Order in Self-Assembled Monolayer Films of Thiols on Gold",
Bain, C. D. and Whitesides, G. M., Science, 1988, 240, 62-63.</td></tr><tr><td>228.</td><td>"The Synthesis of High Carbon Materials from Acetylenic Precursors. Preparation of Aromatic
Monomers Bearing Multiple Ethynyl Groups", Neenan, T. X. and Whitesides, G. M., J. Org. Chem.,
1988, 53, 2489-2496.</td></tr><tr><td>227. </td><td>"L-Lactate Dehydrogenase: Substrate Specificity and Use as a Catalyst in the Synthesis of
Homochiral 2-Hydroxy Acids", Kim, M.-J. and Whitesides, G. M., 1 Am. Chem. Soc., 1988, 110,</td></tr></table>

# Publications (cont.)

## Publications 1980-1989 (cont.)

# Publications (cont.)

## 2959-2964.

<table><tr><th>226.</th><th>Vetting of Functionalized Polyethylene Film Having Ionizable Organic Acids and Bases at the
Polymer-Water Interface: Relations between Functional Group Polarity, Extent of Ionization, and
Contact Angle with Water", Holmes-Farley, S. R., Bain, C. and Whitesides, G. M., Langmuir, 1988,
4, 921-937.</th></tr><tr><td>225.</td><td>"Isotopic Exchange Reactions Occurring in the Hydrogenation of 1,5-
Cyclooctadienedialkylplatinum(II) Complexes over Platinum Black", Miller, T. M. and Whitesides,
G. M., J. Am. Chem. Soc., 1988, //0, 3164-3170.</td></tr><tr><td>224.</td><td>"Deuterium Labeling Experiments Relevant to the Mechanism of Platinum-Catalyzed
Hydrogenation of Diolefindialkylplatinum(II) Complexes: Evidence for Isotopic Exchange via
Platinum Surface Hydrogen; the Stereochemistry of Reduction", Miller, T. M., McCarthy, T. J. and
Whitesides, G. M., J. Am. Chem. Soc., 1988, 110, 3156.3163.</td></tr><tr><td>223.</td><td>"Heterogeneous, Platinum-Catalyzed Hydrogenation of Diolefindialkylplatinum(II) Complexes:
Kinetics", Miller, T. M., Izumi, A. N., Shih, Y.-S. and Whitesides, G. M., J. Am. Chem. Soc., 1988,
110, 3146.3156.</td></tr><tr><td>222.</td><td>'The Structures of Self-Assembled Monolayer Alms of Organosulfur Compounds Adsorbed on Gold
Single Crystals: Electron Diffraction Studies", Strong, L. and Whitesides, G. M., Langmuir, 1988, 4, 
546-558. </td></tr><tr><td>221.</td><td>"Monolayer Films Prepared by the Spontaneous Self-Assembly of Symmetrical and Unsymmetrical
Dialkyl Sulfides from Solution onto Gold Substrates: Structure, Properties, and Reactivity of
Constituent Functional Groups", Troughton, E. B., Bain, C. D., Whitesides, G. M., Nuzzo, R. G.,
Allara, D. L. and Porter, M. D., Langmuir, 1988, 4,  365-385. </td></tr><tr><td>220.</td><td>"The Use of Enzymes as Catalysts for Synthesis in Medicinal Chemistry: Chiral Synthons and
Carbohydrates", Whitesides, G. M. and Kim, M.-J., in New Methods in Drug Research, Vol. 2, A.
Makriyannis, Ed., J.R. Prous, Philadelphia, 1988, 1-15.</td></tr><tr><td>219.</td><td>"[Bis(dicydohexylphosphino)ethane]platinum(0): Reactions with Alkyl, (Trimethylsilyfimethyl, Aryl,
Benzyl, and Alkynyl Carbon-Hydrogen Bonds", Hackett, M. and Whitesides, G. M., 1 Am. Chem.
Soc., 1988, 110, 1449-1462.</td></tr><tr><td>218.</td><td>"The Activation of the C-H Bonds of Benzene by Reaction with [Bis(dicyclo-hexylphosphino)
ethane]platinum(0), Generated by the Thermolysis of cis-[Bis(dicyclohexylphosphino)ethane]
(hydride)(neopentyl)platinum(II)", Hackett, M., Ibers, J. A. and Whitesides, G. M., 1 Am. Chem.
Soc., 1988, 110, 1436-1448.</td></tr><tr><td>217.</td><td>"Generation of Cytidine 5'-Triphosphate Using Adenylate Kinase", Simon, E. S., Bednarski, M. D.
and Whitesides, G. M., Tet Lett., 1988, 29, 1123-1126.</td></tr><tr><td>216.</td><td>"Synthesis of 3-Deoxy-D-manno-2-octulosonate-8-phosphate (KDO-8-P) from D-Arabinose:
Generation of D-Arabinose-5-Phosphate Using Hexokinase", Bednarski, M. D., Grans, D. C.,
DiCosimo, R., Simon, E. S., Stein, P. D. and Whitesides, G. M., Tet. Lett., 1988, 29, 427-430.</td></tr><tr><td>215.</td><td>"Carlons: Organic Polymers from Condensation of Carbon Dinudeophiles with Difunctional
Derivatives of Carboxylic Acids", Kool, L. B. and Whitesides, G. M., 1 Am. Chem. Soc., 1988, 110,
306-307. </td></tr><tr><td>214.</td><td>"Enzyme-Catalyzed Synthesis of Nucleoside Triphosphates from Nucleoside Monophosphates: ATP
from AMP and Ribavirin 5'-triphosphate from Ribavirin 5'-monophosphate", Kim, M.-3. and
Whitesides, G. M., Appi. Biochem. Biotech., 1987, 16, 95-108.</td></tr><tr><td>213.</td><td>"Enzymatic Regeneration of Adenosine 5'-Triphosphate: Acetyl Phosphate, Phosphoenylpyruvate,
Methoxycarbonyl Phosphate, Dihydroxyacetone Phosphate, 5-Phospho-a-D-ribosyl Pyrophosphate,
Uridine-5'-diphosphoglucose", Cans, D. C., Kazlauskas, Ft J., Hirschbein, B. L., Wong, C.-H., Abril,
0. and Whitesides, G. M., in Methods Enzymol.: Immobilized Enzymes/Cells, Pt. C, K. Mosbach,
Ed., 1987, 136, 263-80.</td></tr></table>

# Publications (cont.)

## 2959-2964. (cont.)

<table><tr><th>212.</th><th>"Protein Synthesis in Cell-Free Reticulocyte Lysates on Multi-Hour Incubation", Findeis, M. A. and
Whitesides, G. M., App/. Biochem. Biotech., 1987,15, 169-189. </th></tr><tr><td>211.</td><td>"Placeholder-No publication with this call number",,, 1987.,, 1987.</td></tr><tr><td>210.</td><td>"The Measurement of Thiel-Disulfide Interchange Reactions and Thiol pKa Values", Houk, 1,
Singh, R. and Whitesides, G. M., in Methods in Enzymology: Sulfur and Sulfur Amino Acids, W. B.
Jakoby and 0. W. Griffith, Eds., Academic Press, New York, 1987,129-143.</td></tr><tr><td>209.</td><td>"Structure-Reactivity Relations for Thiol-Disulfide Interchange", Houk, J. and Whitesides, G. M., J. 
Am. Chem. Soc., 1987,log 6825.6836. </td></tr><tr><td>208.</td><td>"What, If Anything, Can Chemistry Offer to Fracture Mechanics?", G. M. and Neenan, T. X., in
Chemistry and Physics of Fracture, NATO ASI Series E: Applied Sciences - No. 130, R. M.
Latanision,  Ed.,Dordrecht,1987, 12-22. </td></tr><tr><td>207.</td><td>"Enzymes in Organic Synthesis", Waldmann, H. and Whitesides, G. M., in Ullmann's Encyclopedia
of Industrial Chemistry, A9: </td></tr><tr><td>206.</td><td>"Limited Nerve Impulse Blockade by 'Leashed' Local Anesthetics", Butterworth, 1. F., Moran, J. R.,
Whitesides, G. M. and Strichartz, G. R.,1. Med. Chem., 1987,30, 1295-1302. </td></tr><tr><td>205.</td><td>"A Short Synthesis of Ambroxim from Sclareol", Decorzant, R., Vial, C., NM, F. and Whitesides, G.
M.,  Tetrahedron,  1987,  43,  1871-1879. </td></tr><tr><td>204.</td><td>"Enzymes as Catalysts in Practical Organic Synthesis", Akiyama, A., Bednarski, M., Kim, M.-J. S.,
E.S., Waldmann, H. and Whitesides, G. M., Chem. Britain, 1987,23,645-654.</td></tr><tr><td>203.</td><td>"The Enantiomeric Purity of Polar Substrates Can Be Determined with Chiral Lanthanide NMR Shift
Reagents in Polar Solvents", Sweeting, L. M., Crans, D. C. and Whitesides, G. M., J. Org. Chem.,
1987,52, 2273-2276. </td></tr><tr><td>202.</td><td>2-Deoxy-D-Ribose "Fumarase-Catalyzed Synthesis of L-threo-Chloromalic Acid, and Its Conversion to
and D-erythro-Sphingosine", Findeis, M. A. and Whitesides, G. M., J. Org. Chem., 1987, 
52,  2838-2848. </td></tr><tr><td>201.</td><td>"Regeneration of Nicotinamide Cofactors for Use in Enzymatic Synthesis", Chenault, K. and
Whitesides, G. M., App/. Sachem. Biotech., 1987, 14, 147-197.</td></tr><tr><td>200.</td><td>"Enzymatic Routes to Enantiomerically Enriched 1-Butene Oxide", Chenault, H. K., Kim, M.-J.,
Akiyama, A., Miyazawa, T., Simon, E. and Whitesides, G. M., J. Org. Chem., 1987,52, 2608-2611. </td></tr><tr><td>199.</td><td>"Membrane-Enclosed Enzymatic Catalysis (MEEC): A Useful, Practical Method for the Manipulation
of Enzymes in Organic Synthesis", Bednarski, M. D., Chenault, H. K., Simon, E. S. and Whitesides,
G. M., J. Am. Chem. Soc., 1987,109, 1283-1285. </td></tr><tr><td>198.</td><td>"Reconstruction of the Interface of Oxidatively Functionalized Polyethylene (PE-CO2H) and
Derivatives on Heating", Holmes-Farley, S. R., Reamey, R. H., Nuzzo, R., McCarthy, T. J. and
Whitesides, G. M., Langmuir, 1987, 3,799-815.</td></tr><tr><td>197.</td><td>"The Synthesis and Thermolysis of Dimethylbis(trialkylphosphine)-platinum(II) Complexes in
Which the Phosphine Ugands Contain Adamantyl, Adamantylmethyl, and Methyl Groups", Hackett,
M. and Whitesides, G. M., aganometallia,  1987, 6, 403-410.</td></tr><tr><td>196.</td><td>"The Enzymatic Utilization of Sucrose in the Synthesis of Amylose and Derivatives of Amylose
Using Phosphorylases", Waldmann, H., Gygax, D., Bednarski, M., Shangraw, W. R. and
Whitesides, G. M., Carbohyd. Res., 1986,157, c4-c7. </td></tr><tr><td>195. </td><td>'The Reactivity of Carboxylic Acid and Ester Groups in the Functionalized Interfacial Region of
'Polyethylene Carboxylic Acid' (PE-CO2H) and Derivatives:  Differentiation of the Functional Groups
into Shallow and Deep Subsets Based on a Comparison of Contact Angle and ATR-IR</td></tr></table>

# Publications (cont.)

## 2959-2964. (cont.)

Measurements", Holmes-Farley, S. R. and Whitesides, G. M., Langmuir, 1986, 2, 62-76.

<table><tr><th>194.</th><th>"Cis(bis(dicyclohexylphosphino)ethane)platinum(0) Reacts with Unactivated Carbon-Hydrogen
Bonds", Hackett, M., Ibers, 3. A., Jemakoff, P. and Whitesides, G. M., J. Am. Chem. Soc., 1986,
108, 8094-8095.</th></tr><tr><td>193.</td><td>"Aldolase-Catalyzed Synthesis of Complex CS and C9 Monosaccharides", Bednarski, M. D.,
Waldmann, H. J. and Whitesides, G. M., Tet. Lett., 1986, 5807.5810.</td></tr><tr><td>192.</td><td>"Synthesis of a Water-Soluble Derivative of Cydohexathacontane-1,2,13,14,25,26-hexone",
Mandeville, W. H. and Whitesides, G. M., J. Org. Chem., 1986, 51, 3257-3261.</td></tr><tr><td>191.</td><td>"Radical Isomerization during Grignard Reagent Formation. A Quantitative Treatment", Garst, J.
F., Deutch, J. E. and Whitesides, G. M., J. Am. Chem. Soc., 1986, 108, 2490-2491.</td></tr><tr><td>190.</td><td>"Chemistry and Materials Science: Molecular Design and Engineering", Whitesides, G. M.,
Wrighton, M. S. and Parshall, G., in Advancing Materials Research, National Academy of Sciences,
Washington, D.C., 1986, 203-224.</td></tr><tr><td>189.</td><td>"Improved Adhesion of Thin Conformal Organic Films to Metal Surfaces", Stewart, K. R.,
Whitesides, G. M., Godfried, H. P. and Silvera, I. F., Rev. Sci. Instrum., 1986, 57, 1381.1383.</td></tr><tr><td>188.</td><td>'The Mechanisms of Thermal Decomposition of trans-Chloroneopentylbis(tricyclopentylphosphine)
platinum(II)", Brainard, R. L., Miller, T. M. and Whitesides, G. M., Organometal/ics, 1986, 5, 1481-
1490. </td></tr><tr><td>187.</td><td>"Fluorescence Properties of Dansyl Groups Covalently Bonded to the Surface of Oxidatively
Functionalized Low-Density Polyethylene Film", Holmes-Farley, S. R. and Whitesides, G. M.,
Langmuir, 1986, 2, 266.282.</td></tr><tr><td>186.</td><td>'The Mechanism of Thermal Decomposition of Bis(tricyclopentylphosphine)-platinacyclopentane
(II): Intramolecular b-Hydride Elimination from the Platinacyclopentane Ring is Slow Relative to
an Intermolecular Chain Reaction Involving Hydridoplatinum Intermediates", Miller, T. M. and
Whitesides, G. M., Organometalks, 1986, 5, 1473-1480.</td></tr><tr><td>185.</td><td>"Preparation of Optically Active 1,2-Diols and a-Hydroxyketones Using Glycerol Dehydrogenase as
Catalyst: Limits to Enzyme-Catalyzed Synthesis Due to Non-competitive and Mixed Inhibition by
Product", Lee, L. G. and Whitesides, G. M., J. Org. Chem., 1986, 51, 25-36.</td></tr><tr><td>184.</td><td>"Acid-Based Behavior of Carboxylic Acid Groups Covalently Attached at the Surface of
Polyethylene: The Usefulness of Contact Angle in Following the Ionization of Surface
Functionality", Holmes-Farley, S. R., Reamey, R. H., McCarthy, T. J., Deutch, J. and Whitesides, G.
M., Langmuir, 1985, 1, 725.740.</td></tr><tr><td>183.</td><td>"Glycerol Kinase: Synthesis of Dihydroxyacetone Phosphate, sn-Glycerol-3-Phosphate, and Chiral
Analogues", Grans, D. C. and Whitesides, G. M., J. Am. Chem. Soc., 1985, 107, 7019-7027.</td></tr><tr><td>182.</td><td>"Glycerol Kinase: Substrate Specificity", Cans, D. C. and Whitesides, G. M., J. Am. Chem. Soc,
1985, 107, 7008-7018.</td></tr><tr><td>181.</td><td>"Enzymes as Catalysts in Synthetic Organic Chemistry", Whitesides, G. M. and Wong, C-H.,
Angew. Chem. Int. Ed. Engl., 1985, 24, 617-638.</td></tr><tr><td>180.</td><td>"Enzyme-Catalyzed Organic Synthesis: A Comparison of Strategies for in situ Regeneration of NAD
from NADH", Lee, L. G. and Whitesides, G. M., J. Am. Chem. Soc., 1985, 107, 6999-7008.</td></tr><tr><td>179.</td><td>"Suppression of Unwanted Heterogeneous Platinum(0)-Catalyzed Reactions by Poisoning with
Mercury(0) in Systems Involving Competing Homogeneous Reactions of Soluble Organoplatinum
Compounds: Thermal Decomposition of Bis(triethylphosphine)-3,3,4,4-
tetramethylplatinacycbpentane", Whitesides, G. M., Hackett, M., Brainard, R. L., Lavalleye, J.-P.
P. M., Sowinski, A. F., Izumi, A. N., Moore, S. S., Brown, D. W. and Staudt, E. M.,
Organometal/ics, 1985, 4, 1819-1830.</td></tr></table>

# Publications (cont.)

## 2959-2964. (cont.)

<table><tr><th>178.</th><th>'The Mechanism of Thermal Decomposition of trans-Chloroethylbis-(triethylphosphine)platinum
(II)", Brainard, R. L. and Whitesides, G. M., Organometallics, 1985, 4, 1550-1557.</th></tr><tr><td>177.</td><td>"Enzymatic Synthesis of DeoxyATP Using DNA as Starting Material", Ladner, W. E. and Whitesides,
G. M., J. Org. Chem., 1985, 50, 1076.1079.</td></tr><tr><td>176.</td><td>"Organic Synthesis Using Enzymes", Whitesides, G. M., in Organic Chemical Synthesis Using
Enzymes, Ciba Foundation Symposium No. 111, Ciba Foundation, London, 1985, 76-90.</td></tr><tr><td>175.</td><td>"Synthesis of Methoxycarbonyl Phosphate, A New Reagent Having High Phosphoryl Donor
Potential for Use in ATP Cofactor Regeneration", Kazlauskas, R. J. and Whitesides, G. M., J. Org.
Chem., 1985, 50, 1069-1076.</td></tr><tr><td>174.</td><td>"Organic Chemicals from Marine Sources", Whitesides, G. M. and Elliot, J., in Biotechnology in the
Marine Sciences, R. M. Colwell, E. R. Pariser and A. J. Sinskey, Eds., John Wiley, New York, 1984,
135-152. </td></tr><tr><td>173.</td><td>"Lipase-Catalyzed Hydrolysis as a Route to Esters of Chiral Epoxy Alcohols", Ladner, W. E. and
Whitesides, G. M., J. Am. Chem. Soc., 1984, 106, 7250-7251.</td></tr><tr><td>172.</td><td>"Enzymatic Methods in Organic Synthesis", Findeis, M. A. and Whitesides, G. M., Ann. Rep. Mad
Otem., 1984, 19, 263-272.</td></tr><tr><td>171.</td><td>"Enzymatic Synthesis of Arginine Phosphate with Coupled ATP Cofactor Regeneration", Bolte, J.
and Whitesides, G. M., thoorg. Chem., 1984, 12, 170-175.</td></tr><tr><td>170.</td><td>"A Practical Enzymatic Synthesis of (SP)-Adenosine 5'-0-(1-Thiotriphosphate)((SP)-ATP-a-S)",
Moran, J. R. and Whitesides, G. M., 1 Org. Chem., 1984, 49, 704.706.</td></tr><tr><td>169.</td><td>"Practical Enzymatic Synthesis of Adenosine-5'-O-(3-Thiophosphate)(ATP-g-S)", Abril, 0., Crans,
D. C. and Whitesides, G. M., 1 Org. Chem., 1984, 49, 1360-1364.</td></tr><tr><td>168.</td><td>"An Efficient Chemical and Enzymatic Synthesis of Nicotinamide Adenine Dinudeotide (NAD+)",
Walt, D. R., Rios-Mercadillo, V. M., Auge, J. and Whitesides, G. M., 1 Am. Chem. Soc, 1984, 106,
234-239. </td></tr><tr><td>167.</td><td>"The Mechanism of Hydrogenolysis of Dineopentylbis(triethylphosphine)platinum(II)", Reamey, R.
H. and Whitesides, G. M., J. Am. Chem. Soc., 1984, 106, 81-85.</td></tr><tr><td>166.</td><td>"Organometallic Reactions of Platinum Involving Metallic Hydrides", Whitesides, G. M., Reamey, R.
H., Brainard, R. L., Izumi, A. N. and McCarthy, T. J., Annals New York Acad. Sci, 1983, 415, 56-
66. </td></tr><tr><td>165.</td><td>"Chemical Modification of Acrylamide Gels: Verification of the Role of Ionization in Phase
Transitions", Nicoll, D., Young, C., Tanaka, T., Pollak, A. and Whitesides, G. M., Macromolecules,
1983, 16, 887-890.</td></tr><tr><td>164.</td><td>"Magnetic Separations in Biotechnology", Whitesides, G. M., Kazlauskas, R. and Josephson, L.,
7787ECH, 1983, 1, 144-148.</td></tr><tr><td>163.</td><td>"Practical Synthesis of 5-Phospho-D-ribosyl-a-1-pyrophosphate (PRPP): Enzymatic Routes from
Ribose-5-phosphate or Ribose", Gross, A., Abril, 0., Lewis, J. M., Geresh, S. and Whitesides, G.
M., 1 Am. Chem. Soc, 1983, 105, 7428-7434.</td></tr><tr><td>162.</td><td>"Enzymes as Catalysts in Organic Synthesis", Whitesides, G. M. and Wong, C-H., Aldrichimica
Acta, 1983, 16, 27-34.</td></tr><tr><td>161.</td><td>"A Convenient Synthesis of Disodium Acetyl Phosphate for Use in situ ATP Cofactor
Regeneration", Crans, D. C. and Whitesides, G. M., J. Org. Chem., 1983, 26, 3130-3132.</td></tr><tr><td>160. </td><td>"Enzymatic Synthesis of S-Adenosyl-L-Methionine from L-Methionine and ATP", Gross, A., Geresh,</td></tr></table>

# Publications (cont.)

## 2959-2964. (cont.)

S. and Whitesides, G. M., App/. Biochem. Biotech., 1983, 8, 415-422.

<table><tr><th>159.</th><th>"Enzyme-Catalyzed Organic Synthesis: Regeneration of Deuterated Nicotinamide Cofactors for Use
in Large-Scale Enzymatic Synthesis of Deuterated Substances", Wong, C.-H. and Whitesides, G.
M., J. Am. Chem. Soc, 1983, 105, 5012-5014.</th></tr><tr><td>158.</td><td>"Synthesis of Sugars by Aldolase-Catalyzed Condensation Reactions", Wong, C.-H. and
Whitesides, G. M., J. Org. Chem., 1983, 48, 3199-3205.</td></tr><tr><td>157.</td><td>"Chemical 2,5-Dimethy1-4-Hydroxy-2,3-Dihydro-furan-3-one and Enzymatic Synthesis of 6-Deoxyhexoses. Conversion to
(FuraneolO) and Analogues", Wong, C.-H. and Whitesides, G. M., J. Org.
Chem., 1983, 48, 3493-3497.</td></tr><tr><td>156. </td><td>"Activation Parameters for Thiolate-Disulfide Interchange", Whitesides, G. M., Houk, J. and
Patterson, M. A. IC, 3. Org. Chem., 1983, 48,112-115.</td></tr><tr><td>155. </td><td>"Relations between Fracture and Coordination Chemistry", Whitesides, G. M., in Atomistics of
Fracture, R. M. Latanision and J. R. Pickens, Eds., Plenum Press, New York, 1983, 337-362.</td></tr><tr><td>154. </td><td>"Preparation of a Mixture of Nucleoside Triphosphates from Yeast RNA: Use in Enzymatic
Synthesis Requiring Nucleoside Triphosphate Regeneration, and Conversion to Nucleoside
Diphosphate Sugars", Wong, C.-H., Haynie, S. L. and Whitesides, G. M., J. Am. Chem. Soc, 1983,
105, 115-117.</td></tr><tr><td>153.</td><td>"Enzyme-Catalyzed Synthesis of N-Acetyllactosamine with in situ Regeneration of Uridine 5'-
Diphosphate Glucose and Uridine 5'-Diphosphate Galactose, Wong, C.-H., Haynie, S. L. and
Whitesides, G. M., J. Org. Chem., 1982, 47, 5416-5418.</td></tr><tr><td>152.</td><td>"Ribulose-1,5-Biphosphate: Routes from Glucose-6-Phosphate (via 6-Phosphogluconate and
Ribulose-5-phosphate) and from Adenosine Monophosphate (via Ribose-5-phosphate and
Ribulose-5-phosphate)", Wong, C.-H., Pollak, A., McCurry, S. D., Sue, M. M., Knowles, J. R. and
Whitesides, G. M., in Methods in Enzymology, W. A. Wood, Ed., Academic Meas, New York, 1982,
108-121. </td></tr><tr><td>151.</td><td>"Asymmetric Synthesis Using Cofactor-Requiring Enzymes", Whitesides, G. M., Wong, C.-H. and
Pollak, A., in Asymmetric Reactions and Processes in Chemistry, E. Eliel and S. Otsuka, Eds.,
American Chemical Society, Washington, D.C., 1982, 185, 1-205.</td></tr><tr><td>150.</td><td>"Synthesis of Phosphoenolpyruvate and Its Use in ATP Cofactor Regeneration", Hirschbein, B. L.,
Mazenod, F. P. and Whitesides, G. M., 1 Org. Chem., 1982, 47, 3765-3766.</td></tr><tr><td>149.</td><td>"Enzyme-Catalyzed Transhydrogenation between Nicotinamide Cofactors and Its Application in
Organic Synthesis", Wong, C.-H. and Whitesides, G. M., 1 Am. Chem. Soc., 1982, 104, 3542-
3544. </td></tr><tr><td>148.</td><td>"Enzyme-Catalyzed Organic Synthesis: NAD(P)H Cofactor Regeneration Using Ethanol/Alcohol
Dehydrogenase/Aldehyde Dehydrogenase and Methanol/Alcohol Dehydrogenase/Aldehyde
Dehydrogenase/Formate Dehydrogenase", Wong, C: H. and Whitesides, G. M., J. Org. Chem.,
1982, 47, 2816.2818.</td></tr><tr><td>147.</td><td>L-Potassium "Laboratory-Scale Enzymatic/Chemical Synthesis of O- and L-b-Chlorolactic Acid and D- and
Glycidate", Hirschbein, B. L. and Whitesides, G. M., J. Am. Chem. Soc., 1982, 104,
4458-4460. </td></tr><tr><td>146.</td><td>"Reductive Elimination of a Carbon-Carbon Bond from Bis(trialkylphosphine)-3,3-
dimethylplatinacyclopropane Produces Bis(trialkylphosphine)-platinum(0) and 1,1-
Dimethylcyclopropane", DiCosimo, R. and Whitesides, G. M., 1 Am. Chem. Soc, 1982, 104, 3601-
3607. </td></tr><tr><td>145.</td><td>"Synthesis and Coordinating Properties of Heterocyclic Tertiary Phosphines", Moore, S. S. and
Whitesides, G. M., J. Org. Chem., 1982, 47, 1489-1493.</td></tr></table>

# Publications (cont.)

## 2959-2964. (cont.)

<table><tr><th>144.</th><th>"Magnetic Separations in Chemistry and Biochemistry", Hirschbein, B. L., Brown, D. W. and
Whitesides, G. M., Chemtech., 1982, 12, 172.179.</th></tr><tr><td>143.</td><td>"Reductive Elimination of H-H, H-CH3, and CH3-CH3 from Bis(phosphine)-platinum(II), -palladium
(II), and -nickel(II) Complexes: A Theoretical Study Using the SCF-Xa-SW Method", Balazs, A. C.,
Johnson, K. H. and Whitesides, G. M., lnorg. Chem., 1982, 21, 2162.2174.</td></tr><tr><td>142.</td><td>"Structures of Dineopentylbis(triethylphosphine)platinum(II) and Bis(triethylphosphine)-3,3-
dimethylplatinacydobutane: Reactant and Product in a Thermal Cyclometallation Reaction", Ibers,
J. C., DiCosimo, R. and Whitesides, G. M., Organometallics, 1982, 1, 13-20.</td></tr><tr><td>141.</td><td>"Affinity Separation of Enzymes from Mixtures Containing Suspended Solids: Comparisons of
Magnetic and Non-Magnetic Techniques", Hirschbein, B. L. and Whitesides, G. M., Apo'. Biochem.
Biotech., 1982, 7, 157-176.</td></tr><tr><td>140.</td><td>"Hybrid Organometallic/Enzymatic Catalyst Systems: Regeneration of NADH Using Dihydrogen",
Abril, O. and Whitesides, G. M., J. Am. Chem. Soc., 1982, 104, 1552-1554.</td></tr><tr><td>139.</td><td>"Cydometalation of Dialkylbis(triethylphosphine)platinum(II) Complexes: Formation of Pt, Pt-Bis
(triethylphosphine)platinacycloalkanes", DiCosimo, R., Moore, S. S., Sowinski, A. F. and
Whitesides, G. M., J. Am. Chem. Soc., 1982, 104, 124.133.</td></tr><tr><td>138.</td><td>"Enzymatic Conversion of a-Ketoaldehydes to Optically Active a-Hydroxacids Using Glyoxalase I
and II", Patterson, M. A. K., Szajewski, R. P. and Whitesides, G. M., J. Org. Chem., 1981, 46,
4682.4685. </td></tr><tr><td>137.</td><td>"Regeneration of NAD(P)H Using Glucose-6-Sulfate and Glucose-6-Phosphate Dehydrogenase",
Wong, C.-H., Gordon, J., Cooney, C. L. and Whitesides, G. M., J. Org. Chem., 1981, 46, 4676-
4679. </td></tr><tr><td>136.</td><td>"Enzyme-Catalyzed Organic Synthesis: Electrochemical Regeneration of NAD(P)H from NAD(P)
Using Methyl Viologen and Flavoenzymes", DiCosimo, R., Wong, C-H., Daniels, L. and Whitesides,
G. M., J. Org. Chem., 1981, 46, 4622-4623.</td></tr><tr><td>135.</td><td>"A Combined Electrochemical/Enzymatic Method for in situ Regeneration of NADH Based on
Cathodic Reduction of Cyclic Disulfides", Shaked, Z., Barber, J. J. and Whitesides, G. M., J. Org.
aem., 1981, 46, 4100-4101.</td></tr><tr><td>134.</td><td>"Enzyme-Catalyzed Organic Synthesis: NAD(P)H Regeneration Using Dihydrogen and the
Orme-Johnson, Hydrogenase from Methanobacter thermoautotrophicum", Wong, C.-H., Daniels, L.,
W. H. and Whitesides, G. M., J. Am. Chem. Soc., 1981, 103, 6227.6228.</td></tr><tr><td>133.</td><td>"Synthesis of Functional Chelating Diphosphines Containing the Bisft(diphenylphosphino)ethyl]
amino Moiety and the Use of These Materials in the Preparation of Water-Soluble Diphosphine
Complexes of Transition Metals", Nuzzo, R. G., Haynie, S. L., Wilson, M. E. and Whitesides, G. M.,
1 Org. Chem., 1981, 46, 2861-2867.</td></tr><tr><td>132.</td><td>'The Mechanism of Formation of Grignard Reagents. The Rate of Reaction of Cydopentyl Bromide
with a Rotating Magnesium Disk", Root, K. S., Deutch, 3. and Whitesides, G. M., J. Am. Chem.
Soc., 1981, .103, 5475-5479.</td></tr><tr><td>131.</td><td>"Heterogenous Platinum-Catalyzed Hydrogenation of Dialkyl(diolefin)platinum(II) Complexes",
McCarthy, T. 3., Shih, Y.-S. and Whitesides, G. M., Proc. Nat. Acad. Sul 1154, 1981, 78, 4649-
4651. </td></tr><tr><td>130.</td><td>"The Mechanisms of Thermal Decomposition of Dialkylbis(triethylphosphine)platinum(II)
Complexes", Whitesides, G. M., Pure Appl. Chem., 1981, 53, 287-292.</td></tr><tr><td>129.</td><td>"Enzyme-Catalyzed Organic Synthesis: NAD(P)H Cofactor Regeneration Using Glucose-6-
Phosphate and the Glucose-6-Phosphate Dehydrogenase from Leuconostoc mesenteroides",
Wong, C.-H. and Whitesides, G. M., J. Am. Chem. Sac, 1981, 103, 4890-4899.</td></tr></table>

# Publications (cont.)

## 2959-2964. (cont.)

<table><tr><th>128.</th><th>"Apparent Fluxionality in Diethyl(phosphine)platinum(II), a Coordinately Unsaturated Intermediate
in b-Hydride Elimination", McCarthy, T. J., Nuzzo, R. G. and Whitesides, G. M., J. Am. Chem. Soc.,
1981, 103, 1676-1678.</th></tr><tr><td>127.</td><td>"Thermal Decomposition of Di(Cycloalky9bis(triethylphosphine)platinum-(II) Complexes", Nuzzo,
R. G., McCarthy, T. J. and Whitesides, G. M., J. Am. Chem. Soc., 1981, 103, 3404-3410.</td></tr><tr><td>126.</td><td>"Mechanisms of Thermal Decomposition of Diethylbis(triethylphosphine)-platinum(II)", McCarthy,
T. 1, Nuzzo, R. G. and Whitesides, G. M., J. Am. Chem. Soc., 1981, 103, 3396-3403.</td></tr><tr><td>125.</td><td>"Ring Strain in Bis(triethylphosphine)-3,3-dimethylplatinacyclobutane is Small", Moore, S. S.,
DiCosimo, R., Sowinski, A. F. and Whitesides, G. M., J. Am. Chem. Soc, 1981, 103, 948-949.</td></tr><tr><td>124.</td><td>"Preparation of Tertiary Phosphine-Olefin Complexes of Platinum(0): A Convenient Synthesis of
Ethylenebis(triethylphosphine)platinum(0)", Nuzzo, R. G., McCarthy, T. J. and Whitesides, G. M.,
!neg. Chem., 1981, 20, 1312-1314.</td></tr><tr><td>123.</td><td>"Practical Enzymatic Syntheses of Ribulose-1,5-diphosphate and Ribose-5-phosphate", Wong, C.-
H., McCurry, S. D. and Whitesides, G. M., 1 Am. Chem. Soc., 1980, 102, 7938-7939.</td></tr><tr><td>122.</td><td>"Synthesis of Nicotinamide Adenine Dinucleotide (NAD) from Adenosine Monophosphate (AMP)",
Walt, D. R., Rios-Mercadillo, V. M., Aug4, J. and Whitesides, G. M.,1. Am. Chem. Sac, 1980, 102,
7805.7806. </td></tr><tr><td>121.</td><td>"Enzyme-Catalyzed Organic Synthesis: NADH Regeneration Using Formate Dehydrogenase",
Shaked, Z. and Whitesides, G. M., J. Am. Chem. Soc., 1980, 102, 7104-7105.</td></tr><tr><td>120.</td><td>"Enzyme Immobilization by Condensation Copolymerization into Cross-linked Polyacrylamide
Gels", Pollak, A., Blumenfield, H., Wax, M., Baughn, R. L. and Whitesides, G. M., J. Am. Chem.
Sac., 1980, 102, 6324-6336.</td></tr><tr><td>119.</td><td>"Organic Synthesis Using Cofactor-Requiring Enzymes", Whitesides, G. M., in Enzymes: The
Interface between Technology and Economics, J. P. Danehy and B. Wolnak, Eds., Marcel Dekker,
Inc, New York, 1980, 17-24.</td></tr><tr><td>118.</td><td>'The Mechanism of Thermal Decomposition of Dineopentylbis(triethyl-phosphine)platinum(II):
Formation of Bis(triethylphosphine)-3,3-dimethylplatinacyclobutane", Foley, P., DiCosimo, R. and
Whitesides, G. M., 1 Am. Chem. Soc, 1980, 102, 6713-6725.</td></tr><tr><td>117.</td><td>"Rates of Thiol-Disulfide Interchange Reactions Involving Proteins, and Kinetic Measurements of
Thiol pKa Values", Shaked, Z., Szajewski, R. P. and Whitesides, G. M., Biochemistry, 1980, 19,
4156-4166. </td></tr><tr><td>116.</td><td>"Trappings of Free Alkyl Radical Intermediates in the Reaction of Alkyl Bromides with
Magnesium", Lawrence, L. M. and Whitesides, G. M., J. Am. Chem. Soc., 1980, 102, 2493.2494.</td></tr><tr><td>115.</td><td>"Reactions of Tetrakis(triphenylphosphine)platinum(0) and Ethylenebis(triphenylphosphine)
platinum(0) with Strong Proton Acids", Foley, P. and Whitesides, G. M., Marg. Chem., 1980, 19,
1402-1404. </td></tr><tr><td>114.</td><td>'The Mechanism of Formation of Grignard Reagents: Corrosion of Metallic Magnesium by Alkyl
Halides in Ethers", Hill, C. L., Vander Sande, J. B. and Whitesides, G. M., J. Org. Chem., 1980, 45,
1020.1028. </td></tr><tr><td>113.</td><td>"Rate Constants and Equilibrium Constants for Thiol-Disulfide Interchange Reactions Involving
Oxidized Gluthathione", Szajewski, R. P. and Whitesides, G. M., 1 Am. Chem. Soc., 1980, 102,
2011-2026. </td></tr><tr><td>112.</td><td>"Reductive Cleavage of Carbon-Halogen Bonds by Tri-n-butyltin Hydride, Lithium 4,4'-
Dimethylbenzophenone Ketyl, and Metallic Magnesium", Barber, J. J. and Whitesides, G. M., J.
Am. Chem. Sac, 1980, 102, 239-243.</td></tr></table>

# Publications (cont.)

## 2959-2964. (cont.)

111. "The Mechanism of Formation of Grignard Reagents: The Kinetics of Reaction of Substituted Aryl Bromides with Magnesium and with Tri-n-butyltin Hydride in Ethereal Solvents", Roberts, H. R., Rogers, H. R., Mitchell, H. L. and Whitesides, G. M., 2 Am. Chem. Soc., 1980,102,231-238.

110. "The Mechanism of Formation of Grignard Reagents: The Rate of Reaction of Cydopentyl Bromide with Magnesium is Transport-Limited in Diethyl Ether", Rogers, H. R., Deutch, J. and Whitesides, G. M., J. Am. Chem. Soc., 1980,102, 226-231.

109. 'The Mechanism of Formation of Grignard Reagents: The Kinetics of Reaction of Alkyl Halides in Diethyl Ether with Magnesium", Rogers, H. R., Hill, C. L, Fijiwara, Y., Rogers, R. J., Mitchell, H. L. and Whitesides, G. M., J. Am. Chem. Soc., 1980,102, 217-226.

# Publications (cont.)

## 2959-2964. (cont.)

The Whitesides Research Group

# Publications

# Publications (cont.)

## Publications 1990-1999

<table><tr><th>684.</th><th>"Bis-o-diynylarene (SODA) Derived Polynaphthalenes as Precursors to Glassy Carbon
Microstructures", Shah, H. V., Brittain, S. T., Huang, Q., Hwu, S.-)., Whitesides, G. M. and Smith,
D. W., Chem. Mat, 1999, 11, 2623-2625.</th></tr><tr><td>683.</td><td>"Exposure of Self-Assembled Monolayers to Highly Charged Ions and Metastable Atoms", Ratliff,
L. P., Minniti, R., Bard, A., Bell, E. W., Gillaspy, J. D., Parks, D., Black, A. J. and Whitesides, G. M.,
App/. Phys. Left, 1999, 75, 590-592.</td></tr><tr><td>682.</td><td>Self-Assembled "Fabrication of Ordered Two-Dimensional Arrays of Micro- and Nanopartides Using Patterned
Monolayers as Templates", Qin, D., Xia, Y., Xu, B., Yang, H., Zhu, C. and Whitesides,
G. M., Adv. Mater., 1999, 11, 1433-1437.</td></tr><tr><td>681.</td><td>"Non-Statistical Binding of a Protein to Clustered Carbohydrates", Horan, N., Yan, L., Isobe, H.,
Whitesides, G. M. and Kahne, D., Proc. Nat Acad. Sci. USA, 1999, 96, 11782.11786.</td></tr><tr><td>680.</td><td>"Selectivities among Capillary Bonds in Mesoscale Self-Assembly", Wu, H., Bowden, N. and
Whitesides, G. M., ADD/. Phys. Lett., 1999, 75, 3222-3224.</td></tr><tr><td>679.</td><td>"The Controlled Formation of Ordered, Sinusoidal Structures by Plasma Oxidation of an
Elastomeric Polymer", Bowden, N., Huck, W., Paul, K. and Whitesides, G. M., Appl. Phys. Lett.,
1999, 75, 2557.2559.</td></tr><tr><td>678.</td><td>"Patterned Polymer Growth on Silicon Surfaces Using Microcontact Printing and Surface-Initiated
Polymerization", Jeon, N. L., Choi, I., Kim, N., Laibinis, P., Harada, Y., Finnie, K. R., Girolami, G.
S., Nuzzo, R. G. and Whitesides, G. M., App/. PIlys. Lett., 1999, 75, 4201.4203.</td></tr><tr><td>677.</td><td>"Patterning Proteins and Cells using Soft Lithography", Kane, R. S., Takayama, S., Ostuni, E.,
Ingber, D. E. and Whitesides, G. M., 8iomatenals, 1999, 20, 2363-2376.</td></tr><tr><td>676. </td><td>"Correlations  Between the Charge of Proteins and the Number of Ionizable Groups They
Incorporate: Studies Using Protein Charge Ladders, Capillary Electrophoresis, and Debye-Hiickel
Theory", Carbeck, J. D., Colton, I. J., Anderson, J. R., Deutch, J. M. and Whitesides, G. M., J. Am.
Chem. Soc., 1999, 121, 10671.10679.</td></tr><tr><td>675.</td><td>"Fabrication of Photonic Crystal Lasers by Nanomolding of Sol-Gel Glasses", Schueller, O. J. A.,
Whitesides, G. M., Rogers, J. A., Meier, M. and Dodabalapur, A., Appl. Opt, 1999, 38, 5799-5802.</td></tr><tr><td>674.</td><td>"Macroscopic, Hierarchical Two-Dimensional Self-Assembly", Choi, I. S., Bowden, N. B. and
Whitesides, G. M., Angew. Chem. Int Ed. Engl., 1999, 38, 3078-3081.</td></tr><tr><td>673.</td><td>"Patterned Polymer Multilayers as Etch Resists", Huck, W. T. S., Yan, L., Stroock, A., Haag, R. and
Whitesides, G. M., Langmuir, 1999, 15, 6862-6867.</td></tr><tr><td>672.</td><td>"Using Patterns in Microfiche as Photomasks in 10-mm-Scale Microfabrication", Deng, T., Tien, J.,
Xu, B. and Whitesides, G. M., Langmuir, 1999, 15, 6575-6581.</td></tr><tr><td>671.</td><td>"Patterning Disorder in Monolayer Resists for the Fabrication of Sub-100-nm Structures in Silver,
Gold, Silicon, and Aluminum", Black, A. J., Paul, K. E., Aizenberg, J. and Whitesides, G. M., J. Am.
Chem. Soc., 1999, 121, 8356.8365.</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

<table><tr><th>670.</th><th>"Complexity in Chemistry", Whitesides, G. M. and Ismagilov, R. F., Science, 1999, 284, 89-92.</th></tr><tr><td>669.</td><td>"Making Negative Poisson's Ratio Microstructures by Soft Lithography, Xu, B., Arias, F., Brittain,
S. T., Zhao, X.-M., Grzybowski, B., Torquato, S. and Whitesides, G. M., Adv. Mater., 1999, 11,
1186-1189. </td></tr><tr><td>668.</td><td>"Microfabrication inside Capillaries Using Multiphase Laminar Flow Patterning", Kenis, P. J. A.,
Ismagilov, R. F. and Whitesides, G. M., Science, 1999, 285, 83.85.</td></tr><tr><td>667.</td><td>"Patterning Cells and Their Environments Using Multiple Laminar Fluid Flows in Capillary
Networks", Takayama, S., McDonald, J. C., Ostuni, E., Uang, M. N., Kenis, P. J. A., Ismagilov, R.
F. and Whitesides, G. M., Proc. Natl. Acad. Sci. USA, 1999, 96, 5545-5548.</td></tr><tr><td>666. </td><td>"Design and Self-Assembly of Open, Regular 3D Mesostructures", Breen, T. L., lien, 3., Oliver, S.
R. J., Hadzic, T. and Whitesides, G. M., Science, 1999, 284, 948.951.</td></tr><tr><td>665. </td><td>"Large-Area Patterning by Vacuum-Assisted Micromolding", leon, N. L., Choi, I. S., Xu, B. and
Whitesides, G. M., Adv. Mater., 1999, 11, 946-950.</td></tr><tr><td>664. </td><td>Nanometer-Thick "Electrical Breakdown of Aliphatic and Aromatic Self-Assembled Monolayers Used as
Organic Dielectrics", Haag, R., Rampi, M. A., Holmlin, R. E. and Whitesides, G. M., J. Am.
Chem. Soc., 1999, 121, 7895-7906.</td></tr><tr><td>663.</td><td>"Binding of a Dimeric Derivative of Vancomycin with L-Lys-D-Ala-D-lactate in Solution and at a
Surface", Rao, 3., Yan, L., Lahiri, 3., Whitesides, G. M., Weis, R. M. and Warren, H. S., Chem.
Blot, 1999, 6, 353-359.</td></tr><tr><td>662.</td><td>"Geometric Control of Switching Between Growth, Apoptosis, and Differentiation During
Angiogenesis Using Mkropatterned Substrates", Dike, L. E., Chen, C. S., Mrksich, M., Tien, 3.,
Whitesides, G. M. and Ingber, D. E., In Vitro Celt Dev. Bid., 1999, 35, 441-448.</td></tr><tr><td>661.</td><td>"Rapid Prototyping of Microfluidic Switches in Poly(dimethyl siloxane) and Their Actuation by
Electroosmotic Flow", Duffy, D. C., Schueller, 0. 3. A., Brittain, S. T. and Whitesides, G. M., J.
Micromechan. Microeng., 1999, 9, 211-217.</td></tr><tr><td>660.</td><td>"Electrochemistry and Soft Lithography: A Route to 3-D Microstructures", Jackman, R. 3. and
Whitesides, G. M., CHEMTECH, 1999, 29, 18-30.</td></tr><tr><td>659.</td><td>"Oriented Growth of Calcite Controlled by Self-Assembled Monolayers of Functionalized
Alkanethiols Supported on Gold and Silver", Aizenberg, J., Black, A. J. and Whitesides, G. M., J.
Am. Chem. Soc., 1999, 121, 4500.4509.</td></tr><tr><td>658.</td><td>"Long-Range Electrostatic Contributions to Protein-Ligand Binding Estimated Using Protein Charge
Ladders, Affinity Capillary Electrophoresis, and Continuum Electrostatic Theory", Caravella, J. A.,
Carbeck, J. D., Duffy, D. C., Whitesides, G. M. and Tidor, B., J. Am. Chem. Soc., 1999, .121, 4340-
4347. </td></tr><tr><td>657.</td><td>"Thermally Actuated Interferometric Sensors Based on the Thermal Expansion of Transparent
Elastomeric Media", Grzybowski, B. A., Brittain, S. T. and Whitesides, G. M., Rev. Sci. Instrum.,
1999, 70, 2031-2037.</td></tr><tr><td>656.</td><td>"Formation of Patterned Microstructures of Conducting Polymers by Soft Lithography and
Applications in Microelectronic Device Fabrication", Beh, W. S., Kim, I. T., Qin, D., Xia, Y. and
Whitesides, G. M., Adv. Mater., 1999, 11, 1038-1041.</td></tr><tr><td>655.</td><td>"Using Elastomeric Membranes as Dry Resists and for Dry Lift-Offw, Jackman, R. 3., Duffy, D. C.,
Chemiayskaya, 0. and Whitesides, G. M., Langmuir, 1999, .15, 2973-2984.</td></tr><tr><td>654.</td><td>"Probing the Energetics of Dissociation of Carbonic Anhydrase-Ligand Complexes in the Gas
Phase", Gao, 3., Wu, Q., Carbeck, 3., Lei, Q. P., Smith, R. D. and Whitesides, G. M., Biciphys. 1,
1999, 76, 3253-3260.</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

<table><tr><th>653.</th><th>"Mesoscale Self-Assembly of Hexagonal Plates Using Lateral Capillary Forces: Synthesis Using the
'Capillary Bond—, Bowden, N., Choi, I. S., Grzybowski, B. and Whitesides, G. M., J. Am. Chem.
Soc., 1999, 121, 5373-5391.</th></tr><tr><td>652.</td><td>"Biospecific Binding of Carbonic Anhydrase to Mixed SAMs Presenting Benzenesulfonamide
Ligands: A Model System for Studying Lateral Steric Effects", Lahiri, J., Isaacs, L., Grzybowski, B.,
Carbeck, J. D. and Whitesides, G. M., Langmuir, 1999, 15, 7186-7198.</td></tr><tr><td>651.</td><td>"Making Honeycomb Microcomposites by Soft Lithography", Xu, B., Arias, F. and Whitesides, G.
M., Adv. Mater., 1999, 11, 492-495.</td></tr><tr><td>650.</td><td>"The Interaction of Proteins and Cells with Self-Assembled Monolayers of Alkanethiolates on Gold
and Silver", Ostuni, E., Yan, L. and Whitesides, G. M., ColloidSurfaces 8, 1999, 15, 3-30.</td></tr><tr><td>649.</td><td>"Biological Surface Engineering: A Simple System for Cell Pattern Formation", Zhang, S., Yan, L.,
Altman, M., Lassie, M., Nugent, H., Frankel, F., Lauffenburger, D. A., Whitesides, G. M. and Rich,
A., Biomater., 1999, 1213-1220.</td></tr><tr><td>648.</td><td>"Patterning Electroluminescent Materials at Feature Sizes as Small as 5 pm Using Elastomeric
Membranes as Masks for Dry Lift-Ofr, Duffy, D. C., Jackman, R. J., Vaeth, K. M., Jensen, K. F.
and Whitesides, G. M., Adv. Mater., 1999, 11, 546-552.</td></tr><tr><td>647.</td><td>"Unconventional Methods for Fabricating and Patterning Nanostructures", Xia, Y., Rogers, J. A.,
Paul,  K. E. and Whitesides, G. M., Chem. Rev., 1999, 99, 1823-1848.</td></tr><tr><td>646.</td><td>"Predicting Crystalline Packing Arrangements of Molecules That Form Hydrogen-Bonded Tapes",
Chin, D. N., Palmore, G. T. R. and Whitesides, G. M., J. Am. Chem. Soc, 1999, 121, 2115.2122.</td></tr><tr><td>645.</td><td>"Patterning Ligands on Reactive SAMs by Microcontact Printing", Lahiri, 3., Ostuni, E. and
Whitesides, G. M., Langmuir, 1999, 15, 2055-2060.</td></tr><tr><td>644.</td><td>"A Strategy for the Generation of Surfaces Presenting Ligands for Studies of Binding Based on an
Active Ester as a Common Reactive Intermediate: A Surface Plasmon Resonance Study", Lahiri, J.,
Isaacs, L., Tien, J. and Whitesides, G. M., Anal. Chem., 1999, 71, 777-790.</td></tr><tr><td>643.</td><td>"Microcontact Printing of Alkanephosphonic Acids on Aluminum: Pattern Transfer by Wet Chemical
Etching", Goetting, L. B., Deng, T. and Whitesides, G. M., Langmuir, 1999, 15, 1182-1191.</td></tr><tr><td>642.</td><td>"Fabrication of Arrays of Schottky Diodes Using Microtransfer Molding", Hu, 3., Deng, T., Beck, R.
G., Westervelt, R. M. and Whitesides, G. M., Sensors and Actuators A: Physical, 1999, 75, 65-69.</td></tr><tr><td>641.</td><td>"Microfabrication of Half-Wave Rectifier Circuits Using Soft Lithography", Deng, T., Goetting, L. B.,
Hu, J. and Whitesides, G. M., Sensors andActuators A: Physical, 1999, 75, 60-64.</td></tr><tr><td>640.</td><td>"Self-Assembly of Hydrogen-Bonded Polymeric Rods Based on the Cyanuric AcidoMelamine
Lattice", Choi, I. S., Li, X., Simanek, E. E., Akaba, R. and Whitesides, G. M., Chem. Mat., 1999, 11,
684-690. </td></tr><tr><td>639.</td><td>"Beam Redirection and Frequency Filtering with Transparent Elastomeric Diffractive Elements",
Grzybowski, B. A., Qin, D. and Whitesides, G. M., Optics Lett, 1999, 38, 2997-3002.</td></tr><tr><td>638.</td><td>'Three-Dimensional Metallic Microstructures Fabricated by Soft Lithography and
Microelectrodeposition", Jackman, R. J., Brittain, S. T., Adams, A., Wu, H., Prentiss, M. G.,
Whitesides, S. and Whitesides, G. M., Langmuir; 1999, 15, 826-836.</td></tr><tr><td>637.</td><td>"Patterning Thin Films of Poly(ethylene imine) on a Reactive SAM Using Microcontact Printing",
Yan, L., Huck, W. T. S., Zhao, X.-M. and Whitesides, G. M., Langmuir; 1999, 15, 1208-1214.</td></tr><tr><td>636.</td><td>"Control of Crystal Nucleation by Patterned Self-Assembled Monolayers", Aizenberg, J., Black, A. J.
and Whitesides, G. M., Nature, 1999, 398, 495-498.</td></tr><tr><td>635. </td><td>"Fabrication of Liquid-Core Waveguides by Soft Lithography", Schueller, O. 3. A., Zhao, X.-M.,</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

Whitesides, G. M., Smith, S. P. and Prentiss, M., Adv. Mater., 1999, 11, 37-41.

<table><tr><th></th><th>Whitesides, G. M., Smith, S. P. Prentiss, M., Adv. Mater., 1999, 11, 37-41.</th></tr><tr><td>634.</td><td>"Micropattemed Surfaces for Control of Cell Shape, Position, and Function", Chen, C. S., Mrksich,
M., Huang, S., Whitesides, G. M. and Ingber, D. E., Biotech. Frog, 1999, 14, 356.363.</td></tr><tr><td>633.</td><td>"Fabrication of Glassy Carbon Microstructures by Soft Lithography", Schueller, O. 3. A., Brittain, S.
T. and Whitesides, G. M., Sensors andActuators A: Physical, 1999, 72, 125-139.</td></tr><tr><td>632.</td><td>"Reconfigurable Diffraction Gratings Based on Elastomeric Microfluidic Devices", Schueller, O. J.
A., Duffy, D. C., Rogers, J. A., Brittain, S. T. and Whitesides, G. M., Sensors and Actuators A;
Physical, 1999, 78, 149-159.</td></tr><tr><td>631.</td><td>"Shape-Selective Recognition and Self-Assembly of mm-Scale Components", Choi, I. S., Bowden,
N. and Whitesides, G. M., J. Am. Chem Soc., 1999, 121, 1754-1755.</td></tr><tr><td>630.</td><td>"Self-Assembling Systems on Scales from Nanometers to Millimeters: Design and Discovery",
Isaacs, L., Chin, D. N., Bowden, N., Xia, Y. and Whitesides, G. M., in Supramolecular Materials
and Technologies, D. N. Reinhoudt, Ed., John Wiley &amp; Sons Ltd.,  New York, 1999, 1-46.</td></tr><tr><td>629.</td><td>"Strategies for the Design and Assembly of Hydrogen-bonded Aggregates in the Solid State",
Chin, D. N., Zerkowski, J. A., MacDonald, J. C. and Whitesides, G. M., in Organised Molecular
Assemblies in the Molecular Solid State, J. K. Whitesell, Ed., Wiley and Sons, London (Chichester),
1999, 185.253.</td></tr><tr><td>628.</td><td>"Self-Assembly and Self-Assembled Monolayers in Micro- and Nanofabrication", Wilbur, J. L. and
Whitesides, G. M., in Nanotechnology, G. Timp, Ed., Springer-Verlag, New York, 1999,331-369.</td></tr><tr><td>627.</td><td>Self-Assembled "Using Surface Plasmon Resonance to Study the Binding of Vancomycin and Its Dimer to
Monolayers Presenting D-Ala-D-Ala", Rao, 3., Yan, L., Xu, B. and Whitesides, G. M., J.
Am. Chem. Soc., 1999, 121, 2629-2630.</td></tr><tr><td>626.</td><td>"Hierarchically Ordered Oxides", Yang, P., Deng, T., Zhao, D., Feng, P., Pine, D., Chmelka, B. F.,
Whitesides, G. M. and Stucky, G. D., Science, 1998, 282, 2244-2246.</td></tr><tr><td>625.</td><td>Direct-Write "Generation of Micrometer-Sized Patterns for Microanalytical Applications Using a Laser
Method and Microcontact Printing", Grzybowski, 8. A., Haag, R., Bowden, N. and
Whitesides, G. M., Anal. Chem., 1998, 70, 4645-4652.</td></tr><tr><td>624.</td><td>"Maskless Lithography: Embossed Photoresist as its Own Optical Element", Paul, K. E., Breen, T.
L., Aizenberg, J. and Whitesides, G. M., App!. Phys. Left, 1998, 73, 2893-2895.</td></tr><tr><td>623.</td><td>"Using Self-Assembled Monolayers to Pattern ECM Proteins and Cells on Substrates", Chen, C. S.,
Ostuni, E., Whitesides, G. M. and Ingber, D. E., in Methods in Molecular Biology: Extracellular
Matrix Protocols, C. Streuli, Ed., Humana Press, Totowa, NJ, 1998, 209-219.</td></tr><tr><td>622.</td><td>"Crystallization of Millimeter-Scale Objects with Use of Capillary Forces", Tien, J., Breen, T. L and
Whitesides, G. M., J. Am. Chem. Soc., 1998, 120, 12670-12671.</td></tr><tr><td>621.</td><td>"Rapid Prototyping of Microfluidic Systems in Poly(dimethylsiloxane)", Duffy, D. C., McDonald, J.
C., Schueller, O. J. A. and Whitesides, G. M., Anal. Chem., 1998, 70, 4974-4984.</td></tr><tr><td>620.</td><td>"Three-Dimensional Mesoscale Self-Assembly", Huck, W. T. S., Tien, J. and Whitesides, G. M., J.
Am. Chem. Soc., 1998, 120, 8267.8268.</td></tr><tr><td>619.</td><td>"Controlling Local Disorder in Self-Assembled Monolayers by Patterning the Topology of Their
Metallic Supports", Aizenberg, J., Black, A. J. and Whitesides, G. M., Nature, 1998, 394, 868-871.</td></tr><tr><td>618.</td><td>"Patterning a Preformed, Reactive SAM Using Microcontact Printing", Yan, L., Zhao, X.-M. and
Whitesides, G. M., J. Am. (hem. Soc., 1998, 120, 6179-6180.</td></tr><tr><td>617.</td><td>"Placeholder-No publication with this call number",,, 1998.,, 1998.</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

<table><tr><th>616.</th><th>"Spontaneous Formation of Ordered Structures in Thin Films of Metals Supported on an
Elastomeric Polymer", Bowden, N., Brittain, S., Evans, A. G., Hutchinson, 3. W. and Whitesides, G.
M.,  Nature,1998,393, 146-149. </th></tr><tr><td>615.</td><td>"Correlation Between the Charge of Proteins in Solution and in the Gas Phase Investigated by
Protein Charge Ladders, Capillary Electrophoresis, and Electrospray Ionization Mass
Spectrometry", Carbeck, 3. 0., Severs, J. C., Gao, J., Wu, Q., Smith, R. D. and Whitesides, G. M.,
J. Phys. Chem. 8, 1998,102,10596-10601.</td></tr><tr><td>614.</td><td>"A Trivalent System from VancomycinoD-Ala-D-Ala with Higher Affinity Than AvidinoBiotin", Rao,
J., Lahiri, J., Isaacs, L., Weis, R. M. and Whitesides, G. M., Science,  1998,280,708-711.</td></tr><tr><td>613.</td><td>"Design and Fabrication of Topologically Complex, Three-Dimensional Microstructures", Jackman,
R. J., Brittain, S. T., Adams, A., Prentiss, M. G. and Whitesides, G. M., Science,1998, 280,  2089-
2091. </td></tr><tr><td>612.</td><td>"Fabricating Large Arrays of Microwells with Arbitrary Dimensions and Filling Them Using
Discontinuous Dewetting", Jackman, R. J., Duffy, D. C., Ostuni, E., Willmore, N. D. and
Whitesides, G. M., Anal. Chem.,1998, 70,  2280-2287. </td></tr><tr><td>611.</td><td>"Alkanethiol Self-Assembled Monolayers as the Dielectric of Capacitors with Nanoscale Thickness",
Rampi, M. A., Schueller, O. 3. A. and Whitesides, G. M., Appl. Phys. Lett, 1998,  72,1781-1783.</td></tr><tr><td>610.</td><td>"The Adhesion Energy between Polymer Thin Films and Self-Assembled Monolayers", Zhuk, A. V.,
Evans, A. G., Hutchinson, 3. W. and Whitesides, G. M., J. Mater. Res., 1998,13, 3555.3564. </td></tr><tr><td>609.</td><td>"Soft lithography and microfabrication", Brittain, S., Paul, K., Zhao, X.-M. and Whitesides, G.,
Physics World, 1998,11,31-36.</td></tr><tr><td>608.</td><td>"Regulation of Protrusion Shape and Adhesion to the Substratum During Chemotactic Responses
of Mammalian Carcinoma Cells", Bailly, M., Yan, L., Whitesides, G. M., Condeelis, 3. S. and Segall,
3. E., Exp. Cell Res, 1998,241,285-299.</td></tr><tr><td>607.</td><td>'The Use of Soft Lithography to Fabricate Arrays of Schottky Diodes", Flu, J., Beck, R. G.,
Westervelt, R. M. and Whitesides, G. M., Adv. Mater., 1998,10, 574-577. </td></tr><tr><td>606.</td><td>"Studying How Different Terminal Groups Change the Motion of H2NSO2C6H4CONH(EG)3R When
Bound to the Active Site of Human Carbonic Anhydrase II", Chin, D. N., Lau, A. Y. and Whitesides,
G. M., J. Org. Chem., 1998,63,938-945.</td></tr><tr><td>605.</td><td>'Thermally-Actuated Reflection Mode Asymmetric Fabry-Perot Modulator Utilizing a Thin
Transparent Elastomeric Film", Rogers, J. A., Schueller, O. J. A. and Whitesides, G. M., Appl. Phys.
Lett,1998, 72,  1951-1953. </td></tr><tr><td>604.</td><td>"Soft Lithography", Xia, Y. and Whitesides, G. M., Anna. Rev. Mater. 5d., 1998,  28,  153-184. </td></tr><tr><td>603.</td><td>"Protein Charge Ladders, Capillary Electrophoresis, and the Role of Electrostatics in Biomolecular
Recognition", Carbeck, J. D., Colton, I. J., Gao, J. and Whitesides, G. M., Acc. Chem. Res., 1998, 
31,  343-350. </td></tr><tr><td>602.</td><td>"Imaging profiles of light intensity in the near field: applications to phase-shift photolithography",
Aizenberg, J., Rogers, J. A., Paul, K. E. and Whitesides, G. M., Appl. Optics, 1998,37, 2145-2152. </td></tr><tr><td>601.</td><td>"Fabrication of microstructures using shrinkable polystyrene films", Zhao, X.-M., Xia, Y., Schueller,
O., Qin, D. and Whitesides, G. M., Sensors and Actuators A: Physical, 1998,65, 209.217. </td></tr><tr><td>600.</td><td>"Affinity capillary electrophoresis: A physical-organic tool for studying interactions in biomolecular
recognition", Colton, I. 3., Carbeck, J. D., Rao, J. and Whitesides, G. M., Electrophoresis,  1998, 
19,  367-382. </td></tr><tr><td>599. </td><td>"Molecular Conformation in Oligo(ethylene glycol)-Terminated Self-Assembled Monolayers on Gold
and Silver Surfaces Determines Their Ability to Resist Protein Adsorption", Harder, P., Grunze, M.,</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

Dahint, R., Whitesides, G. M. and Laibinis, P., J. Phys. Chem. 6 1998, 102, 426-436.

<table><tr><th>598.</th><th>"Polyvalent Interactions in Biological Systems: Implications for Design and Use of Multivalent
Ligands and Inhibitors", Mammen, M., Choi, S.-K. and Whitesides, G. M., Angew. Chem. Int. Ed.
Engl., 1998, 37, 2755-2794.</th></tr><tr><td>597.</td><td>"Fabrication of Three-Dimensional Microstructures by Electrochemically Welding Structures
Formed by Microcontact Printing on Planar and Curved Substrates", Jackman, R. J., Brittain, S. T.
and Whitesides, G. M., J. MEMS, 1998, 7, 261-266.</td></tr><tr><td>596.</td><td>"Generating -90 nanometer features using near-field contact-mode photolithography with an
elastomeric phase mask", Rogers, J. A., Paul, K. E., Jackman, R. J. and Whitesides, G. M., J. ✓ac. 
Sci. Technol. B, 1998, 16, 59-68.</td></tr><tr><td>595.</td><td>"Using Mixed Self-Assembled Monolayers Presenting RGD and (EG)3OH Groups To Characterize
Long-Term Attachment of Bovine Capillary Endothelial Cells to Surfaces", Roberts, C., Chen, C. S.,
Mrksich, M., Martichonok, V., Ingber, D. E. and Whitesides, G. M., J. Am. Chem. Sac:, 1998, 120,
6548-6555. </td></tr><tr><td>594. </td><td>"Self-Assembly of an Operating Electrical Circuit Based on Shape Complementarity and the
Hydrophobic Effect", Terfort, A. and Whitesides, G. M., Adv. Mater., 1998, 10, 470.473.</td></tr><tr><td>593. </td><td>"Estimating the Entropic Cost of Self-Assembly of Multipartide Hydrogen-Bonded Aggregates
Based on the Cyanuric AcidoMelamine Lattice", Mammen, M., Shakhnovich, E. I., Deutch, J. M.
and Whitesides, G. M., J. Org. Chem., 1998, 63, 3821.3830.</td></tr><tr><td>592.</td><td>"Use of Electroless Silver as the Substrate in Microcontact Printing of Alkanethiols, and Its
Application in Microfabrication", Xia, Y., Venkateswaran, N., Qin, D., Tien, J. and Whitesides, G.
M., Langmuir, 1998, 14, 363-371.</td></tr><tr><td>591. </td><td>"Soft Lithography", Xia, Y. and Whitesides, G. M., Angew. Chem. Int. Ed. Engl., 1998, 37, 550-
575. </td></tr><tr><td>590. </td><td>"Microcontact Printing of SAMs", Tien, J., Xia, Y. and Whitesides, G. M., in Thin Films, A. Ulman,
Ed., Academic Press, New York 1998, 24, 227-253.</td></tr><tr><td>589. </td><td>"Quantifying distortions In soft lithography", Rogers, 3. A., Paul, K. E. and Whitesides, G. M., J.
✓ac.  Sci. Technol. B, 1998, 16, 88-97.</td></tr><tr><td>588. </td><td>"Phase separation of ultrathin polymer-blend films on patterned substrates", Karim, A., Douglas,
3. F., Lee, B. P., Glotzer, S. C., Rogers, 3. A., Jackman, R. 3., Amis, E. J. and Whitesides, G. M.,
Phys. Rev. E., 1998, 57, R6273-R6276.</td></tr><tr><td>587.</td><td>"Patterning of a polysiloxane precursor to silicate glasses by microcontact printing", Marzolin, C.,
Terfort, A., Tien, J. and Whitesides, G. M., Thin SolidFilms, 1998, 315, 9.12.</td></tr><tr><td>586.</td><td>"Fabrication of Glass Microstructures by Micro-Molding of Sol-Gel Precursors", Marzolin, C., Smith,
S. P., Prentiss, M. and Whitesides, G. M., Adv. Mater., 1998, 10, 571-574.</td></tr><tr><td>585.</td><td>"Using a Convenient, Quantitative Model for Torsional Entropy To Establish Qualitative Trends for
Molecular Processes That Restrict Conformational Freedom", Mammen, M., Shakhnovich, E. I. and
Whitesides, G. M., J. Org. Chem., 1998, 63, 3168-3175.</td></tr><tr><td>584.</td><td>"Affinity Capillary Electrophoresis: Using Capillary Electrophoresis to Study the Interactions of
Proteins with Ligands", Gao, J., Mrksich, M., Mammen, M. and Whitesides, G. M., in High
Performance Capillary Electrophoresis: Theory, Techniques, and Applications, M. G. Khaledi, Ed.,
John Wiley &amp; Sons, Inc., New York, 1998, 146 947-972.</td></tr><tr><td>583.</td><td>"Photolithography with transparent reflective photomasks", Qin, D., Xia, Y., Black, A. J. and
Whitesides, G. M., J. ✓ac.  Set Technol. B, 1998, 16, 98-103.</td></tr><tr><td>582. </td><td>"Effect of Surface Wettability on the Adsorption of Proteins and Detergents", Sigal, G. B., Mrksich,</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

M. and Whitesides, G. M., J. Am. Chem. Soc, 1998, 120, 3464-3473.

<table><tr><th>581.</th><th>"Microfabrication, Microstructures and Microsystems", Qin, D., Xia, Y., Rogers, J. A., Jackman, R.
3., Zhao, X.-M. and Whitesides, G. M., in Microsystem Technology in Chemistry and Life Sciences,
A. Manz and H. Becker, Eds., Springer-Verlag, Berlin, 1998, .194, 1-20.</th></tr><tr><td>580.</td><td>"A methanol/dioxygen biofuel cell that uses NAD+-dependent dehydrogenases as catalysts:
application of an electro-enzymatic method to regenerate nicotinamide adenine dinudeotide at
low overpotentials", Palmore, G. T. R., Bertschy, H., Bergen, S. H. and Whitesides, G. M., J.
Electroanal. Chem., 1998, 443, 155-161.</td></tr><tr><td>579.</td><td>"On the Surface of Things: Images of the Extraordinary in Science", Frankel, F. and Whitesides, G.
M., Chronkle Books, SanFrancisco, 1997.</td></tr><tr><td>578.</td><td>"Selective Deposition of Conducting Polymers on Hydroxyl-Terminated Surfaces with Printed
Monolayers of Alkylsiloxanes as Templates", Huang, Z., Wang, P.-C., MacDiarmid, A. G., Xia, Y.
and Whitesides, G. M., Langmuir, 1997, 13, 6480-6484.</td></tr><tr><td>577.</td><td>"Microfabrication Through Electrostatic Self-Assembly", Tien, 3., Terfort, A. and Whitesides, G. M.,
Langmuir, 1997, 13, 5349.5355.</td></tr><tr><td>576.</td><td>"Tight Binding of a Dimeric Derivative of Vancomycin with Dimeric L-Lys-D-Ala-D-Ala", Rao, J. and
Whitesides, G. M., J. Am. Chen. Soc., 1997, 119, 10286-10290.</td></tr><tr><td>575.</td><td>"Using Capillary Electrophoresis to Study the Electrostatic Interactions Involved in the Association
of D-Ala-D-Ala with Vancomycin", Rao, J., Cotton, I. 3. and Whitesides, G. M., J. Am. Chem. Soc.,
1997, 119, 9336-9340.</td></tr><tr><td>574.</td><td>"Geometric Control of Cell Life and Death", Chen, C. S., Mrksich, M., Huang, S., Whitesides, G. M.
and Ingber, D. E., Science, 1997, 276, 1425-1428.</td></tr><tr><td>573.</td><td>"Demonstration of waveguide couplers fabricated using  microtransfer molding", Zhao, X.-M.,
Smith, S. P., Waldman, S. J., Whitesides, G. M. and Prentiss, M., Appl. Phys. Lett, 1997, 71,
1017-1019. </td></tr><tr><td>572.</td><td>"Soft Lithographic Methods for Nanofabrication", Zhao, X.-M., Younan, X. and Whitesides, G. M.,
J. Mat Chem, 1997, 7, 1069-1074.</td></tr><tr><td>571.</td><td>"Fabrication and Characterization of Glassy Carbon MEMS", Schueller, O. J. A., Brittain, S. T.,
Marzolin, C. and Whitesides, G. M., Chem. Mat, 1997, 9, 1399-1406.</td></tr><tr><td>570.</td><td>"Using Microcontact Printing to Fabricate Microcoils on Capillaries for High Resolution Proton
Nuclear Magnetic Resonance on Nanoliter Volumes", Rogers, 3. A., Jackman, R. 3., Whitesides, G.
M., Olson, D. L. and Sweedler, J. V., Appl. Phys. Lett., 1997, 70, 2464-2466.</td></tr><tr><td>569.</td><td>"Microscopic patterning of oriented mesocopic silica through guided growth", Trau, M., Yao, N.,
Kim, E., Xia, Y., Whitesides, G. M. and Aksay, I. A., Nature, 1997, 390, 674-676.</td></tr><tr><td>568.</td><td>"Solvent-Assisted Microcontact Molding: A Convenient Method for Fabricating Three-Dimensional
Structures on Surfaces of Polymers", Kim, E., Xia, Y., Zhao, X.-M. and Whitesides, G. M., Adv.
Mater., 1997, 9, 651.654.</td></tr><tr><td>567.</td><td>"Formation of Protein Charge Ladders by Acylation of Amino Groups on Proteins", Colton, I. J.,
Anderson, J. R., Gao, 3., Chapman, R. G., Isaacs, L. and Whitesides, G. M., J. Am. Chem. Soc.,
1997, 119, 12701.12709.</td></tr><tr><td>566.</td><td>"Formation and Reaction of Interchain Carboxylic Anhydride Groups on Self-Assembled
Monolayers on Gold", Yan, L., Marzolin, C., Terfort, A. and Whitesides, G. M., Langmuir, 1997, 13,
6704-6712. </td></tr><tr><td>565. </td><td>"Using Microcontact Printing to Pattern the Attachment of Mammalian Cells to Self-Assembled
Monolayers of Alkanethiolates on Transparent Films of Gold and Silver", Mrksich, M., Dike, L. E.,</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

Tien, J., Ingber, D. E. and Whitesides, G. M., Exp. Cell Res., 1997, 235, 305-313.

<table><tr><th>564.</th><th>"Elastomeric Light Valves", Qin, D., Xia, Y. and Whitesides, G. M., Adv. Mater., 1997, 9, 407-410.</th></tr><tr><td>563.</td><td>"Imaging the irradiance distribution in the optical near field", Aizenberg, J., Rogers, J. A., Paul, K.
E. and Whitesides, G. M., Appl. Phys. Lett, 1997, 71, 3773.3775.</td></tr><tr><td>562.</td><td>"Nanometer scale patterning and pattern transfer on amorphous Si, crystalline Si, and SiO2
surfaces using self-assembled monolayers", Wang, D., Thomas, S. G., Wang, K. L., Xia, Y. and
Whitesides, G. M., Appl. Phys. Lett, 1997, 70, 1593-1595.</td></tr><tr><td>561.</td><td>"Using an elastomeric phase mask for sub-100 nm photolithography in the optical near field",
Rogers, ). A., Paul, K. E., Jackman, R. ). and Whitesides, G. M., Appl. Phys. Lett.,1997, 70, 2658-
2660. </td></tr><tr><td>560.</td><td>"Fabrication of Glassy Carbon Microstructures by Pyrolysis of Microfabricated Polymeric
Precursors", Schueller, O. 3. A., Brittain, S. T. and Whitesides, G. M., Adv. Mater., 1997, 9, 477-
480. </td></tr><tr><td>559.</td><td>"Representing Primary Electrophoretic Data in the 1/Time Domain: Comparison to
Representations in the Time Domain", Mammen, M., Colton, I. 3., Carbeck, 3., Bradley, R. and
Whitesides, G. M., Anal. Chem., 1997, 69, 2165-2170.</td></tr><tr><td>558.</td><td>'Three-dimensional self-assembly of millimetre-scale components", Terfort, A., Bowden, N. and
Whitesides, G. M., Nature, 1997, 386, 162.164.</td></tr><tr><td>557.</td><td>"Self-Assembly of Mesoscale Objects into Ordered Two-Dimensional Arrays", Bowden, N., Terfort,
A., Carbedc, 3. and Whitesides, G. M., Science, 1997, 276, 233-235.</td></tr><tr><td>556.</td><td>"Treating Electrostatic Shielding at the Surface of Silica as Discrete SiloxideoCation Interactions",
Mammen, M., Carbeck, J., Simanek, E. E. and Whitesides, G. M., 1 Am. Chem. Soc., 1997, 119,
3469-3476. </td></tr><tr><td>555.</td><td>"Using Self-Assembled Monolayers That Present Oligo(ethylene glycol) Groups To Control the
Interactions of Proteins with Surfaces", Mrksich, M. and Whitesides, G. M., in Poly(ethylene glycol)
Chemistry and Biological Applications, J. M. Harris and S. Zalipsky, Eds., American Chemical
Society, Washington, DC 1997, 680, 361-373.</td></tr><tr><td>554.</td><td>"Using Surface Plasmon Resonance Spectroscopy to Measure the Acsnriation of Detergents with
Self-Assembled Monolayers of Hexadecanethiolate on Gold", Sigal, G. B., Mrksich, M. and
Whitesides, G. M., Langmuir, 1997, 13, 2749.2755.</td></tr><tr><td>553.</td><td>"Generation and In Situ Evaluation of Libraries of Poly(Acrylic Add) Presenting Sialosides as Side
Chains as Polyvalent Inhibitors of Influenza-Mediated Hemagglutination", Choi, S.-K., Mammen,
M. and Whitesides, G. M., J. Am. Chem. Soc., 1997, 119, 4103.4111.</td></tr><tr><td>552.</td><td>"Using Soft Lithography to Fabricate GaAs/AlGaAs Heterostructure Field Effect Transistors", Hu, J.,
Beck, R. G., Deng, T., Westervelt, R. M., Maranowski, K. D., Gossard, A. C. and Whitesides, G. M.,
Appl Phys. Lett, 1997, 71, 2020.2022.</td></tr><tr><td>551.</td><td>"On-Line Detection of Nonspecific Protein Adsorption at Artificial Surfaces", Seigel, R. R., Harder,
P., Dahint, R., Grunze, M., Josse, F., Mrksich, M. and Whitesides, G. M., Anal. Chem., 1997, 69,
3321-3328. </td></tr><tr><td>550.</td><td>"Fabrication and Characterization of a Concentric, Cylindrical Microtransformer", Jackman, R. J.,
Rogers, 3. A. and Whitesides, G. M., IEEE Trans. Magnetics, 1997, 33, 2501-2503.</td></tr><tr><td>549.</td><td>"Extending Microcontact Printing as a Microlithographic Technique", Xia, Y. and Whitesides, G. M.,
Langmuir, 1997, 13, 2059-2067.</td></tr><tr><td>548. </td><td>Free-Standing "Microcontact Printing and Electroplating on Curved Substrates: A Means for Produdng
Three-Dimensional Microstructures with Possible Applications Ranging from Micro-Coil</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

<table><tr><th></th><th>Springs to Coronary Stents", Rogers, J. A., Jackman, R. J. and Whitesides, G. M., Adv. Mater.,
1997, 9, 475.477.</th></tr><tr><td>547.</td><td>"Constructing Single- and Multiple-Helical Microcoils and Characterizing Their Performance as
Components of Microinductors and Microelectromagnets", Rogers, J. A., Jackman, R. 3. and
Whitesides, G. M., .1. HEMS, 1997, 6, 184.192.</td></tr><tr><td>546.</td><td>"Benzimidazolene-2-thiones: A New Class of Molecules for the Engineering of Molecular Tapes in
the Organic Solid State", Simanek, E. E., Tsoi, A., Wang, C. C. C., Whitesides, G. M., McBride, M.
and Palmore, T. R., Chem. Mat, 1997, 9, 1954-1961.</td></tr><tr><td>545.</td><td>"Nanostructure fabrication in silicon using cesium to pattern a self-assembled monolayer",
Younkin, R., Berggren, K. K., Johnson, K. S., Prentiss, M., Ralph, D. C. and Whitesides, G. M.,
Appl. Phys. Lett, 1997, 71, 1261-1263.</td></tr><tr><td>544.</td><td>"A miniaturized arrayed assay format for detecting small molecule-protein interactions in cells",
You, A. 3., Jackman, R. I., Whitesides, G. M. and Schreiber, S. L., Chem. Biol., 1997, 4, 969-975.</td></tr><tr><td>543.</td><td>"Fabrication of Polymeric Microstructures With High Aspect Ratios Using Shrinkable Polystyrene
Films", Zhao, X.-M., Xia, Y., Qin, D. and Whitesides, G. M., Adv. Mater., 1997, 9, 251-254.</td></tr><tr><td>542.</td><td>"Using Protein Charge Ladders to Estimate the Effective Charges and Molecular Weights of
Proteins in Solution", Gao, J. and Whitesides, G. M., Anal. Chem., 1997, 69, 575-580.</td></tr><tr><td>541.</td><td>"Observation of Diastereomers of the Hydrogen-Bonded Aggregate Hub(M)3o3CA Using 1H
Nuclear Magnetic Resonance Spectroscopy When CA Is an Optically-Active Isocyanuric Acid",
Simanek, E. E., Qiao, S., Choi, I. S. and Whitesides, G. M.,1. Org. Chem., 1997, 62, 2619.2621.</td></tr><tr><td>540.</td><td>"Self-Assembly of Zinc Porphyrins around the Periphery of Hydrogen-Bonded Aggregates that
Bear Imidazole Groups", Simanek, E. E., <change><s>Isaacs,</s></change> L., Li, X., Wang, C. C. C. and Whitesides, G. M., 2
Org. Chetn., 1997, 62, 8994.9000.</td></tr><tr><td>539.</td><td>"Replica Molding Using Polymeric Materials: A Practical Step Toward Nanomanufacturing", Xia, Y.,
McClelland, J. J., Gupta, R., Qin, D., Zhao, X.-M., Sohn, L. L., Celotta, R. 3. and Whitesides, G. M.,
Adv. Mater., 1997, 9, 147-149.</td></tr><tr><td>538.</td><td>"Demonstration of a Nanolithographic System Using a Self-Assembled Monolayer Resist for
Neutral Atomic Cesium", Berggren, K. K., Youkin, R., Cheung, E., Prentiss, M., Black, A. J.,
Whitesides, G. M., Ralph, D. C., Black, C. T. and Tinkham, M., Adv. Mater., 1997, 9, 52-55.</td></tr><tr><td>537.</td><td>"Using Self-Assembled Monolayers to Study the Interactions of Man-Made Materials with
Proteins", Merritt, M. V., Mrksich, M. and Whitesides, G. M., in Principles of Tissue Engineering, R.
P. Lanza, W. L. Chick and R. Langer, Eds., R. G. Landes Co., Austin, TX, 1997, 211-223.</td></tr><tr><td>536.</td><td>"Micro- and Nanofabrication Techniques Based on Self-Assembled Monolayers", Nealey, P. F.,
Black, A. J., Wilbur, J. L. and Whitesides, G. M., in Molecular Electronics, 3. Jortner and M. Ratner,
Eds., Blackwell Science, Oxford, 1997 343-367.</td></tr><tr><td>535.</td><td>"Wave-front Engineering by Use of Transparent Elastomeric Optical Elements", Rogers, 3. A.,
Schueller, 0. J. A., Marzolin, C. and Whitesides, G. M., Appl. Optics, 1997, 36, 5792-5795.</td></tr><tr><td>534.</td><td>"Studies on a-sialylation using slaty' donors with an auxiliary 3-thiophenyl group", Martichonok, V.
and Whitesides, G. M., Carbohyd. Res., 1997, 302, 123.129.</td></tr><tr><td>533.</td><td>"Polymorphic Packing Arrangements in a Class of Engineered Organic Crystals", Zerkowski, J. A.,
MacDonald, J. C. and Whitesides, G. M., Chem. Mat, 1997, 9, 1933-1941.</td></tr><tr><td>532.</td><td>"Hydrogen-Bonded Tapes Based on Symmetrically Substituted Diketopiperazines: A Robust
Structural Motif for the Engineering of Molecular Solids", Palacin, S., Chin, D. N., Simanek, E. E.,
MacDonald, J. C., Whitesides, G. M., McBride, M. T. and Palmore, G. T. R., J. Am. Chem. Soc.,
1997, 119, 11807-11816.</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

<table><tr><th>531.</th><th>"Using microcontact printing to generate amplitude photomasks on the surfaces of optical fibers:
A method for producing in-fiber gratings", Rogers, 3. A., Jackman, R. J., Whitesides, G. M.,
Wagner, J. L. and Vengsarkar, A., App/. Phys. Lett, 1997, 70, 7-9.</th></tr><tr><td>530.</td><td>"Self-assembled monolayers exposed by metastable argon and metastable helium for neutral
atom lithography and atomic beam imaging", Bard, A., Berggren, K. K., Wilbur, 3. L, Gillaspy, 3.
0., Rolston, S. L., McClelland, J. J., Phillips, W. D., Prentiss, M. and Whitesides, G. M., 1 Vac Sci.
Technol 8,1997, 15, 1805-1810.</td></tr><tr><td>529.</td><td>"Stimulation of Human Cytotoxic T Cells with HIV-Derived Peptides Presented by Recombinant
HLA-A2 Peptide Complexes", Walter, J. B., Brander, C., Mammen, M., Garboai, D., Kalams, S. A.,
Whitesides, G. M., Walker, B. and Eisen, H. N., Int. lmm., 1997, 9, 451-459.</td></tr><tr><td>528.</td><td>"Computations and IH NMR Spectroscopy of the Imide Region Can Distinguish Isomers of
Hydrogen-Bonded Aggregates", Chin, D. N., Simanek, E. E., U, X., Wazeer, M. I. M. and
Whitesides, G. M., J. Org. Chem., 1997, 62, 1891.1895.</td></tr><tr><td>527.</td><td>"Imbibition and Flow of Wetting Liquids in Noncircular Capillaries", Kim, E. and Whitesides, G. M.,
1 Phys. Chem., 1997, 101, 855.863.</td></tr><tr><td>526.</td><td>"Noncovalent Polycationic Coatings for Capillaries in Capillary Electrophoresis of Proteins",
Cordova, E., Gao, J. and Whitesides, G. M., Anal. Chem., 1997, 69, 1370-1379.</td></tr><tr><td>525.</td><td>Joseph-McCarthy, "Carbonic Anhydrase-Inhibitor Binding: From Solution to the Gas Phase",Wu, Q., Gao, J.,
D., Sigal, G. B., Bruce, J. E., Whitesides, G. M. and Smith, R. D., J. Am. Chem. Soc.,
1996, 119, 1157-1158.</td></tr><tr><td>524.</td><td>"Synthesis of a Phosphonate Analog of Sialic Acid (Neu5Ac) Using Indium-Mediated Allylation of
Unprotected Carbohydrates in Aqueous Media", Gao, J., Martichonok, V. and Whitesides, G. M., J.
Org. Chem., 1996, 61, 9538-9540.</td></tr><tr><td>523.</td><td>"Predicting the Relative Stabilities of Multi-particle Hydrogen-Bonded Aggregates Based on the
Number of Hydrogen Bonds and the Number of Particles, and Measuring These Stabilities with
Titrations Using Dimethylsulfoxide", Mammen, M., Simanek, E. E. and Whitesides, G. M., J. Am.
Chem. Soc., 1996, 118, 12614-12623.</td></tr><tr><td>522.</td><td>N-Substituted "Synthesis of C-5 Analogs of N-Acetylneuraminic Acid via Indium-mediated Allylation of
2-Amino-2-deoxymannoses", Choi, S.-K., Lee, S. and Whitesides, G. M., J. Org.
Chem., 1996, 61, 8739-8745.</td></tr><tr><td>521.</td><td>"Using Neutral Metastable Argon Atoms and Contamination Lithography to Form Nanostructures in
Silicon, Silicon Dioxide, and Gold", Johnson, K. S., Berggren, K. K., Black, A. J., Black, C. T., Chu,
A. P., Dekker, N. H., Ralph, D. C., Thywissen, 1 H., Youkin, R., Prentiss, M., Tinkham, M. and
Whitesides, G. M., App/. Phys. Lett, 1996, 69, 2773-2775.</td></tr><tr><td>520.</td><td>"Microcontact Printing with a Cylindrical Rolling Stamp: A Practical Step Toward Automatic
Manufacturing of Patterns with Submicrometer-Sized Features", Xia, Y., Qin, D. and Whitesides,
G. M., Adv. Mater., 1996, 8, 1015-1017.</td></tr><tr><td>519.</td><td>"Self-Assembled Monolayers and Lithography", Whitesides, G. M., Black, A. 3., Nealey, P. F. and
Wilbur, J. L., The Robert A. Welch Foundation 39th Conference on Chemical Research on
Nanophase Chemistry, Houston, TX, 1996, 109-121.</td></tr><tr><td>518.</td><td>"Fabrication of Micrometer-Scale Structures on GaAs and GaAs/AlGaAs Quantum Well Material
Using Microcontact Printing", Kim, E., Whitesides, G. M., Freiler, M. B., Levy, M., Lin, 3. L. and
Osgood, R. M., Nanotechnology, 1996, Z 266-269.</td></tr><tr><td>517.</td><td>"Cyanuric Acid and Melamine: A Platform for the Construction of Soluble Aggregates and
Self-Assembly Crystalline Materials", Simanek, E. E., Li, X., Choi, I. S. and Whitesides, G. M., in Templating,
and Self-Organization, J.-P. Sauvage and M. W. Hosseini, Eds., Elsevier Science, Oxford,
1996, 9, 595-621.</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

<table><tr><th>516.</th><th>"Pattern Transfer to Silicon by Microcontact Printing and RIE", Whidden, T. K., Ferry, D. K.,
Kozicki, M. N., Kim, E., Kumar, A., Wilbur, 3. L. and Whitesides, G. M., Nanotechnology,  1996, Z
447-451. </th></tr><tr><td>515.</td><td>"Microcontact Printing of Self-Assembled Monolayers: Applications in Microfabrication", Wilbur, J.
L., Kumar, A., Biebuyck, H. A., Kim, E. and Whitesides, G. M., Nanotechnology,1996, 7, 452.457.</td></tr><tr><td>514.</td><td>"Non-Photolithographic Methods for Fabrication of Elastomeric Stamps for Use in Microcontact
Printing", Xia, Y., Tien, J., Qin, D. and Whitesides, G. M., Langmuir,1996,12,4033-4038.</td></tr><tr><td>513.</td><td>"A New Strategy for Controlling the Size and Shape of Metallic Features Formed by Electroless
Deposition of Copper: Microcontact Printing of Catalysts on Oriented Polymers, Followed by
Thermal Shrinkage", Hidber, P. C., Nealey, P. F., Helbig, W. and Whitesides, G. M., Langmuir, 
1996,12,5209-5215.</td></tr><tr><td>512.</td><td>"Shadowed Sputtering of Gold on V-Shaped Microtrenches Etched in Silicon and Applications in
Microfabrication", Xia, Y. and Whitesides, G. M., Adv.  Mater:, 1996, 8, 765-768.</td></tr><tr><td>511.</td><td>"Elastomeric Binary Phase Gratings for Measuring Acceleration, Displacement, Strain and Stress",
Rogers, J. A., Qin, D., Schueller, 0. J. A. and Whitesides, G. M., Rev. Sd. Instrum., 1996, 67,
3310.3319. </td></tr><tr><td>510.</td><td>"A Practical Method for the Synthesis of a-Sialyl Glycosides", Martichonok, V. and Whitesides, G.
M.,  J. Am. Chem. Sac, 1996,118,8187-8191.</td></tr><tr><td>509.</td><td>"Functional Group Identification in Scanning Tunneling Microscopy of Molecular Adsorbates", Cyr,
D. M., Venkataraman, B., Flynn, G. W., Black, A. and Whitesides, G. M., J. Phys. Chem., 1996, 
100,  13747-13759. </td></tr><tr><td>508.</td><td>"Molecular Self-Assembly of Aliphatic Thiols on Gold Colloids", Weisbecker, C. S. and Whitesides,
G. M., Langmuir,  1996,12,3763.3772.</td></tr><tr><td>507.</td><td>"Microcontact Printing of Alkanethiols on Silver and Its Application in Microfabrication", Xia, Y.,
Kim, E. and Whitesides, G. M., J. Electrochem. Sac., 1996,143,1070-1079.</td></tr><tr><td>506.</td><td>"Controlling Cell Attachment on Contoured Surfaces with Self-Assembled Monolayers of
Alkanethiolates on Gold", Mrksich, M., Chen, C. S., Xia, Y., Dike, L. E., Ingber, D. E. and
Whitesides, G. M., Proc. Nat. Acad. Sci. USA, 1996,  93,  10775-10778. </td></tr><tr><td>505.</td><td>"Characterization of Hydrogen-bonded Aggregates in Chloroform by Electrospray Ionization Mass
Spectrometry", Cheng, X., Gao, Q., Smith, R. D., Simanek, E. E., Mammen, M. and Whitesides, G.
M.,  J. Org. Chem., 1996,  61,  2204-2206. </td></tr><tr><td>504.</td><td>"Complex Optical Surfaces by Replica Molding against Elastomeric Masters", Xia, Y., Kim, E., Zhao,
X.-M., Rogers, 3. A., Prentiss, M. and Whitesides, G. M., Science,1996,273,347-349.</td></tr><tr><td>503.</td><td>"Elastomeric Diffraction Gratings as Photothermal Detectors", Rogers, J. A., Jackman, R. 3.,
Schueller, 0. J. A. and Whitesides, G. M., Appt. Optics, 1996,35,6641-6647.</td></tr><tr><td>502.</td><td>"Micromolding in Capillaries: Applications in Materials Science", Kim, E., Xia, Y. and Whitesides, G.
M.,  J. Am. Chem. Soc., 1996, 1./8, 5722-5731.</td></tr><tr><td>501.</td><td>"Micromolding of Polymers in Capillaries: Applications in Microfabrication", Xia, Y., Kim, E. and
Whitesides, G. M., Chem. Mat, 1996,8,1558-1567.</td></tr><tr><td>500.</td><td>"Fabrication of Single-Mode Polymeric Waveguides Using Micromolding in Capillaries", Zhao, X.-
M., Stoddart, A., Smith, S. P., Kim, E., Xia, Y., Prentiss, M. and Whitesides, G. M., Adv. Mater.,
1996,8,420-424.</td></tr><tr><td>499.</td><td>"Elastomeric Optics", Wilbur, 3. L., Jackman, R. J., Whitesides, G. M., Cheng, E., Lee, L. and
Prentiss, M., Chem. Mat, 1996,8,1380-1385.</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

<table><tr><th>498.</th><th>"Pattern Transfer: Self-Assembled Monolayers as Ultrathin Resists", Xia, Y., Zhao, X.-M. and
Whitesides, G. M., Microelec. Eng., 1996, 32, 255.268.</th></tr><tr><td>497.</td><td>"Optically Controlled Collisions of Biological Objects to Evaluate Potent Polyvalent Inhibitors of
Virus-Cell Adhesion", Mammen, M., Helmerson, K., Kishore, R., Choi, 5.-K., Phillips, W. D. and
Whitesides, G. M., Chem. Blot, 1996, 3, 757-763.</td></tr><tr><td>496.</td><td>"Approaches to Synthesis Based on Non-Covalent Bonds", Whitesides, G. M., Simanek, E. E. and
Gorman, C. B., in NATO Advanced Study Institute on Chemical Synthesis: Gnosis to Prognosis, C.
Chatgilialoglu and V. Snieckus, Eds., Kluwer Academic Publishers, Dordrecht, 1996, 320, 565-588.</td></tr><tr><td>495.</td><td>"Rapid Prototyping of Complex Structures with Feature Sizes Larger than 20 pm", Qin, 0., Xia, Y.
and Whitesides, G. M., Adv. Mater., 1996, 8, 917-919.</td></tr><tr><td>494.</td><td>"Monomeric Inhibitors of Influenza Neuraminidase Enhance the Hemagglutination Inhibition
Activities of Polyacrylamides Presenting Multiple C-Sialoside Groups", Choi, S.-K., Mammen, M.
and Whitesides, G. M., Chem. Blot, 1996, 3, 97-104.</td></tr><tr><td>493.</td><td>"Benzenesulfonamide-Peptide Conjugates as Probes for Secondary Binding Sites Near the Active
Site of Carbonic Anhydrase", Sigal, G. B. and Whitesides, G. M., 8ioorg. &amp; Med. Chem. Lett,
1996, 6, 559.564.</td></tr><tr><td>492.</td><td>"Evaluating Electrostatic Contributions to Binding with the Use of Protein Charge Ladders", Gao,
3., Mammen, M. and Whitesides, G. M., Science, 1996, 272, 535-537.</td></tr><tr><td>491.</td><td>"Patterning with Magnetic Materials at the Micron Scale", Palacin, S., Hidber, P. C., Bourgoin, J.-
P., Miramond, C., Fermon, C. and Whitesides, G. M., Chem. Mat, 1996, 8, 1316.1325.</td></tr><tr><td>490.</td><td>"Two- and Three-Dimensional Crystallization of Polymeric Microspheres by Micromolding in
Capillaries", Kim, E., Xia, Y. and Whitesides, G. M., Adv. Mater., 1996, 8, 245-247.</td></tr><tr><td>489.</td><td>"Polyacrylamides Bearing Pendant a-Sialoside Groups Strongly Inhibit Agglutination of
Erythrocytes by Influenza Virus: The Strong Inhibition Reflects Enhanced Binding through
Cooperative Polyvalent Interactions", Sigal, G. B., Mammen, M., Dahmann, G. and Whitesides, G.
M., J. Am. Chem. Soc., 1996, 118, 3789-3800.</td></tr><tr><td>488.</td><td>"Screening Derivatized Peptide Libraries for Tight Binding Inhibitors to Carbonic Anhydrase II by
Electrospray Ionization-Mass Spectrometry", Gao, J., Cheng, X., Chen, R., Sigal, G. B., Bruce, J.
E., Schwartz, B. L., Hofstadler, S. A., Anderson, G. A., Smith, R. D. and Whitesides, G. M., J. Med.
Chem., 1996, 39, 1949-1955.</td></tr><tr><td>487.</td><td>"Stereoselective a-Sialylation with Sialyl Xanthate and Phenylsulfenyl Triflate (PST) as a
Promotor", Martichonok, V. and Whitesides, G. M., J. Org. Chem., 1996, 61, 1702.1706.</td></tr><tr><td>486.</td><td>"Microcontact Printing of Palladium Colloids: Micron-Scale Patterning by Electroless Deposition of
Copper, Hidber, P. C., Helbig, W., Kim, E. and Whitesides, G. M., Langmuir, 1996, 12, 1375-
1380. </td></tr><tr><td>485.</td><td>"Using Self-Assembled Monolayers to Understand the Interactions of Man-Made Surfaces with
Proteins and Cells", Mrksich, M. and Whitesides, G. M., Ann. Rev. 8iophys. Blomol. Struct., 1996,
25, 55-78.</td></tr><tr><td>484.</td><td>"Engineering the Solid State with 2-Benzimidazolones", Schwiebert, K. E., Chin, D. N., MacDonald,
J. C. and Whitesides, G. M., J. Am. Chem. Soc., 1996, 118, 4018-4029.</td></tr><tr><td>483.</td><td>"Contact Angles for Liquid Drops at a Model Heterogeneous Surface Consisting of Alternating and
Parallel Hydrophobic/Hydrophilic Strips", Drelich, J., Wilbur, J. L., Miller, J. D. and Whitesides, G.
M., Langmuir 1996, 12, 1913-1922.</td></tr><tr><td>482.</td><td>"Synthesis and Evaluation of Thioether-Based Tris-Melamines as Components of Self-Assembled
Aggregates Based on the CA-M Lattice", U, X., Chin, D. and Whitesides, G. M., J. Org. Chem.,
1996, 61, 1779.1786.</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

<table><tr><th>481.</th><th>"A Self-Assembled Monolayer for the Binding and Study of Histidine-Tagged Proteins by Surface
Plasmon Resonance", Sigal, G. B., Bamdad, C., Barberis, A., Strominger, J. and Whitesides, G. M.,
Anal. Chem., 1996, 64 490.497.</th></tr><tr><td>480.</td><td>"Platinum-Catalyzed Oxidations of Organic Compounds by Ferric Sulfate: Use of a Redox Fuel Cell
to Mediate Complete Oxidation of Ethylene Glycol by Dioxygen at 80°C", Gorman, C. B., Bergens,
S. H. and Whitesides, G. M., J. Catal., 1996,158,92-96.</td></tr><tr><td>479.</td><td>"Fabrication of Arrays of Channel Waveguides by Three-Dimensional Self-Assembly Using
Patterned Organic Monolayers as Templates", Kim, E., Whitesides, G. M., Lee, L. IC, Smith, S. P.
and Prentiss, M., Adv. Mat., 1996, 8, 139.142.</td></tr><tr><td>478.</td><td>"Using Two-Stage Chemical Amplification to Determine the Density of Defects in Self-Assembled
Monolayers of Alkanethiolates on Gold", Zhao, X.-M., Wilbur, 3. L. and Whitesides, G. M.,
Langmuir,  1996,12, 3257-3264. </td></tr><tr><td>477.</td><td>"Fabrication of Three-Dimensional Micro-Structures: Microtransfer Molding", Zhao, X.-M., Xia, Y.
and Whitesides, G. M., Adv. Mater., 1996,8,837-840.</td></tr><tr><td>476.</td><td>"Self-Assembled Monolayers of Alkanethiolates Presenting Tri(propylenesulfoxide) Groups Resist
the Adsorption of Protein", Deng, L., Mrksich, M. and Whitesides, G. M., J. Am. Chem. Sac, 1996, 
118,  5136.5137. </td></tr><tr><td>475.</td><td>"Microcontact Printing of Alkanethiols on Copper and Its Application in Microfabrication", Xia, Y.,
Kim, E., Mrksich, M. and Whitesides, G. M., Chem. Mat, 1996,8,601-603.</td></tr><tr><td>474.</td><td>"Holy Grails of Chemistry", Bard, A..1., Whitesides, G. M., Zare, R. N. and McLafferty, F. W., Acc. 
Chen.Res.,1995,28,91.</td></tr><tr><td>473.</td><td>"Formation of Polymer Microstructures by Selective Deposition of Polyion Multilayers using
Patterned SAMs as a Template", Hammond, P. T. and Whitesides, G. M., Macromolecules,  1995, 
28,  7569-71. </td></tr><tr><td>472.</td><td>"Reagents for Rapid Reduction of Disulfide Bonds", Singh, R., Lamoureux, G. V., Lees, W. 3. and
Whitesides, G. M., in Methods Enzymol.: Biothiols Part A, L. Packer, Ed., Academic Press, 1995, 
251,167-173. </td></tr><tr><td>471.</td><td>"A Selective Etching Solution for Use with Patterned Self-Assembled Monolayers of Alkanethiolates
on Gold, Silver and Copper", Xia, Y., Zhao, X.-M., Kim, E. and Whitesides, G. M., Chem. Mat,
1995, 7, 2332.2337.</td></tr><tr><td>470.</td><td>"Bio-Specific Adsorption of Carbonic Anhydrase to Self-Assembled Monolayers of Alkanethiolates
that Present Benzenesulfonamide Groups on Gold", Mrksich, M., Grunwell, J. R. and Whitesides,
G. M., J. Am. Chem. Soc., 1995,  11712009.12010.</td></tr><tr><td>469.</td><td>"Effective Inhibitors of Hemagglutination by Influenza Virus Synthesized from Polymers Having
Active Ester Groups. Insight into Mechanism of Inhibition", Mammen, M., Dahmann, G. and
Whitesides, G. M., J. Med. Chem., 1995,38,4179-4190.</td></tr><tr><td>468.</td><td>"Using Capillary Electrophoresis to Follow the Acetylation of the Amino Groups of Insulin and to
Estimate Their Basicities", Gao, J., Mrksich, M., Gomez, F. A. and Whitesides, G. M., Anal. Chem.,
1995, 67, 3093.3100.</td></tr><tr><td>467.</td><td>"Determination of the Binding of Ugands Containing the N-2,4-Dinitrophenyl Group to Bivalent
Monoclonal Rat Anti-DNP Antibody Using Affinity Capillary Electrophoresis", Mammen, M., Gomez,
F. A. and Whitesides, G. M., Anal. Chem.,  1995,  6Z3526-3535.</td></tr><tr><td>466.</td><td>"Microlithography by Using Neutral Metastable Atoms and Self-Assembled Monolayers", Berggren,
K. K., Bard, A., Wilbur, 3. L., Gillaspy, I. D., Helg, A. G., McClelland, 3. 3., Rolston, S. L., Phillips,
W. D., Prentiss, M. and Whitesides, G. M., Science,1995,269,1255-1257.</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

<table><tr><th>465.</th><th>"Polymer microstructures formed by moulding in capillaries", Kim, E., Xia, Y. and Whitesides, G.
M.,  Nature,1995,376, 581-584. </th></tr><tr><td>464.</td><td>"Fabrication of Submicron Features on Curved Substrates by Microcontact Printing", Jackman, R.,
Wilbur, 3. and Whitesides, G. M., Science,  1995,269,664-666.</td></tr><tr><td>463.</td><td>Thioacetyl-Containing "Self-Assembled Monolayers and Multilayers of Conjugated Thiols, a,w-Dithiols, and
Adsorbates. Understanding Attachments Between Potential Molecular Wires and Gold
Surfaces", Tour, 3. M., Jones II, L., Pearson, D. L., Lamba, J. 3. S., Burgin, T. P., Whitesides, G.
M., Allara, D. L., Parikh, A. N. and Atre, S. V., J. Am. Chem. Soc., 1995,117,9529-9534.</td></tr><tr><td>462.</td><td>Self-Assembled "Surface Plasmon Resonance Permits In Situ Measurement of Protein Adsorption on
Monolayers of Alkanethiolates on Gold", Mrksich, M., Sigal, G. B. and Whitesides, G.
M.,  Langmuir,1995, 11,  4383-4385. </td></tr><tr><td>461.</td><td>"Affinity Capillary Electrophoresis", Chu, Y.-H., Avila, L. Z., Gao, J. and Whitesides, G. M., Act. 
Chem. Res., 1995,28,461-468.</td></tr><tr><td>460.</td><td>"Using Electrospray Ionization FTICR Mass Spectrometry to Study Competitive Binding of
Inhibitors to Carbonic Anhydrase", Cheng, X., Chen, R., Bruce, J. E., Schwartz, B. L., Anderson, G.
A., Hofstadler, S. A., Gale, D. C., Smith, R. D., Gao, J., Sigal, G. B., Mammen, M. and Whitesides,
G. M., J. Am. Chem. Soc., 1995,117, 8859-8860. </td></tr><tr><td>459.</td><td>"Secondary Interactions Significantly Removed from the Sulfonamide Binding Pocket of Carbonic
Anhydrase II Influence Binding Constants", Boriack, P. A., Christianson, D. W., Kingery-Wood, 3.
and Whitesides, G. M., J. Med. Chem., 1995,  38,  2286-2291. </td></tr><tr><td>458.</td><td>"Detection of Hydrogen-Bonded Supramolecular Complexes Using Electrospray Ionization from
Chloroform", Cheng, X., Gao, Q., Smith, R., Simanek, E., Mammen, M. and Whitesides, G., Rapic 
Commun. Mass Spectrum., 1995, 9, 312-316.</td></tr><tr><td>457.</td><td>"Increasing Binding Constants of Ligands to Proteins by Using 'Greasy Tails'", Gao, J., Qiao, S. and
Whitesides, G. M., J. Med. Chem., 1995,38,2292-2301.</td></tr><tr><td>456.</td><td>"Microcontact Printing of Octadecylsiloxane on the Surface of Silicon Dioxide, and Its Application
in Microfabriation", Xia, Y., Mrksich, M., Kim, E. and Whitesides, G. M., J. Am. Chem. Soc., 1995, 
117,9576-9577.</td></tr><tr><td>455.</td><td>"Patterning Self-Assembled Monolayers Using Microcontact Printing: A New Technology for
Biosensors?", M. and Whitesides, G. M., TIBTECH,  1995,  13,  228-235. </td></tr><tr><td>454.</td><td>"Patterned Self-Assembled Monolayers Formed by Microcontact Printing Direct Selective
Metallization by Chemical Vapor Deposition on Planar and Non-Planar Substrates", Jeon, N. L.,
Nuzzo, R. G., Xia, Y., Mrksich, M. and Whitesides, G. M., Langmuir, 1995, II,3024-3026.</td></tr><tr><td>453.</td><td>"Lithographic Molding: A Convenient Route to Structures with Sub-Micrometer Dimensions",
Wilbur, 3. L., Kim, E., Xia, Y. and Whitesides, G., Adv. Mater., 1995, 7, 649-652.</td></tr><tr><td>452.</td><td>"Differentiating Functional Groups with the Scanning Tunneling Microscope", Venkataraman, B.,
Flynn, G. W., Wilbur, J. L., Folkers, J. P. and Whitesides, G. M., J. Phys. Chem., 1995, 99, 8684-
8689. </td></tr><tr><td>451.</td><td>"Self-Assembled Monolayers (SAMs) on Gold Generated from Alkanethiols with the Structure
RNHCOCH2SH", Tam-Chang, S.-W., Biebuyck, H. A., Whitesides, G. M. and Nuzzo, R., Langmul; 
1995, //, 4371.4382.</td></tr><tr><td>450.</td><td>"Control of the Shape of Liquid Lenses on a Modified Gold Surface Using an Applied Electrical
Potential Across a Self-Assembled Monolayer", Gorman, C. B., Biebuyck, H. A. and Whitesides, G.
M.,  Langmuir,1995, 11, 2242-2246.</td></tr><tr><td>449. </td><td>"Molecular Dynamics Simulations of H2NSO2C6H4CONH(Gly)3Bn Bound to the Active Site of
Human Carbonic Anhydrase II", Chin, D. N. and Whitesides, G. M., J. Am. Chem. Soc, 1995, 117</td></tr></table>

# Publications (cont.)

## Publications 1990-1999 (cont.)

# Publications (cont.)

## 6153-6164.

<table><tr><th>448.</th><th>"Use of Controlled Reactive Spreading of Liquid Alkanethiol on the Surface of Gold to Modify the
Size of Features Produced by Microcontact Printing", Xia, Y. and Whitesides, G. M., J. Am. Chem.
Soc., 1995, 117, 3274-3275.</th></tr><tr><td>447.</td><td>"Reduction in the Size of Features of Patterned SAMs Generated by Microcontact Printing with
Mechanical Compression of the Stamp", Xia, Y. and Whitesides, G. M., Adv. Mater., 1995, 7, 471-
473. </td></tr><tr><td>446.</td><td>"Patterned Self-Assembled Monolayers and Meso-Scale Phenomena", Kumar, A., Abbott, N. A.,
Kim, E., Biebuyck, H. A. and Whitesides, G. M., Act. Chem. Res., 1995, 26; 219.226.</td></tr><tr><td>445.</td><td>"Self-Assembled Monolayers of Long-Chain Hydroxamic Acids on the Native Oxide of Metals",
Folkers, J. P., Gorman, C. 8., Laibinis, P. E., Buchholz, S. and Whitesides, G. M., Langmuir, 1995,
11, 813-824.</td></tr><tr><td><change><s>444.</s></change></td><td>"Structure and Wetting Properties of w-Alkoxy-n-alkanethiolate Monolayers on Gold and Silver",
Laibinis, P. E., Bain, C. D., Nuzzo, R. G. and Whitesides, G. M., J. Phys. Chem., 1995, 99, 7663-
7676. </td></tr><tr><td>443.</td><td>"The Use of Minimal Free Energy and Self-Accembly to Form Shapes", Kim, E. and Whitesides, G.
M., Chem. Mat, 1995, 7, 1257-1264.</td></tr><tr><td>442.</td><td>"Use of a Patterned Self-Assembled Monolayer to Control the Formation of a Liquid Resist Pattern
on a Gold Surface", Gorman, C. B., Biebuyck, H. A. and Whitesides, G. M., Chem. Mat, 1995, Z
252-254. </td></tr><tr><td>441.</td><td>"Fabrication of Patterned, Electrically Conducting Polypyrrole Using a Self-Assembled Monolayer: A
Route to All-Organic Circuits", Gorman, C. B., Biebuyck, H. A. and Whitesides, G. M., Chem. Mat,
1995, 7, 526.529.</td></tr><tr><td>440.</td><td>"Reagents for Rapid Reduction of Disulfide Bonds in Proteins", Singh, R. and Whitesides, G. M., in
Techniques in Protein Chemistry VI, J. W. Crabb, Ed., Academic Press, New York, 1995, 259-266.</td></tr><tr><td>439.</td><td>"Scanning Force Microscopes Can Image Patterned Self-Assembled Monolayers", Wilbur, J. L.,
Biebuyck, H. A., MacDonald, J. C. and Whitesides, G. M., Langmuir, 1995, 11, 825-831.</td></tr><tr><td>438.</td><td>"Active Control of Wetting Using Applied Electrical Potentials and Self-Assembled Monolayers",
Abbott, N. L., Gorman, C. B. and Whitesides, G. M., Langmuir, 1995, II, 16-18.</td></tr><tr><td>437.</td><td>"Combining Patterned Self-Assembled Monolayers of Alkanethiolates on Gold with Anisotropic
Etching of Silicon to Generate Controlled Surface Morphologies", Kim, E., Kumar, A. and
Whitesides, G. M., J. Electrochem. Soc., 1995, 142, 628-633.</td></tr><tr><td>436.</td><td>"Design and Synthesis of Hydrogen-bonded Aggregates: Theory and Computation Applied to
Three Systems Based on the Cyanuric Acid-Melamine Lattice", Simanek, E. E., Mammen, M.,
Gordon, D. M., Chin, D., Mathias, 3. P., Seto, C. T. and Whitesides, G. M., Tetrahedron, 1995, 51,
607-619. </td></tr><tr><td>435.</td><td>"Noncovalent Synthesis: Using Physical-Organic Chemistry to Make Aggregates", Simanek, E. E.,
Mathias, J. P., Seto, C. T., Chin, D., Mammen, M., Gordon, D. M. and Whitesides, G. M., Act.
Chem. Res., 1995, 28, 37-44.</td></tr><tr><td>434.</td><td>"Formation and Cleavage of P-0 Bonds", Bertschy, H., Baudin, G. and Whitesides, G. M., in
Enzyme Catalysis in Organic Synthesis: A Comprehensive Handbook, K. Drauz and H. Waldmann,
Eds., VCH, Weinheim, 1995, 505-545.</td></tr><tr><td>433.</td><td>"Self-Assembled Monolayers: Models for Organic Surface Chemistry", Whitesides, G. M. and
Gorman, C. B., in Handbook of Surface Imaging and Visualization, A. T. Hubbard, Ed., CRCPress,
Boca Raton, 1995, 713-733.</td></tr></table>

# Publications (cont.)

## 6153-6164. (cont.)

<table><tr><th>432.</th><th>"Reduction of Aldehydes and Ketones", Bertschy, H., Chenault, H. K. and Whitesides, G. M., in
Enzyme Catalysis in Organic Synthesis: A Comprehensive Handbook, K. Drauz and H. Waldmann,
Eds., VCH, Weinhelm, 1995, 595-628.</th></tr><tr><td>431.</td><td>"Self-Assembling Materials", Whitesides, G. M., Scientific American, 1995, 273, 146-149.</td></tr><tr><td>430.</td><td>"Enzymes in Synthetic Organic Chemistry", Wong, C.-H. and Whitesides, G. M., Tetrahedron
Organic Chemistry Series, J. E. Baldwin and P. D. Magnus, Eds., Pergamon Press, London, 1994.</td></tr><tr><td>429.</td><td>"Computational Simulations of Supramolecular Hydrogen-bonded Aggregates: HubM2, FlexM3,
and Adamantane-based Hubs in Chloroform", Chin, D. N., Gordon, D. M. and Whitesides, G. M., J.
Am. Chem. Soc., 1994, 116, 12033-12044.</td></tr><tr><td>428.</td><td>"Wetting Characteristics of Liquid Drops at Heterogeneous Surfaces", Drelich, 3., Miller, J. D.,
Kumar, A. and Whitesides, G. M., Colloids andSurf. A, 1994, 93, 1-13.</td></tr><tr><td>427.</td><td>"Autophobic Pinning of Drops of Alkanethiols on Gold", Biebuyck, H. A. and Whitesides, G. M.,
Langmuir, 1994, 10, 4581-4587.</td></tr><tr><td>426.</td><td>"Solid-State Structures of Hydrogen-Bonded Tapes Based on Cyclic 2o Diamides", MacDonald, J.
C. and Whitesides, G. M., Chem. Rev., 1994, 94, 2383-2420.</td></tr><tr><td>425.</td><td>"1H NMR Spectroscopy of the Hydrogen-bonded Imide Groups of Hub(M)3:3CA Provides a Useful
Method for the Characterization of these Aggregates", Simanek, E. E., Wazeer, M. I. M., Mathias,
3. P. and Whitesides, G. M., J. Org. Chem., 1994, 59, 4904-4909.</td></tr><tr><td>424.</td><td>"Determination of the Effective Charge of a Protein in Solution by Capillary Electrophoresis", Gao,
3., Gomez, F. A., Harter, R. and Whitesides, G. M., Proc. Nat. Acad. Sc'. USA, 1994, 9/, 12027-
12030. </td></tr><tr><td>423.</td><td>"Measurements of the Conductivity of Individual 10 nm Carbon Nanotubes", Weisbecker, C. S. and
Whitesides, G. M., Proc. Mat. Res. Soc., 1994, 349, 263-268.</td></tr><tr><td>422.</td><td>"Microfabrication by Microcontact Printing of Self-Assembled Monolayers", Wilbur, J. L., Kumar, A.,
Kim, E. and Whitesides, G., Adv. Mater., 1994, 6, 600-604.</td></tr><tr><td>421.</td><td>"Studies in the Organic Solid State", Zerkowski, 3., MacDonald, J., Chin, D. and Whitesides, G. M.,
Bull. Mat. Res. Sac, 1994, 328, 3-14.</td></tr><tr><td>420.</td><td>"Self-Organization of Organic Liquids on Patterned Self-Assembled Monolayers of Alkanethiolates
on Gold", Biebuyck, H. A. and Whitesides, G. M., Langmuir, 1994, 10, 2790.2793.</td></tr><tr><td>419.</td><td>"Synthesis of KDO Using Indium-Mediated Allylation of 2,3:4,5-Di-O-isopropylidene-D-arabinose in
Aqueous Media", Gao, J., Haerter, R., Gordon, D. M. and Whitesides, G. M., J. Org. Chem., 1994,
59, 3714-3715.</td></tr><tr><td>418.</td><td>"Combining Micromachining and Molecular Self-Assembly To Fabricate Microelectrodes", Abbott,
N. L., Rolison, D. R. and Whitesides, G. M., Langmuir, 1994, 10, 2672-2682.</td></tr><tr><td>417.</td><td>"Comparison of Organic Monolayers on Polycrystalline Gold Spontaneously Assembled from
Solutions Containing Dialkyl Disulfides or Alkanethiols", Biebuyck, H. A., Bain, C. D. and
Whitesides, G. M., Langmuir, 1994, 10, 1825-1831.</td></tr><tr><td>416.</td><td>"Patterning Self-Assembled Monolayers: Applications in Materials Science", Kumar, A., Biebuyck,
H. A. and Whitesides, G. M., Langmuir, 1994, 10, 1498-1511.</td></tr><tr><td>415.</td><td>"Using Micromachining, Molecular Self-Assembly and Wet Etching to Fabricate 0.1 to 1
Micrometer-Scale Structures of Gold and Silicon", Abbott, N., Kumar, A. and Whitesides, G. M.,
Chem. Mat., 1994, 6, 596-602.</td></tr><tr><td>414. </td><td>"Polyacrylamides Bearing Pendant a-Sialoside Groups Strongly Inhibit Agglutination of
Erythrocytes by Influenza A Virus: Multivalency and Steric Stabilization of Particulate Biologicial</td></tr></table>

# Publications (cont.)

## 6153-6164. (cont.)

Systems", Lees, W. J., Spaltenstein, A., Wood-Kingery, J. E. and Whitesides, G. M., J. Med. Chem., 1994, 37, 3419-3433.

<table><tr><th></th><th>Chem., 1994, 37, 3419-3433.</th></tr><tr><td>413.</td><td>"Engineering Cell Shape and Function", Singhvi, R., Kumar, A., Lopez, G. P., Stephanopolous, G.
N., Wang, D. I. C., Whitesides, G. M. and Ingber, D. E., Science, 1994, 264, 696-698.</td></tr><tr><td>412.</td><td>"Reagents for Rapid Reduction of Native Disulfide Bonds in Proteins", Singh, R. and Whitesides, G.
M., Bioorg. Chem., 1994, 22, 109-115.</td></tr><tr><td>411.</td><td>"A Redox Fuel Cell That Operates with Methane as Fuel at 120°C, Bergens, S. H., Gorman, C. B.,
Palmore, G. T. R. and Whitesides, G. M., Science, 1994, 265, 1418-1420.</td></tr><tr><td>410.</td><td>"Affinity Capillary Electrophoresis: Insights into the Binding of SH3 Domains by Peptides Derived
from an SH3-Binding Protein", Gomez, F. A., Chen, J. K., Tanaka, A., Schreiber, S. L. and
Whitesides, G. M., J. Org. Chem., 1994, 59, 2885.2886.</td></tr><tr><td>409.</td><td>"Determination of Binding Constants of Ligands to Proteins by Affinity Capillary Electrophoresis:
Compensation for Electroosmotic Flow", Gomez, F. A., Avila, L. Z., Chu, Y.-H. and Whitesides, G.
M., Anal. Chem., 1994, 64 1785.1791.</td></tr><tr><td>408.</td><td>"Self-Assembly Through Hydrogen Bonding: Peripheral Crowding-A New Strategy for the
Preparation of Stable Supramolecular Aggregates Based on Parallel, Connected Rosettes",
Mathias, 3., Simanek, E. E. and Whitesides, G. M., J. Am. Chem. Soc., 1994, 116, 4326.4340.</td></tr><tr><td>407.</td><td>"Structural Preferences of Hydrogen-Bonded Networks in Organic Solution-the Cyclic CA3o M3
'Rosette- , Mathias, J., Zerkowski, J., Seto, C., Simanek, E. E. and Whitesides, G. M., .1. AR). Chem.
Soc., 1994, 116, 4316-4325.</td></tr><tr><td>406.</td><td>"Self-assembled Monolayers containing Mercaptoalkylboronic Acids Adsorbed onto Gold From a
Highly Cross-Linked, Thermally Stable Borate Glass Surface", Carey, R. I., Folkers, J. P. and
Whitesides, G. M., Langmuir, 1994, 10, 2228-2234.</td></tr><tr><td>405.</td><td>"Potential-dependent Wetting of Aqueous Solutions on Self-Assembled Monolayers Formed from
15-(Ferrocenylcarbonyl)pentadecanethiol", Abbott, N. and Whitesides, G. M., Langmuir, 1994, 10,
1493.1497. </td></tr><tr><td>404.</td><td>"Wetting and Protein Adsorption of Self-Assembled Monolayers of Alkanethiolates Supported on
Transparent Films of Gold", DiMilla, P., Folkers, J. P., Biebuyck, H. A., Harter, R., Lopez, G. and
Whitesides, G. M., J. AIM Oren,. Soc., 1994, 116, 2225.2226.</td></tr><tr><td>403.</td><td>"The Wetting of Monolayer Films Exposing Ionizable Acids and Bases", Lee, T. R., Carey, R. I.,
Biebuyck, H. A. and Whitesides, G. M., Langmuir, 1994, .74 741-749.</td></tr><tr><td>402.</td><td>"Microbial and Enzymatic Biofuel Cells", Palmore, G. T. R. and Whitesides, G. M., in Enzymatic
Conversion of Biomass for Fuels Production, M. E. Himmel, 3. 0. Baker and R. P. Overend, Eds.,
ACS Books, American ChemicalSociety, Washington, 1994, 271-290.</td></tr><tr><td>401.</td><td>"Self-Assembly Through Hydrogen Bonding: Preparation and Characterization of Three New Types
of Supramolecular Aggregates Based on Parallel, Cyclic CA3oM3 'Rosettes'', Mathias, J. P., Seto,
C. T., Simanek, E. E. and Whitesides, G. M., J. Am. Chem. Soc., 1994, 114 1725-1736.</td></tr><tr><td>400.</td><td>"Molecular Self-Assembly and Micromachining", Abbott, N. L., Biebuyck, H. A., Buchholz, S.,
Folkers, J. P., Han, M. Y., Kumar, A., Lopez, G. P., Weisbecker, C. S. and Whitesides, G. M., in
Atomic and Nanoscale Modification of Materials, P. Avouris, Ed., Kluwer Academic Publishers,
Ventura, 1994, 239, 293.301.</td></tr><tr><td>399.</td><td>"Identification of Two Hydrophobic Patches in the Active Site Cavity of Human Carbonic
Anhydrase II by Solution-Phase and Solid-State Studies and Their Use in the Development of
Tight-Binding Inhibitors", Jain, A., Whitesides, G. M., Alexander, R. S. and Christianson, D. W., J.
Med. Chem., 1994, 37, 2100-2105.</td></tr><tr><td>398. </td><td>"Lack of Effect of the Length of Oligoglycine- and Oligo(ethylene glycol)- Derived para-</td></tr></table>

# Publications (cont.)

## 6153-6164. (cont.)

<table><tr><th></th><th>Substituents on the Affinity of Benzenesulfonamides for Carbonic Anhydrase II in Solution", Jain,
A., Huang, S. G. and Whitesides, G. M., J. Am. Chem. Soc., 1994, 116, 5057-5062.</th></tr><tr><td>397.</td><td>"Investigations Into the Robustness of Hydrogen-Bonded Crystalline Tapes", Zerkowski, J. A. and
Whitesides, G. M., Chem. Mat, 1994, 6, 1250-1257.</td></tr><tr><td>396.</td><td>"New Varieties of Crystalline Architecture Produced by Small Changes in Molecular Structure in
Tape Complexes of Melamines and Barbiturates", Zerkowski, J. A., Mathias, J. P. and Whitesides,
G. M., J. Am. Chem. Soc., 1994, .116, 4305-4315.</td></tr><tr><td>395.</td><td>"Steric Control of Secondary, Solid-State Architecture in 1:1 Complexes of Melamines and
Barbiturates That Crystallize as Crinkled Tapes", Zerkowski, J. A. and Whitesides, G. M., 1. Am.
aem. Soc., 1994, 116, 4298-4304.</td></tr><tr><td>394.</td><td>"The Design of Organic Structures in the Solid State: Molecular Tapes Based on the Network of
Hydrogen Bonds Present in the Cyanuric AcidoMelamine Complex", Zerkowski, J. A., Seto, C. T.,
Wierda, D. A. and Whitesides, G. M., J. Am. Chem. Soc., 1994, 116, 2382-2391.</td></tr><tr><td>393.</td><td>"Patterned Condensation Figures as Optical Diffraction Gratings", Kumar, A. and Whitesides, G.
M., Science, 1994, 263, 60.62.</td></tr><tr><td>392.</td><td>"Phase Behavior of Two-Component Self-Assembled Monolayers of Alkanethiolates on Gold",
Folkers, J. P., Laibinis, P. E., Deutch, J. and Whitesides, G. M., J. Phys. Chem., 1994, 98, 563-571.</td></tr><tr><td>391.</td><td>"Using Finite Element Analysis to Calculate the Shapes of Geometrically-Confined Drops of Liquid
on Patterned, Self-Assembled Monolayers: A New Method to Estimate Excess Interfacial Free
Energies gsv- gsl", Abbott, N. L., Racz, L M., Szekely, 3. and Whitesides, G. M., J. Am. Chem.
Soc., 1994, 116, 290-294.</td></tr><tr><td>390.</td><td>"Design, Preparation, and Characterization of Hydrogen Bonded Supramolecular Aggregates
Based on the Cyanuric AddoMelamine Lattice", Mathias, 3. P., Simanek, E. E., Seto, C. T. and
Whitesides, G. M., Macromot Symp., 1994, 77, 157-166.</td></tr><tr><td>389.</td><td>"Interchange Between Monolayers on Gold Formed From Unsymmetrical Disulfides and Solutions
of Thiols: Evidence for Sulfur-Sulfur Bond Cleavage by Gold Metal", Biebuyck, H. A. and
Whitesides, G. M., Langmuir, 1993, 9, 1766-1770.</td></tr><tr><td>388.</td><td>"Organized Molecular Assemblies", Whitesides, G. M., Ferguson, G. S., Allara, D., Scherson, D.,
Speaker, L. and Ullman, A., Crit. Rev. Surf. Chem., 1993, 3, 49.65.</td></tr><tr><td>387.</td><td>"Indium-mediated Allylations of Unprotected Carbohydrates in Aqeous Media: A Short Synthesis of
Sialic Acid (Neu-5-Ac)", Gordon, D. M. and Whitesides, G. M., J. Org. Chem., 1993, 58, 7937-
7938. </td></tr><tr><td>386.</td><td>"Self-Assembly Through Hydrogen Bonding: Preparation of a Supramolecular Aggregate
Composed of 10 Molecules", Mathias, J. P., Simanek, E. E., Seto, C. T. and Whitesides, G. M.,
Angew. Chem. Int Ed. Engl., 1993, 32, 1766-1769.</td></tr><tr><td>385.</td><td>"Fabrication and Imaging of Two-Dimensional Patterns of Proteins Adsorbed on Self-Assembled
Monolayers by Scanning Electron Microscopy", Lopez, G. P., Biebuyck, H. A., Hrter, R., Kumar, A.
and Whitesides, G. M., J. Am. Chem. Soc., 1993, 115, 10774.10781.</td></tr><tr><td>384.</td><td>"Monolayers on Disordered Substrates: Self-Assembly of Alkyltrichlorosilanes on Surface-Modified
Polyethylene and Poly(dimethylsiloxane)", Ferguson, G. S., Chaudhury, M. K., Biebuyck, H. A. and
Whitesides, G. M., Macromolecules, 1993, 26, 5870.5875.</td></tr><tr><td>383.</td><td>"Damage to CF3CONH-Terminated Organic SAMs on Al, Ti, Cu, and Au by Al Ka X-rays Is Due
Principally to Electrons", Graham, R. L., Bain, C. D., Biebuyck, H. A., Laibinis, P. E. and
Whitesides, G. M., J. Phys. Chem., 1993, 97, 9456-9464.</td></tr><tr><td>382. </td><td>'Tin- and Indium-Mediated Allylation in Aqueous Media: Application to Unprotecter
Carbohydrates", Kim, E., Gordon, D. M., Schmid, W. and Whitesides, G. M., J. Org. Chem., 1993</td></tr></table>

# Publications (cont.)

## 6153-6164. (cont.)

58, 5500-5507.

<table><tr><th>381.</th><th>Self-Assembled "Convenient Methods for Patterning the Adhesion of Mammalian Cells to Surfaces Using
Monolayers of Alkanethiolates on Gold", Lopez, G. P., Albers, M. W., Schreiber, S. L.,
Carroll, R. W., Peralta, E. and Whitesides, G. M., J. Am. Chem. Soc., 1993, 115, 5877-5878.</th></tr><tr><td>380.</td><td>"Features of Gold Having Micrometer to Centimeter Dimensions Can Be Formed through a
Combination of Stamping with an Elastomeric Stamp and an Alkanethiol Ink Followed by Chemical
Etching", Kumar, A. and Whitesides, G. M., Appl. Phys. Left., 1993, 63, 2002-2004.</td></tr><tr><td>379.</td><td>"Preparation of Conjugates of Proteins with Amyloses by Elongation of Covalently-Attached
Primers Using Phosphorylase", Chu, Y.H. and Whitesides, G. M., 8loorg. Chem., 1993, 21, 319-
329. </td></tr><tr><td>378.</td><td>"Catalytic Activity of Native Enzymes during Capillary Electrophoresis: An Enzymatic
'Microreactor, Avila, L. Z. and Whitesides, G. M., J. Org. Chem., 1993, 58, 5508-5512.</td></tr><tr><td>377.</td><td>"Feed-Forward Neural Networks in Chemistry: Mathematical Systems for Classification and Pattern
Recognition", Burns, J. A. and Whitesides, G. M., Chem. Rev., 1993, 93, 2583-2601.</td></tr><tr><td>376.</td><td>"Affinity Electrophoresis in Multisectional Polyacrylamide Slab is a Useful and Convenient
Technique for Measuring Binding Constants of Aryl Sulfonamides to Bovine Carbonic Anhydrase
B", Chu, Y.-H., Chen, 3. K. and Whitesides, G. M., Anal. Chem., 1993, 65, 1314-1322.</td></tr><tr><td>375.</td><td>"Imaging of Features on Surfaces by Condensation Figures", Lopez, G. P., Biebuyck, H. A., Frisbie,
C. D. and Whitesides, G. M., Science, 1993, 260, 647-649.</td></tr><tr><td>374.</td><td>"Diastereoselectivity (Enantioselectivity) of Aldol Condensations Catalyzed by Rabbit Muscle
Aldolase at C-2 of RCHOHCHO if R has an Appropriately Placed Negatively Charged Group", Lees,
W. J. and Whitesides, G. M., J. Org. Chem., 1993, 58, 1887-1894.</td></tr><tr><td>373.</td><td>"Using Affinity Capillary Electrophoresis to Identify the Peptide in a Peptide Library that Binds
Most Tightly to Vancomycin", Chu, Y.-H., Avila, L. Z., Biebuyck, H. A. and Whitesides, G. M., 1
Org. Chem., 1993, 58, 648-652.</td></tr><tr><td>372.</td><td>"A Convenient Procedure for Transfer Blotting of Coomassie Blue-Stained Proteins from PAGE Gels
to Transparencies", Chu, Y. H. and Whitesides, G. M., 8iotechniques, 1993, 14, 925-930.</td></tr><tr><td>371.</td><td>C-Glycoside "Neuraminidase Resistant Hemagglutination Inhibitors: Acrylamide Copolymers Containing a
of N-Acetylneuraminic Acid", Sparks, M. A., Williams, K. W. and Whitesides, G. M., J.
Med. Chem., 1993, 36, 778-783.</td></tr><tr><td>370.</td><td>"Synthesis of Methyl a-Sialosides N-substituted with Large Alkanoyl Groups, and Investigation of
Their Inhibition of Agglutination of Erythrocytes by Influenza A Virus?, W., Avila, L. Z., Williams,
K. W. and Whitesides, G. M., 81.2org. &amp; Med. (hem. Lett, 1993, 3, 747.752.</td></tr><tr><td>369.</td><td>'Thiol-Disulfide Interchange", Singh, R. and Whitesides, G. M., in Sulfur-Containing Functional
Groups; Supplement S, S. Patai, Ed., 3. Wiley and Sons, Ltd., London, 1993, 633-658.</td></tr><tr><td>368.</td><td>"Use of Affinity Capillary Electrophoresis to Determine Kinetic and Equilibrium Constants for
Binding of Arylsulfonamides to Bovine Carbonic Anhydrase", Avila, L. Z., Chu, Y.-H., Blossey, E. C.
and Whitesides, G. M., J. Med. Chem., 1993, 36, 126-133.</td></tr><tr><td>367.</td><td>"Synthesis of Dithiols as Reducing Agents for Disulfides in Neutral Aqueous Solutions and
Comparison of Reduction Potentials", Lamoureux, G. V. and Whitesides, G. M., J. Org. Chem.,
1993, 58, 633-641.</td></tr><tr><td>366.</td><td>"Equilibrium Constants for Thiol-Disulfide Interchange Reactions: A Coherent, Corrected Set",
Lees, W. 3. and Whitesides, G. M., J. Org. Chem., 1993, 58, 642-647.</td></tr><tr><td>365. </td><td>"Adsorption of Proteins onto Surfaces Containing End-Attached Oligo(Ethylene Oxide): A Model
System Using Self-Assembled Monolayers", Prime, K. L. and Whitesides, G. M., J. Am. Chem. Soc.,</td></tr></table>

# Publications (cont.)

## 6153-6164. (cont.)

1993, 115, 10714-10721.

<table><tr><th>364.</th><th>"Interpretation of the Reduction Potential of 6,6'-Dideoxy-6,6'-Dithiosucrose Disulfide by
Comparison of the Conformations of 6,6'-Dideoxy-6,6'-Dithiosucrose Disulfide, 6,6'-
Dideoxysucrose-6,6'-Dithiol, and Sucrose in Aqueous Solution", Lees, W. 3. and Whitesides, G. M.,
J. Am. Chem. Soc, 1993,115,1860.1869.</th></tr><tr><td>363.</td><td>"Inorganic Environment Derived from the Sol-Gel Route Does Not Improve the Thermal or
Oxidative Stability of 2,4-Dinitroaniline in Coatings", Schutte, C. L., Williams, K. W. and
Whitesides, G. M., Polymer,  1993,34, 2609-2614. </td></tr><tr><td>362.</td><td>"Large-Scale Synthesis of b-L-Fucopyranosyl Phosphate and the Preparation of GDP-b-Fucose",
Adelhorst, K. and Whitesides, G. M., Carbohyd. Res., 1993,242,69-76.</td></tr><tr><td>361.</td><td>"Synthesis, Characterization, and Thermodynamic Analysis of a 1+1 Self-Assembling Structure
Based on the Cyanuric Acid-Melamine Lattice", Seto, C. T. and Whitesides, G. M., J. Am. Chem.
Soc.,1993,115,1330-1340.</td></tr><tr><td>360.</td><td>"Molecular Self-Assembly Through Hydrogen Bonding: Aggregation of Five Molecules to Form a
Discrete Supramolecular Structure", Seto, C. T., Mathias, J. P. and Whitesides, G. M., J. Am.
Chem. Soc., 1993,115, 1321.1329. </td></tr><tr><td>359.</td><td>"Synthesis of Potential Inhibitors of Hemagglutination by Influenza Virus: Chemoenzymic
Preparation of N-5 Analogs of N-Acetylneuraminic Acid", Sparks, M., Williams, K., Lukacs, C.,
Schrell, A., Priebe, G., Spaltenstein, A. and Whitesides, G. M., Tetrahedron,1993, 49,  1-12. </td></tr><tr><td>358.</td><td>"Scanning Electron Microscopy Can Form Images of Patterns in Self-Assembled Monolayers",
Lopez, G. P., Biebuyck, H. A. and Whitesides, G. M., Langmuir;1993, 9, 1513-1516.</td></tr><tr><td>357.</td><td>"Molecular Self-Assembly Through Hydrogen Bonding: Supramolecular Aggregates Based on the
Cyanuric Acid-Melamine Lattice", Seto, C. T. and Whitesides, G. M., J. Am. Chem. Soc, 1993,115,
905-916. </td></tr><tr><td>356.</td><td>"Self-Assembly through Networks of Hydrogen Bonds", Mathias, J. P., Seto, C. T., Zerkowski, J. A.
and Whitesides, G. M., in Molecular Recognition: Chemical and Biochemical Problems II, Roya. 
Society of Chemistry, 1992, 111, 35-49.</td></tr><tr><td>355.</td><td>"The Agglutination of Erythrocytes by Influenza Virus is Strongly Inhibited by Liposomes
Incorporating an Analog of Sialyl Gangliosides", Kingery-Wood, 3. E., Williams, K. W., Sigal, G. B.
and Whitesides, G. M., J. Am. Chem. Soc., 1992,114, 7303-7305. </td></tr><tr><td>354.</td><td>"Manipulation of the Wettability of Surfaces on the 0.1 to 1-Micrometer Scale Through
Miaomachining and Molecular Self-Assembly", Abbott, N. L., Folkers, 3. P. and Whitesides, G. M.,
Science,  1992, 25Z 1380-2.</td></tr><tr><td>353.</td><td>"The Use of Self-Assembled Monolayers and a Selective Etch to Generate Patterned Gold
Features", Kumar, A., Biebuyck, H. A., Abbott, N. L. and Whitesides, G. M., J. Am. Chem. Soc.,
1992,114, 9188-9199. </td></tr><tr><td>352.</td><td>"Self-Assembled Monolayers of n-Alkanethiolates on Copper Are Barrier Films that Protect the
Metal Against Oxidation by Air", Laibinis, P. E. and Whitesides, G. M., J. Am. Chem. Soc., 1992, 
114,9022-9028.</td></tr><tr><td>351.</td><td>"Affinity Capillary Electrophoresis Can Simultaneously Measure Binding Constants of Multiple
Peptides to Vancomycin", Chu, Y.-H. and Whitesides, G. M., J. Org. Chem., 1992,57,3524-3525.</td></tr><tr><td>350.</td><td>"Solid-State Structures of 'Rosette' and 'Crinkled Tape' Motifs Derived from the Cyanuric
AcidoMelamine Lattice", Zerkowski, J. A., Seto, C. T. and Whitesides, G. M., J. Am. Chem. Soc.,
1992,114, 5473-5475. </td></tr><tr><td>349. </td><td>"Structure of Monolayers Formed by Coadsorption of Two n-Alkanethiols of Different Chair
Lengths on Gold and Its Relation to Wetting", Laibinis, P. E., Nuzzo, R. G. and Whitesides, G. M.</td></tr></table>

# Publications (cont.)

## 6153-6164. (cont.)

J. Phys. Chem., 1992, 96, 5097-5105.

<table><tr><th>348.</th><th>"Self-Assembled Monolayers of Alkanethiols on Gold: The Adsorption and Wetting Properties of
Monolayers Derived from Two Components with Alkane Chains of Different Lengths", Folkers, J.
P., Laibinis, P. E. and Whitesides, G. M., J. Adhes. Sci. Tech., 1992, 6, 1397-1410.</th></tr><tr><td>347.</td><td>"Self-Assembled Monolayers of Alkanethiols on Gold: Comparisons of Monolayers Containing
Mixtures of Short- and Long-Chain Constituents with CH3 and CH2OH Terminal Groups", Folkers,
3. P., Laibinis, P. E. and Whitesides, G. M., Langmuir, 1992, 8, 1330-1341.</td></tr><tr><td>346.</td><td>"How to Make Water Run Uphill", Chaudhury, M. K. and Whitesides, G. M., Science, 1992, 256,
1539.1541. </td></tr><tr><td>345.</td><td>"Substrate Specificity and Carbohydrate Synthesis Using Transketolase", Kobori, Y., Myles, D. C.
and Whitesides, G. M., J. Om. Chem., 1992, 57, S899.5907.</td></tr><tr><td>344.</td><td>"Use of Affinity Capillary Electrophoresis To Measure Binding Constants of Ugands to Proteins",
Chu, Y.-H., Avila, L. Z., Biebuyck, H. A. and Whitesides, G. M., J. Med. Chem., 1992, 35, 2915-
2917. </td></tr><tr><td>343.</td><td>"The Enzymatic Synthesis of 1,5-Dideoxy-1,5-diimino-D-talitol and 1-Deoxygalactostatin Using
Fuculose 1-Phosphate Aldolase", Lees, W. 3. and Whitesides, G. M., Bioorg. Chem., 1992, 20, 173-
179. </td></tr><tr><td>342.</td><td>"Heterogeneous, Platinum-Catalyzed Hydrogenations of (Diolefin)dialkylplatinum(II) Complexes",
Lee, T. R. and Whitesides, G. M., Acc. Chem. Res., 1992, 25, 266-272.</td></tr><tr><td>341.</td><td>"Nucleoside Phosphate Sugars: Syntheses on Practical Scales, and Their Use as Reagents in the
Enzymatic Preparation of Oligosaccharides and Glycoconjugates", Heidlas, 3. E., Williams, K. W.
and Whitesides, G. M., Acc. Chem. Res., 1992, 25, 307-314.</td></tr><tr><td>340.</td><td>2-Desoxy-L-xylo-hexose", "Chemo-enzymatische Synthese von Kohlenhydraten: Die Herstellung von L-Xylose and
Schmid, W., Heidlas, J., Mathias, J. P. and Whitesides, G. hf, Liebigs Ann. Chem.,
1992, 95-97.</td></tr><tr><td>339.</td><td>"Correlation Between Surface Free Energy and Surface Constitution", Chaudhury, M. K. and
Whitesides, G. M., Science, 1992, 255, 1230-1232.</td></tr><tr><td>338.</td><td>"Designing Ordered Molecular Arrays in Two and Three Dimensions", Folkers, 3. P., Zerkowski, 3.
A., Laibinis, P. E., Seto, C. T. and Whitesides, G. M., in Supramolecular Architecture in Two and
Three Dimensions, T. Bein, Ed., ACS Symposium Series; American Chemical Society, Washington,
O.C., 1992, 499, 10-23.</td></tr><tr><td>337.</td><td>"Molecular Recognition in Gels, Monolayers, and Solids", Prime, K. L., Chu, Y.-H., Schmid, W.,
Seto, C. T., Chen, J. K., Spaltenstein, A., Zerkowski, J. A. and Whitesides, G. M., in
Macromolecular Assemblies, P. Stroeve and A. C. Balazs, Eds., ACS Symposium Series; American
Chemical Society, Washington, D.C., 1992, 493, 227-239.</td></tr><tr><td>336.</td><td>"w-Terminated Alkanethiolate Monolayers on Surfaces of Copper, Silver and Gold have Similar
Wettabilities", Laibinis, P. E. and Whitesides, G. M., J. Am. Chem. Soc., 1992, 114, 1990-1995.</td></tr><tr><td>335.</td><td>"Toward Orthogonal Self-Assembly of Redox Active Molecules on Pt and Au: Selective Reaction of
Disulfide with Au and Isonitrile with Pt", Hickman, J. 3., Laibinis, P. E., Auerbach, D. I., Zou, C.,
Gardner, T. 3., Whitesides, G. M. and Wrighton, M. S., Langmuir, 1992, 8, 357-359.</td></tr><tr><td>334.</td><td>"Synthesis of 2-Amino-1,2-dideoxy-D-galactitol Hydrochloride and 5-Arnino-1,4-anhydro-5,6-
dideoxy-L-galactitol Hydrochloride", Adelhorst, K. and Whitesides, G. M., Cartohyd. Res., 1992,
232, 183-185.</td></tr><tr><td>333.</td><td>"Thermal Reconstruction of the Functionalized Interface of Polyethylene Carboxylic Add and Its
Derivatives", Ferguson, G. S. and Whitesides, G. M., in Modern Approaches to Wettability: Theory
and Applications, G. Loeb and M. Schrader, Eds., Plenum Press, New York, 1992, 6, 143.177.</td></tr></table>

# Publications (cont.)

## 6153-6164. (cont.)

<table><tr><th>332.</th><th>"Practical Enzyme-Based Syntheses of Uridine 5'-Diphosphogalactose (UDP-Gal) and Uridine 5'-
Diphospho-N-acetylgalactosamine (UDP-GaINAc) on Gram Scale", Heidlas, J., Lees, W. and
Whitesides, G. M., 1 Org. Chem., 1992, 57, 152.157.</th></tr><tr><td>331.</td><td>"Gram-Scale Synthesis of Uridine 5'-Diphospho-N-acetylglucosamine, UDP-GIcNAc: Comparison of
Enzymatic and Chemical Routes", Heidlas, J. E., Lees, W. J., Pale, P. and Whitesides, G. M., 1
Org. Chem., 1992, 57, 146-151.</td></tr><tr><td>330.</td><td>"Molecular Self-Assembly and Nanochemistry: A Chemical Strategy for the Synthesis of
Nanostructures", Whitesides, G. M., Mathias, J. P. and Seto, C. T., Science, 1991, 254, 1312-1319.</td></tr><tr><td>329.</td><td>"Enzymes as Catalysts in Carbohydrate Synthesis", Toone, E. J. and Whitesides, G. M., in Enzymes
in Carbohydrate Synthesis, M. D. Bednarski and E. S. Simon, Eds., ACS Symposium Series,
American Chemical Society, Washington, DC 1991, 466, 1-22.</td></tr><tr><td>328.</td><td>"Meso-2,5-Dimercapto-N,N,N',N'-tetramethyladipamide: A Readily Available, Kinetically Rapid
Reagent for the Reduction of Disulfides in Aqueous Solution", Lees, W. J., Singh, R. and
Whitesides, G. M., 1 Org. Chem., 1991, 56, 7328-7331.</td></tr><tr><td>327.</td><td>"X-Ray Damage to CF3CO2-terminated Organic Monolayers on Si/Au Supports is Due Primarily to
X-Ray Induced Electrons", Laibinis, P. E., Graham, R. L., Biebuyck, H. A. and Whitesides, G. M.,
Science, 1991, 254, 981-983.</td></tr><tr><td>326.</td><td>"Comparisons of Self-Assembled Monolayers on Silver and Gold: Mixed Monolayers Derived from
HS(CH2)21X and HS(CH2)10Y (X, Y = CH3, CH2OH) Have Similar Properties", Laibinis, P. E., Fox,
M. A., Folkers, J. P. and Whitesides, G. M., Langmuir; 1991, Z 3167-3173.</td></tr><tr><td>325.</td><td>"A Transketolase-Based Synthesis of (+)-exo-Brevicomin", Myles, D. C., Andrulis, P. J. I. and
Whitesides, G. M., Tet. Left., 1991, 32, 4835-4838.</td></tr><tr><td>324.</td><td>"Enzymatic Synthesis  of Uridine 5'-Diphosphoglucuronic Acid on a Gram Scale", Toone, E. 3.,
Simon, E. S. and Whitesides, G. M., 1 Org. Chem., 1991, 56, 5603-5606.</td></tr><tr><td>323.</td><td>"Attenuation of Photoelectrons in Monolayers of n-Alkanethiols Adsorbed on Copper, Silver and
Gold", Laibinis, P. E., Bain, C. D. and Whitesides, G. M., 1 Phys. Chem., 1991, 95, 7017-7021.</td></tr><tr><td>322.</td><td>"Wetting Films on Chemically Modified Surfaces: An X-ray Study", Tidswell, I. M., Rabedeau, T. A.,
Pershan, P. S., Folkers, J. P., Baker, M. V. and Whitesides, G. M., Phys. Rev. 8, 1991, 44, 10869-
10879. </td></tr><tr><td>321.</td><td>"Carbon-Carbon Bond Formation in Aqueous Ethanol: Diastereoselective Transformation of
Unprotected Carbohydrates to Higher Carbon Sugars Using Allyl Bromide and Tin Metal", Schmid,
W. and Whitesides, G. M., 1 Am. Chem. Soc., 1991, 113, 6674-6676.</td></tr><tr><td>320.</td><td>"Selenols Catalyze the Interchange Reactions of Dithiols and Disulfides in Water", Singh, R. and
Whitesides, G. M., 1 Org. Chem., 1991, 56, 6931-6933.</td></tr><tr><td>319.</td><td>"Heterogeneous Reductions of (Homohypostrophene)dialkylplatinum(II) Complexes Provide a
Useful System for the Study of Intermediate Surface Alkyls on Platinum", Lee, T. R. and
Whitesides, G. M., Cat. Lett, 1991, 9, 451.472.</td></tr><tr><td>318.</td><td>"X-ray Grazing Incidence Diffraction from Alkylsiloxane Monolayers on Silicon Wafers", Tidswell, I.
M., Rabedeau, T. A., Pershan, P. S., Kosowsky, S. D., Folkers, J. P. and Whitesides, G. M., 1
Chem. Phys., 1991, 95, 2854-2861.</td></tr><tr><td>317.</td><td>n-Alkanethiols "A Comparison of the Structures and Wetting Properties of Self-Assembled Monolayers of
on the Coinage Metal Surfaces Cu, Ag, Au", Laibinis, P. L., Whitesides, G. M., Allara,
D. L., Tao, Y.-T., Parikh, A. N. and Nuzzo, R. G., J. Am. Chem. Soc., 1991, 113, 7152-7167.</td></tr><tr><td>316. </td><td>"The Reduction of C' Bonds Proceeds with Retention of Configuration: Stereochemical
Investigation of the Heterogeneous Reduction by Dideuterium of (Homohypostrophene)neopentyl</td></tr></table>

# Publications (cont.)

## 6153-6164. (cont.)

<table><tr><th></th><th>(2-norbomyl)platinum(II) Complexes on Platinum Black", Lee, T. R., Wierda, D. A. and
Whitesides, G. M., J. Am. Chem. Sac, 1991, 113, 8745.8753.</th></tr><tr><td>315.</td><td>"Self-Assembled Organic Monolayers: Model Systems for Studying Adsorption of Proteins at
Surfaces", Prime, K. L. and Whitesides, G. M., Science, 1991, 252, 1164-1167.</td></tr><tr><td>314.</td><td>"Contact Adhesion of Thin Gold Films on Elastomeric Supports: Cold Welding Under Ambient
Conditions", Ferguson, G. S., Chaudhury, M. K., Sigal, G. B. and Whitesides, G. M., Science, 1991,
253, 776-778.</td></tr><tr><td>313.</td><td>"Molecular Self-Assembly of Two-Terminal, Voltammetric Microsensors with an Internal
Reference", Hickman, J. J., Ofer, D., Laibinis, P. E., Whitesides, G. M. and Wrighton, M. S.,
Science, 1991, 252, 688-691.</td></tr><tr><td>312.</td><td>1,4-dideoxy-D-arabinitol "a-Aminoaldehyde Equivalents as Substrates for Rabbit Muscle Aldolase: Synthesis of
and (2R,5R)-dihydroxymethyl-(3R,4R)-dihydroxypyrrolidine", Hung, R. R., Straub, J.
A. and Whitesides, G. M., J. Org. Chem., 1991, 56, 3849-3855.</td></tr><tr><td>311.</td><td>"Synthesis of Glycosyl Phosphates Using the Fraser-Reid Activation", Pale, P. and Whitesides, G.
M., J. Org. Chem., 1991, 56, 4547-4549.</td></tr><tr><td>310.</td><td>"Selective Reduction of Disulfides by Tris(2-carboxyethyl)phosphine", Burns, J. A., Butler, J. C.,
Moran, J. R. and Whitesides, G. M., J. Org. Chem., 1991, 56, 2648.2650.</td></tr><tr><td>309.</td><td>"A Reagent for Reduction of Disulfide Bonds in Proteins That Reduces Disulfide Bonds Faster than
Does Dithiothreitor, Singh, R. and Whitesides, G. M.,1. Org. Chem., 1991, 56, 2332-2337.</td></tr><tr><td>308.</td><td>"CMP-N-Acetylneuraminic Acid Synthetase of Escherichia coli: Overexpression, Purification and
Use in the Enzymatic Synthesis of CMP-N-Acetylneuraminic Acid and CMP-Neuraminic Acid
Derivatives", Shames, S. L., Simon, E. S., Christopher, C. W., Schmid, W., Whitesides, G. M. and
Lang, L.-L., Glycobiology, 1991, 1, 187-191.</td></tr><tr><td>307.</td><td>"Heterogeneous Catalysis on Platinum and Self-Assembled Monolayers on Metal and Metal Oxide
Surfaces", Lee, T. R., Laibinis, P. E., Folkers, 3. P. and Whitesides, G. M., Pure App/.. Own., 1991,
63, 821-828.</td></tr><tr><td>306.</td><td>"The Heterogeneous Reductions of (Diolefin)dialkylplatinum(1I) Complexes on Platinum Black in
Ethyl Alcohol: Kinetics, Isotopic Interchange of Hydrogen between Coadsorbed Surface Alkyls, and
Comparison of Surface Alkyls Generated from the Platinum Complexes and from Olefins", Lee, T.
R. and Whitesides, G., M., J. Am. Chem. Soc., 1991, 113, 2576-2585.</td></tr><tr><td>305.</td><td>"Isotopic Exchange in the Platinum-Catalyzed Reductions of Olefins in Protic Solvents", Lee, T. R.
and Whitesides, G. M., J. Am. Chem. Soc., 1991, 113, 2568-2576.</td></tr><tr><td>304.</td><td>"Selective Functionalization of Gold Microstructures with Ferrocenyl Derivatives via Reaction with
Thiols or Disulfides: Characterization by Electrochemistry and Auger Electron Spectroscopy",
Hickman, 3. 3., Ofer, D., Zou, C., Wrighton, M. S., Laibinis, P. E. and Whitesides, G. M., J. Am.
ChM. SOC., 1991, 113, 1128-1132.</td></tr><tr><td>303.</td><td>"The Loss of Halide from Sol-Gel films on Heating Does Not Involve Oxidation", Schutte, C. L. and
Whitesides, G. M., Chem. Mater., 1991, 3, 267-271.</td></tr><tr><td>302.</td><td>"Direct Measurement of Interfacial Interactions between Semispherical Lenses and Flat Sheets of
Polydimethylsiloxane and Their Chemical Derivatives", Chaudhury, M. K. and Whitesides, G. M.,
Langmun; 1991, 7, 1013-1025.</td></tr><tr><td>301.</td><td>"Acid-Base Interactions in Wetting", Whitesides, G. M., Biebuyck, H. A., Folkers, J. P. and Prime,
K. J., 1 Adhes. So: Tech., 1991, 5, 57-69.</td></tr><tr><td>300.</td><td>"Self-Assembly of a Hydrogen-Bonded 2+3 Supramolecular Complex", Seto, C. T. and Whitesides,
G. M., J. Am. Chem. Soc., 1991, 113, 712-713.</td></tr></table>

# Publications (cont.)

## 6153-6164. (cont.)

<table><tr><th>299.</th><th>"Polyacrylamides Bearing Pendant a-Sialoside Groups Strongly Inhibit Agglutination of
Erythrocytes by Influenza Virus", Spaltenstein, A. and Whitesides, G. M., J. AM. Chem. Soc., 1991,
113, 686-687.</th></tr><tr><td>298.</td><td>"The Extent of Incorporation of Excess Deuterium in the Platinum-Catalyzed Reduction of
Unsubstituted Cycloolefins by H2 in D2O/THF Increases with the Strain Energy of the Product
Cycloalkanes", Lee, T. ft and Whitesides, G. M., J. Am. Chem. Soc., 1991, 113, 369-370.</td></tr><tr><td>297.</td><td>"The Reduction by Deuterium on Platinum Black of exo-2-norbornyls and enclo-2-norbornyla to
Norbomane-2-d1 Occurs with Predominant Retention of Configuration", Lee, T. R. and Whitesides,
G. M., J. Am. Chem. Soc., 1991, 113, 368-369.</td></tr><tr><td>296.</td><td>"Formation of Self-Assembled Monolayers by Chemisorption of Derivatives of Oligo(ethylene
glycol) of Structure HS(CH2)11(OCH2CH2)mOH on Gold", Pale-Grosdemange, C., Simon, E. S.,
Prime, K. L. and Whitesides, G. M., J. Am. Chem. Sac, 1991, 113, 12-20.</td></tr><tr><td>295.</td><td>"Analysis of depth profiles of sol-gel derived multilayer coatings by Rutherford backscattering
spectrometry and by cross-sectional transmission electron microscopy", Schutte, C. L., Smith, P.
M. and Whitesides, G. M., J. Mater. Res., 1991, 4 835.839.</td></tr><tr><td>294.</td><td>"Enzymes as Catalysts in Carbohydrate Synthesis", Toone, E. J., Kobori, Y., Myles, D. C., Ozaki,
A., Schmid, W., von der Osten, C., Sinskey, A. 1 and Whitesides, G. M., in Chemical Aspects of
Enzyme Biotechnology; Proceedings of the 8th Annual IUCCP Symposium, A. I. Scott, F. M.
Raushell and T. O. Baldwin, Eds., Plenum, New York, 1990, 179-195.</td></tr><tr><td>293.</td><td>"Organic Surface Chemistry: Polymers and Self-Assembled Monolayers", Whitesides, G. M.,
Chimia, 1990, 44, 310-311.</td></tr><tr><td>292.</td><td>"A New Approach to Cyclitols Based on Rabbit Muscle Aldolase (RAMA)", Schmid, W. and
Whitesides, G. M., J. Am. Chem. Soc., 1990, 112, 9670-9671.</td></tr><tr><td>291.</td><td>'The Design of Organic Structures in the Solid State: Hydrogen-Bonded Molecular Tapes'",
Zerkowski, 3. A., Seto, C. T., Wierda, D. A. and Whitesides, G. M., J. Am. Chem. Soc., 1990, 112,
9025-9026. </td></tr><tr><td>290.</td><td>"What Will Chemistry Do in the Next Twenty Years?", G. M., Angew. Chem. Int Ed. Engl., 1990,
29, 1209-1218.</td></tr><tr><td>289.</td><td>"Synthesis of the a-Methyl Ketoside of 5-Amino Neuraminic Acid Methyl Ester and its
Corresponding 5-Myristoyl and 5-Cyclopropanoyl Derivative", Schrell, A. and Whitesides, G. Al.,
Liebigs Ann. Chem., 1990, 1111.1114.</td></tr><tr><td>288.</td><td>"Self-Assembly Based on the Cyanuric Acid-Melamine Lattice", Seto, C. T. and Whitesides, G. M.,
J. Am. Chem. Soc, 1990, 112, 64O9-6411.</td></tr><tr><td>287.</td><td>"Quantifying Acid-Base Properties of Organic Functional Groups at a Polyethylene-Water Interface
by Photoacoustic Calorimetry", Zhang, L., Shulman, M. A., Whitesides, G. M. and Grabowski, 3. 3.,
J. Am. Chem. Soc, 1990, 112, 7069-7071.</td></tr><tr><td>286.</td><td>'The Diffusion of Cesium Ion in 5i02 Films Derived from Sol-Gel Precursors", Schutte, C. L. and
Whitesides, G. M., Chem. Mat, 1990, .2, 576.581.</td></tr><tr><td>285.</td><td>"Degenerate Intermolecular Thiolate-Disulfide Interchange Involving Cyclic Five-Membered
Disulfides Is Faster by —103 Than That Involving Six- or Seven-Membered Disulfides", Singh, R.
and Whitesides, G. M., J. Am. Chem. Soc., 1990, 112, 6304-6309.</td></tr><tr><td>284.</td><td>"Predicting the Stability of Cyclic Disulfides by Molecular Modeling: 'Effective Concentrations' in
Thiol-Disulfide Interchange and the Design of Strongly Reducing Dithiols", Bums, J. A. and
Whitesides, G. M., J. Am. Chem. Soc., 1990, 112, 6296-6303.</td></tr><tr><td>283. </td><td>"Overproduction and Substrate Specificity of a Bacterial Fuculose-1-Phosphate Aldolase: A New
Enzymatic Catalyst for Stereocontrolled Aldol Condensation", Ozaki, A., Toone, E. 3., von der</td></tr></table>

# Publications (cont.)

## 6153-6164. (cont.)

Osten, C. H., Sinskey, A. J. and Whitesides, G. M., J. Am. Chem. Soc., 1990, //2, 4970-4971.

<table><tr><th>282.</th><th>"Convenient Syntheses of Cytidine 5'-Triphosphate (CTP), Guanosine S'-Triphosphate (GTP), and
Uridine 5'-Triphosphate (UTP) and Their Use in the Preparation of UDP-Glucose, UDP-Glucuronic
Acid, and GDP-Mannose", Simon, E. S., Grabowski, S. and Whitesides, G. M., J. Org. Chem., 1990,
55, 1834-1841.</th></tr><tr><td>281.</td><td>"Enzymes in Organic Synthesis", Waldmann, H., Grabowski, S., Simon, E. S. and Whitesides, G.
M., in Enzymes in Industry, W. Gerhartz, Ed., VCH, Welnhelm, 1990, 141-148.</td></tr><tr><td>280.</td><td>"Effective Molarity in Diffusion-Controlled Reactions", Mazor, M. H., Wong, C. F., McCammon, J.
A., Deutch, J. M. and Whitesides, G. M., J. Phys. Chem., 1990, 94, 3807.3812.</td></tr><tr><td>279.</td><td>"Preparation of a Mixture of Nucleoside Triphosphates Suitable for Use in Synthesis of Nucleotide
Phosphate Sugars from Ribonucleic Acid Using Nuclease P1, A Mixture of Nucleoside
Monophosphokinases and Acetate Kinase", Haynie, S. L. and Whitesides, G. M., Apo,. Biochem.
Biotech., 1990, 23, 205-220.</td></tr><tr><td>278.</td><td>UDP-Glucose", "Enzyme-Catalyzed Organic Synthesis of Sucrose and Trehalose with in situ Regeneration of
Haynie, S. L. and Whitesides, G. M., App.( Biochem. Biotech., 1990, 23, 155.170.</td></tr><tr><td>277.</td><td>"Comparison of Rate Constants for Thiolate-Disulfide Interchange in Water and in Polar Aprotic
Solvents Using Dynamic 1H NMR Line Shape Analysis", Singh, R. and Whitesides, G. M., J. Am.
Chem. Soc., 1990, 112, 1190-1197.</td></tr><tr><td>276.</td><td>"Size of Alkyl Group R: Principal Factor Determining Wettability of Surface-Functionalized
Polyethylenes (PE-CONHR and PE-002R) by Water", Wilson, M. D., Ferguson, G. S. and
Whitesides, G. M., J. Am. Ghent Soc., 1990, 112, 1244-1245.</td></tr><tr><td>275.</td><td>"Wet Chemical Approaches to the Characterization of Organic Surfaces: Self-Assembled
Monolayers, Wetting and the Physical-Organic Chemistry of the Solid-Liquid Interface",
Whitesides, G. M. and Laibinis, P. E., Langmuir, 1990, 6, 87-96.</td></tr><tr><td>274.</td><td>"X-Ray Specular Reflection Studies of Silicon Coated by Organic Monolayers (Alkylsiloxanes)",
Tidswell, I. M., Ocko, B. M., Pershan, P. S., Wasserman, S. R., Whitesides, G. M. and Me, 3. D.,
Physical Reviews 8,1990, 41,1111-1120.</td></tr></table>

# Publications (cont.)

## 6153-6164. (cont.)

The Whitesides Research Group

# Publications

# Publications (cont.)

## Publications 2000-Present

<table><tr><th>957.</th><th>"Surface Plasmon Resonances of Free-Standing Gold Nanowires Fabricated by NanoSciving", Xu,
Q., Bao, 3., Capasso, F. &amp; Whitesides, G. M., Angewandte Chemie InternationalEdition, 2006, 45,
3631-3635. </th></tr><tr><td>956.</td><td>"Differentiation of Proteins based on Characteristic Patterns of Accociation and Denaturation in
Solutions of Sodium Dodecyl Sulfate.", Gudiksen, K. L., Gitlin, I. &amp; Whitesides, G. M., Proceedings
of the NationalAcademy ofScience, 2006, 103, 7968-7972.</td></tr><tr><td>955.</td><td>"The Intersection of Biology and Materials Science", Whitesides, G. M. &amp; Wong, A. P., MRS
Bulletin, 2006, 31, 19-27.</td></tr><tr><td>954.</td><td>Break-up.", "Formation of Droplets and Bubbles in a Microfluidic T-junction - Scaling and Mechanism of
Garstecki, P., Fuerstman, M. .1., Stone, H. A. &amp; Whitesides, G. M., Lab on a Chip,  2006, 4
437-446. </td></tr><tr><td>953.</td><td>"Optical Waveguiding using Thermal Gradients across Homogeneous Liquids in Microfluidic
Channels.", Tang, S. K. T., Mayers, B. T., Vezenov, D. V. &amp; Whitesides, G. M., Applied Physics
Letters 2006, 88, 061112-1 - 061112-3.</td></tr><tr><td>952.</td><td>"Experimental Approaches for Controlling Current Flowing through Metal-molecules-Metal
Junctions.", Tran, E., Duati, M., Fern, V., Klaus, M., Zhamikov, M., Whitesides, G. M. &amp; Rampi, M.
A., AdvancedMaterials, 2006, 18, 1323-1328.</td></tr><tr><td>951.</td><td>"Why are Proteins Charged? Networks of Charge-Charge Interactions in Proteins Measured by
Charge Ladders and Capillary Electrophoresis.", Gitlin, I., Carbeck, 3. D. &amp; Whitesides, G. M.,
Angewandte Chemie InternationalEdition, 2006, 45, 3022-3060.</td></tr><tr><td>950.</td><td>'The Paradoxical Themodynamic Basis for the Interaction of Ethylene Glycol, Glycine, and
Sarcosine Chains with Bovine Carbonic Anhydrase II: An Unexpected Manifestation of
Enthalpy/Entropy Compensation.", Krishnamurthy, V. M., Bohall, B. R., Semetey, V. &amp; Whitesides,
G. M., J. AM. Chem. Soc., 2006, 128, 5802-5812.</td></tr><tr><td>949.</td><td>"Electron Transport Across Hexa-peri-hexabenzocoronene Units in a Metal-Self-Assembled
Monolayer-Metal Junction.", Duati, M., Grave, C., Tcbeborateva, N., Wu, 3., Miillen, K.,
Shaporenko, A., Zharnikov, M., Kriebel, 3. K., Whitesides, G. M. &amp; Rampi, M. A., Advancec
Materials, 2006, 18, 329-333.</td></tr><tr><td>948.</td><td>"Promotion of Opsonization by Antibodies and Phagocytosis of Gram-Positive Bacteria by a
Bifunctional Polyacrylamide.", Krishnamurthy, V. M., Quinton, L. 3., Estroff, L. A., Metallo, S., M.,
I. J., Mizgerd, J. P. &amp; Whitesides, G. M., Biomaterials, 2006, 27, 3663-3674.</td></tr><tr><td>947.</td><td>"Mechanics of a Process to Assemble Microspheres on a Patterened Electrode.", Zhu, T.,
Winkleman, A., Whitesides, G. M. &amp; Suo, Z., Applied Physics Letters, 2006, 88, 144101.1 -
144101-3. </td></tr><tr><td>946.</td><td>"Formation of Bubbles and Droplets in Microfluidic Systems.", Garstecki, P., Galian-Calvo, A. M. &amp;
Whitesides, G. M., Bulletin of the Polish Academy ofSciences, 2006, 53, 361-372.</td></tr><tr><td>945.</td><td>'Tessellation of a Stripe.", Garstecki, P. &amp; Whitesides, G. M., Phys. Rev. E, 2006, 73, 031603 -
1031603-10. </td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

<table><tr><th>944.</th><th>"Peracetylated Bovine Carbonic Anhydrase (BCA-Ac18) is Kinetically More Stable than Native BCA
to Sodium Dodecyl Sulfate.", Gitlin, I., Gudilcsen, K. L. &amp; Whitesides, G. M., Journal of Physics,
Chemistry 8, 2006, 110, 2372-2377.</th></tr><tr><td>943.</td><td>"Mixing with Bubbles: A Practical Technology for use with Portable Microfluidic Devices.",
Garstecki, P., Fuerstman, M. J., Fischbach, M. A., Sia, S. K. &amp; Whitesides, G. M., Lab on a ao,
2006, 6, 207-212.</td></tr><tr><td>942.</td><td>"Gating Current Flowing through Molecules in Metal-Molecules-Metal Junctions.", Tran, E., Duati,
M., Whitesides, G. M. &amp; Rampi, M. A., Faraday Discussions, 2006, 131, 197-203.</td></tr><tr><td>941.</td><td>"Swimming in Circles: Motion of Bacteria Near Solid Boundries.", Lauga, E., DiLuzio, W.,
Whitesides, G. M. &amp; Stone, H. A., Biophysical Journal, 200690, 400-412.</td></tr><tr><td>940.</td><td>"Synthesis and Conformational Study of Water-Soluble, Rigid, Rod-like Oligopiperidines.",
Semetey, V., Moustakas, D. &amp; Whitesides, G. M., Angewandte Chemie International Edition, 2006,
45, 588-591.</td></tr><tr><td>939.</td><td>", Wolfe, D. B. &amp; Whitesides, G. M. in Nanolithography and Patterning Techniques in
Microelectronics (S. Bucknall, D. G) 76-119 (Woodhead Publishing Limited and CRC Press LLC,
Cambridge, England, 2005).</td></tr><tr><td>938.</td><td>"Reagent-Loaded Cartridges for Valveless and Automated Fluid Delivery in Microfluidic Devices.",
Linder, V., Sia, S. K. &amp; Whitesides, G. M., Analytical Chemistry, 2005, 77 64-71.</td></tr><tr><td>937.</td><td>"Optical Waveguiding in Suspensions of Dielectric Particles.", Conroy, R. S., Mayers, B. T.,
Vezenov, D. V., Wolfe, D. B., Prentiss, M. &amp; Whitesides, G. M., AppliedPhysics Letters, 2005, 44,
7853.7857. </td></tr><tr><td>936.</td><td>"", Whitesides, G. M., Kriebel, J. K. &amp; Mayers, B. T., in Nanoscale Assembly — Chemical
Techniques (ed. Huck W. T. S.), 217-239 (Springer (formerly Kluwer), Cambridge, UK, 2005.</td></tr><tr><td>935.</td><td>"Controlling the Electron Transfer Mechanism in Metal-Molecules-Metal Junctions.", Tran, E.,
Whitesides, G. M. &amp; Rampi, M. A., Electrochimka Acta, 2005, 50, 4850.4856.</td></tr><tr><td>934.</td><td>"Molecular Engineering of Surfaces using Self-Assembled Monolayers.", Whitesides, G. M., Kriebel,
J. K. &amp; Love, J. C., Science Progress, 2005, 88, 17-48.</td></tr><tr><td>933.</td><td>"Diffusion-Controlled Optical Elements for Optofluidics.", Wolfe, D. B., Conroy, R. S., Vezenov, D.
V., Mayers, B. T., Prentiss, M. G. &amp; Whitesides, G. M., AppliedPhysics Letters, 2005, 8Z 181105-1
- 181105-3.</td></tr><tr><td>932.</td><td>"Oscillations with Uniquely Long Periods in a Microfluidic Bubble Generator.", Garstecki, P.,
Fuerstman, M. J. &amp; Whitesides, G. M., Nature Physics, 2005, 1, 168-171.</td></tr><tr><td>931.</td><td>"Fabrication of Thin, Metallic Films along the Sidewalls of a Topographically Patterned Stamp and
Their Application in Charge Printing.", Cao, T., Xu, Q., Winkleman, A. &amp; Whitesides, G. M., SMALL,
2005, 1, 1191-1195.</td></tr><tr><td>930.</td><td>"Making Things by Self-Assembly", Boncheva, M. and Whitesides, G. M., MRS Bulletin, 2005, 30,
736-742. </td></tr><tr><td>929.</td><td>"Direct Patterning of Mammalian Cells onto Porous Tissue Engineering Substrates using Agarose
Stamps", Stevens, M. M., Mayer, M., Anderson, D. G., Weibel, D. B., Whitesides, G. M. and
Langer, R., Biomaterials, 2005, 26, 7636-7641.</td></tr><tr><td>928.</td><td>"Imaging Patterns of Intensity in Topographically Directed Photolithography", Paul, K. E., Breen,
T. L., Smith, S. P., Hadzik, T., Prentiss, M. G. and Whitesides, G. M., J. Vac. Sci. Technol., B,
2005, 23, 918-925.</td></tr><tr><td>927. </td><td>"Torque-Actuated Valves for Microfluidics", Weibel, D. B., Kruithof, M., Potenta, S., Sia, S. K., Lee,</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

A. and Whitesides, G. M., Anal. Chem., 2005, 77, 4726-4733.

<table><tr><th>926.</th><th>"Combining Microscience and Neurobiology", Weibel, D. B., Garstecki, P. and Whitesides, G. M.,
Current Opinion In Neurobiology, 2005,15, 1-8. </th></tr><tr><td>925.</td><td>"Controlling the Shape of Filamentous Cells of Escherichia Coli", Takeuchi, S., DiLuzio, W., Weibel,
D. B. and Whitesides, G. M., Nano Lett, 2005,5,1819-1823.</td></tr><tr><td>924.</td><td>"Nanoscience, Nanotechnology, and Chemistry", Whitesides, G. M., Small,  2005,1, 172-179. </td></tr><tr><td>923.</td><td>"Modeling the Anodic Half-Cell of a Low-Temperature Coal Fuel Cell", Weibel, D. B., Lee, A.,
Ferrigno, R., Boulatov, R. and Whitesides, G. M., Angew. Chem. Int. Ed., 2005,  44,2-6.</td></tr><tr><td>922.</td><td>"Microoxen: Microorganisms to Move Microscale Loads", Weibel, D. B., Garstecki, P., Ryan, D.,
DiLuzio, W., Mayer, M., Seto, 1 E. and Whitesides, G. M., Proc. Natl. Acad. Sci. , 2005,  102, 
11963-11967. </td></tr><tr><td>921.</td><td>"A Low-Threshold, High-Efficiency Microfluidic Waveguide Laser", Vezenov, D. V., Mayers, B. T.,
Conroy, R. S., Whitesides, G. M., Snee, P., Chan, Y., Nocera, D. G. and Bawendi, M. G., J. Am.
Chem. .5oc., 2005,127, 8952.8953. </td></tr><tr><td>920.</td><td>"Space- and Time-Resolved Spectrophotometry in Microsystems", Damean, N., Sia, S. K., Linder,
V., Narovlyansky, M. and Whitesides, G. M., Proc. Ned. Acad. Sci , 2005,102,10035-10039.</td></tr><tr><td>919.</td><td>"Escherichia coli Swim on the Right-Hand Side", DiLuzio, W., Turner, L., Mayer, M., Garstecki, P.,
Weibel, D. B., Berg, H. C. and Whitesides, G. M., Nature,  2005,  435,  1271-1274. </td></tr><tr><td>918.</td><td>"A Bacterial Printing Press that Regenerates its Ink: Contact Printing Bacteria Using Hydrogel
Stamps", Weibel, D. B., Lee, A., Mayer, M., Brady, S. F., Bruzewicz, D. A., Yang, 1, DiLuzio, W.,
Clardy, J. and Whitesides, G. M., Langmuir,2005, 21,  6436-6442. </td></tr><tr><td>917. </td><td>"Water-Soluble Sacrificial Layers for Surface Micromachining", Under, V., Gates, B. D., Ryan, D.,
Parviz, B. A. and Whitesides, G. M., SMALL,2005,1,730-736.</td></tr><tr><td>916. </td><td>"A General Method for Patterning Gradients of Biomolecules on Surfaces Using Microfluidic
Networks", Jiang, X., Xu, Q., Dertinger, S. K. W., Stroock, A. D., Fu, T. and Whitesides, G. M.,
Anal. Chem., 2005, 77, 2338-2347.</td></tr><tr><td>915.</td><td>"Non-Linear Dynamics of a Flow-Focusing Bubble Generator: An Inverted Dripping Faucet",
Garstecki, P., Fuerstman, M. J. and Whitesides, G. M., Physical Review Letters, 2005, 9( 234502-
1- 234502-4.</td></tr><tr><td>914.</td><td>"A Design for Mixing Using Bubbles in Branched Microfluidic Channels", Garstecki, P., Fischbach,
M. A. and Whitesides, G. M., Applied Physics Letters, 2005,86,244108-1 - 244108-3.</td></tr><tr><td>913.</td><td>"Directed Self-Assembly of Spherical Particles on Patterned Electrodes by an Applied Electric
Field", Winkleman, A., Gates, B. D., McCarty, L. S. and Whitesides, G. M., Adv. Mater. , 2005, 17
1507-1511. </td></tr><tr><td>912.</td><td>"Mechanism for Flow-Rate Controlled Breakup in Confined Geometries: A Route to Mondisperse
Emulsions", Garstecki, P., Stone, H. A. and Whitesides, G. M., Physical Review Letters, 2005,  94, 
164501-1 - 164501-4.</td></tr><tr><td>911.</td><td>"Directing Cell Migration with Asymmetnc Micropatterns", Jiang, X., Bruzewicz, D. A., Wong, A. P.,
Piel, M. and Whitesides, G. M., Proc. Nati Acad. Sci. , 2005,102, 975-978. </td></tr><tr><td>910.</td><td>"New Approaches to Nanofabrication: Molding, Printing, and Other Techniques", Gates, B. D., Xu,
Q., Stewart, M., Ryan, D., Willson, C. G. and Whitesides, G. M., Chem. Rev. , 2005,  105,  1171-
1196. </td></tr><tr><td>909. </td><td>"Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology", Love, J. C.,
Estroff, L. A., Kriebel, J. K., Nuzzo, R. G. and Whitesides, G. M., Chem. Rev. , 2005,  105,  1103-</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

1169.

<table><tr><th>908.</th><th>"An Axisymmetric Flow-Focusing Microfluidic Device", Takeuchi, S., Garstedd, P., Weibel, D. B.
and Whitesides, G. M., Adv. Mater. , 2005, 17, 1067.1072.</th></tr><tr><td>907.</td><td>"Eliminating Positive Charged Lysine e-NH3+ Groups on the Surface of Carbonic Anhydrase has no
Significant Influences on Its Folding from Sodium Dodecyl Sulfate", Gudiksen, K. L., Gitlin, I.,
Yang, J., Urbach, A. R. and Whitesides, G. M., J. Am. Chem. Soc., 2005, 127, 4707-4714.</td></tr><tr><td>906.</td><td>"The Art of Scientific Writing", Whitesides, G. M., Adv. Mater. , 2005, 17, 775-776.</td></tr><tr><td>905.</td><td>"Integrated Fluorescent Light Source for Optofluidic Applications", Vezenov, D. V., Mayers, B. T.,
Wolfe, D. B. and Whitesides, G. M., Applied Physics Letters, 2005, 86, 041104-1 - 041104-3.</td></tr><tr><td>904.</td><td>"Microengineering the Environment of Mammalian Cells in Culture", Chen, C. S., Jiang, X. and
Whitesides, G. M., MRS Bulletin, 2005, 30, 194.201.</td></tr><tr><td>903.</td><td>"Arrays and Cascades of Fluorescent Liquid-Liquid Waveguides: Broadband Light Sources for
Spectroscopy in Microchannels", Mayers, B. T., Vezenov, D. V., Vullev, V. and Whitesides, G. M.,
Anal. Chem., 2005, 77, 1310-1316.</td></tr><tr><td>902.</td><td>"Magnetic Self-Assembly of Three-Dimensional Surfaces from Planar Sheets", Boncheva, M.,
Andreev, S. A., Mahadevan, L., Winkleman, A., Reichman, D., Prentiss, M. G., Whitesides, S. and
Whitesides, G. M., Proc. Natl. Acad. Sci., , 2005, 102, 3924-3929.</td></tr><tr><td>901.</td><td>"Templated Self-Assembly: Formation of Folded Structures by Relaxation from a Pre-Stressed,
Planar Tape", Boncheva, M. and Whitesides, G. M., Adv. Mater , 2005, 17 553-557.</td></tr><tr><td>900.</td><td>"Approaching Zero: Using Crystal Fracture as a Metric for Replica Molding", Xu, Q., Mayers, B. T.,
Lahav, M., Vezenov, D. V. and Whitesides, G. M., J. Am. Chem. Soc., 2005, 127.</td></tr><tr><td>900.</td><td>"Approaching Zero: Using Crystal Fracture as a Metric for Replica Molding", Xu, Q., Mayers, B. T.,
Lahav, M., Vezenov, D. V. and Whitesides, G. M., J. Am. Chem. Soc, 2005, 127.</td></tr><tr><td>899.</td><td>"Generation of Monodisperse Partides Using Microfluidics: Control Over Size, Shape and
Composition", Xu, S., Nie, Z., Seo, M., Lewis, P., Kumacheva, E., Garstedd, P., Weibel, D. B.,
Gitlin, I. and Whitesides, G. M., Angew. Chem. Int. Ed, 2005, 44, 724-728.</td></tr><tr><td>898.</td><td>"Reagent-Loaded Cartridges for Valveless and Automated Fluid Delivery in Microfluidic Devices",
Under, V., Sia, S. K. and Whitesides, G. M., Anal. Chem., 2005, 77, 64-71.</td></tr><tr><td>897.</td><td>"Nanoscience, Nanotedmology, and Chemistry", Whitesides, G. M., Small, 2005, 1, 172-179.</td></tr><tr><td>896.</td><td>"Directing Cell Migration with Asymmetric Micropattems", Jiang, X., Bruzewicz, D. A., Wong, A. P.,
Piel, M. and Whitesides, G. M., Proc. Natl. Acad. Sci. , 2005, 102, 975-978.</td></tr><tr><td>895.</td><td>"Whitesides' Group: Writing a Paper"", Whitesides, G. M., Adv. Mater , 2004, 16, 1375-1377.</td></tr><tr><td>894.</td><td>"Effects of Surface Modification and Moisture on the Rates of Charge Transfer Between Metals
and Organic Materials", Wiles, J. A., Fialkowski, M., Radowski, M. R., Whitesides, G. M. and
Grzybowski, B., J. Phys. Chem. 8, 2004, 108, 20296.20302.</td></tr><tr><td>893.</td><td>"Nanostructures Replicated by Polymer Molding", Wolfe, D. B., Love, J. C. and Whitesides, G. M.,
in Encyclopedia ofNanoscience and Nanotechnology, New York, 2004, 2657-2666.</td></tr><tr><td>892.</td><td>"Fabrication of Free-Standing Metallic Pyramidal Shells", Xu, Q., Tonics, I., Fuerstman, M. 3., Love,
J. C. and Whitesides, G. M., Nano Lett., 2004, 4, 2509-2511.</td></tr><tr><td>891.</td><td>"Compatibility of Mammalian Cells on Surfaces of Poly(dimethylsiloxane)", Lee, N., 3, Jiang, X.,
Ryan, D. and Whitesides, G. M., Langmuk, 2004, 20, 11684-11691.</td></tr><tr><td>890. </td><td>"The Influence of the Zn(II) Confactor on the Refolding of Bovine Carbonic Anhydrase after</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

<table><tr><th></th><th>Denaturation with Sodium Dodecyl Sulfate", Gudiksen, K. L., Urbach, A. R., Gitlin, I., Yang, J.,
Vasquez, J. A., Costello, C. E. and Whitesides, G. M., Anal. Chem., 2004, 76, 7151-7161.</th></tr><tr><td>889.</td><td>"An Integrated Approach to a Portable and Low-Cost Immunoassay for Resource-Poor Settings",
Sia, S. K., Under, V., Amirparviz, B. A., Siegel, A. and Whitesides, G. M., Angew. Chem. Int. Ed., 
2004,43, 498.502. </td></tr><tr><td>888.</td><td>"Mechanical Anisotrophy of Adherent Cells Probed by a Three-Dimensional Magnetic Twisting
Device", Hu, S., Eberhard, L., Chen, J. K., Love, J. C., Butler, J. P., Fredberg, J. J., Whitesides, G.
M. and Wang, N., American Journal of Physiology - Cell Physioh2gy, 2004,287,C1184-C1191.</td></tr><tr><td>887.</td><td>"Self-Assembling Fluidic Machines", Grzybowski, B., Radkowski, M., Campbell, C. J., Lee, N., 3 and
Whitesides, G. M., Appl. Phys. Lett, 2004,84, 1798-1800. </td></tr><tr><td>886.</td><td>"Composite Ferromagnetic Photoresist for the Fabrication of Miaoelectromechanical Systems",
Damean, N., Parviz, B. A., Lee, N., 3, Odom, T. W. and Whitesides, G. M., Journal of
Micromechanics and Microengineering, 2004,15,29-34.</td></tr><tr><td>885.</td><td>"Patterning Multiple Aligned Self-Assembled Monolayers Using Light", Ryan, D., Parviz, B. A.,
Linder, V., Semetey, V., Sia, S. K., Su, J., Mrksich, M. and Whitesides, G. M., Langmuir,  2004,  20, 
9080.9088. </td></tr><tr><td>884.</td><td>"Palladium as a Substrate for Self-Assembled Monolayers Used in Biotechnology", Jiang, X.,
Bruzewicz, D. A., Thant, M. M. and Whitesides, G. M., Anal. Chem., 2004, 76, 6116-6121.</td></tr><tr><td>883.</td><td>"Formation of Monodisperse Bubbles in a Microfluidic Flow-Focusing Device", Garstecki, P., Gitlin,
I., DiLuzio, W. and Whitesides, G. M., Applied Physics Letters, 2004, 85, 2649.2651.</td></tr><tr><td>882.</td><td>"A Magnetic Trap for Living Cells Suspended in a Paramagnetic Buffer", Winkleman, A., Gudiksen,
K. L., Ryan, D., Greenfield, D., Prentiss, M. G. and Whitesides, G. M., Applied Physics Letters,
2004,85,2411.2413.</td></tr><tr><td>881.</td><td>"Self-Assembled Monolayers (SAMs) and Synthesis of Planar Micro- and Nanostructures", Yan, L.,
Huck, W. T. S. and Whitesides, G. M., J. Macro. Sci., 2004,  44,  175-206. </td></tr><tr><td>880.</td><td>"Potentiometric Titrations in a Poly(dimethylsiloxane)-Based Microfluidic Device", Ferrigno, R.,
Lee, N., 3, Jiang, X. and Whitesides, G. M., Anal. Chem., 2004,  76,  2273-2280. </td></tr><tr><td>879.</td><td>"Unconventional Nanofabrication", Gates, B. 0., Xu, Q., Love, J. C., Wolfe, D. B. and Whitesides,
G. M., Annual Review of Materials Research, 2004,34, 339-372. </td></tr><tr><td>878.</td><td>"Dynamic Control of Liquid-Core, Liquid-Cladding Optical Waveguides", Wolfe, D. B., Conroy, R.
S., Garstecki, P., Mayers, B. T., Fischbach, M. A., Paul, K. E., Prentiss, M. G. and Whitesides, G.
M.,  Proc. Nati. Acad. Sd. , 2004,101, 12434-12438. </td></tr><tr><td>877.</td><td>"Micropattemed Agarose Gels for Stamping Arrays of Proteins and Gradients of Proteins", Mayer,
M., Yang, 3., Gitlin, I., Gracias, D. H. and Whitesides, G. M., Proteomics,  2004, 4, 2366-2376.</td></tr><tr><td>876.</td><td>"Electron Transfer in a Hg-SAM//SAM-Hg Junction Medicated by Redox Centers", Tran, E., Rampi,
M. A. and Whitesides, G. M., Angew. Chem. Int. Ed., 2004,  43,  3835-3839. </td></tr><tr><td>875.</td><td>"Assumptions: Taking Chemistry in New Directions", Whitesides, G. M., Angew. Chem. Int Ed,
2004,  43,  3632.3641. </td></tr><tr><td>874.</td><td>"Soft Lithography", Love, J. C., Wolfe, D. B., Gates, B. D. and Whitesides, G. M., in McGraw-Hill
2004 Yearbook of Science and Technology, McGraw-Hill, New York, 2004,323-326.</td></tr><tr><td>873.</td><td>"Biomimetic Approaches to the Design of Functional, Self-Assembling Systems", Boncheva, M. and
Whitesides, G. M., Dekker Encyclopedia of Nanosaence and Nanotechnology, 2004,  .1,  287-294. </td></tr><tr><td>872. </td><td>"Shear Patterning of Microdominos: A New Class of Procedures for Making Micro- and
Nanostructures", Gates, B. D., Xu, Q., Thalladi, V. R., Cao, T., Knickerbocker, T. and Whitesides,</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

G. M., Angew. Chem. Int. Ed., 2004, 43, 2779-2783.

<table><tr><th>871.</th><th>"Self-Assembled Aggregates of IgGs as Templates for the Growth of Clusters of Gold
Nanoparticles", Yang, J., Mayer, M., Kriebel, J. K., Garstecki, P. and Whitesides, G. M., Angew.
Chem. Int. Ed., 2004, 43, 1555-1558.</th></tr><tr><td>870.</td><td>"Fabrication of Planar Optical Waveguides by Electrical Microcontact Printing", Wolfe, D. B.,
Conroy, R. S., Love, J. C., Gates, B. D., Prentiss, M. G. and Whitesides, G. M., Applied Physics
Letters, 2004, 84, 1623-1625.</td></tr><tr><td>869.</td><td>"Fabrication of Metal Structures with Nanometer-Scale Lateral Dimensions by Sectioning Using a
Microtome", Xu, Q., Gates, B. D. and Whitesides, G. M., J. Am. Chem. Sac, 2004, 126, 1332-
1333. </td></tr><tr><td>868.</td><td>"Solvent Compatibility of Poly(Dimethylsiloxane)-Based Microfluidic Devices", Lee, N., J, Park, C.
and Whitesides, G. M., Anal. Chem., 2004, 75, 6544-6554.</td></tr><tr><td>867.</td><td>"Electron Exchange Between Two Electrodes Medicated By Two Electroactive Adsorbates",
Schmickler, W., Rampi, M. A., Tran, E. and Whitesides, G. M., Faraday Discuss, 2004, 125, 171-
177. </td></tr><tr><td>866.</td><td>"Engineering Microtools in Polymers to Study Cell Biology", Jiang, X. and Whitesides, G. M., Chem.
Eng. Tech., 2003, 3, 475.480.</td></tr><tr><td>865.</td><td>"Propagation of Viruses on Micropatterned Host Cells", Endler, E. E., Duca, K. A., Nealey, P. F.,
Whitesides, G. M. and Yin, J., 8/atech. &amp; Bioeng., 2003, 81, 719-725.</td></tr><tr><td>864.</td><td>"Three-Dimensional Self-Assembly of Metallic Rods with Sub-Micron Diameters Using Magnetic
Interactions", Love, J. C., Urbach, A. R., Prentiss, M. G. and Whitesides, G. M., J. Am. Chem. Soc,
2003, 125, 12696-12697.</td></tr><tr><td>863.</td><td>"Replication of Vertical Features Smaller than 2 nm by Soft Lithography", Gates, B. D. and
Whitesides, G. M., J. Am. Chem. Soc, 2003, 125, 14986-14987.</td></tr><tr><td>862.</td><td>"Using Self-Assembly for the Fabrication of Nano-Scale Electronic and Photonic Devices",
Amirparviz, B. A., Ryan, D. and Whitesides, G. M., IEEE Trans. Adv. Pack., 2003, 26, 233-241.</td></tr><tr><td>861.</td><td>"Asymmetric Dimes Can be Formed by Dewetting Half-Shells of Gold Deposited on the Surfaces
of Spherical Oxide Colloids", Lu, Y., Xiong, H., Jiang, X., Xia, Y., Prentiss, M. G. and Whitesides, G.
M., JAm. Chem. Soc., 2003, 125, 12724-12725.</td></tr><tr><td>860.</td><td>"Synthesis of Monodisperse Polymers from Proteins", Yang, J., Gitlin, I., Krishnamurthy, V. M.,
Vasquez, J. A., Costello, C. E. and Whitesides, G. M., J. Am. Chem. Soc, 2003, 125, 12392-12393.</td></tr><tr><td>859.</td><td>"Microfluidic Devices Fabricated in Poly(dimethylsiloxane) for Biological Studies", Sia, S. K. and
Whitesides, G. M., Electrophoresis; 2003, 24, 3563-3576.</td></tr><tr><td>858.</td><td>"A Tool for Studying Contact Electrification in Systems Comprising Metals and Insulating
Polymers", Wiles, J. A., Grzybowski, B. A., Winkleman, A. and Whitesides, G. M., Anal. Chem.,
2003, 75, 4859-4867.</td></tr><tr><td>857.</td><td>"Microfabricated Teflon Membranes for Low-Noise Recordings of Ion Channels in Planar Lipid
Bilayers", Mayer, M., Kriebel, J. K., Tosteson, M. T. and Whitesides, G. M., Biophys. J., 2003, 85,
2684-2695. </td></tr><tr><td>856.</td><td>"Sub-100 nm Confinement of Magnetic Nanoparticles Using Localized Magnetic Field Gradients",
Urbach, A. R., Love, 3. C., Prentiss, M. G. and Whitesides, G. M., JAm. Chem. Soc., 2003, 125,
12704-12705. </td></tr><tr><td>855.</td><td>"The Right Size: Nanobiotechnology", Whitesides, G. M., Nature Biotech., 2003, 21, 1161-1165.</td></tr><tr><td>854. </td><td>"Two-Dimensional Colloid Crystals Obtained by Coupling of Flow and Confinement", Kumacheva,</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

<table><tr><th></th><th>E., Garstecki, P., Wu, H. and Whitesides, G. M., Phys. Rev. Lett, 2003, 91, 128301-1 - 128301-4.</th></tr><tr><td>853.</td><td>"Surface Tension-Powered Self-Assembly of Microstructures - The State-of-the-Art", Syms, R. R.
A., Yeatman, E. M., Bright, V. M. and Whitesides, G. M., J. Microelect Syst, 2003, 12, 387.417.</td></tr><tr><td>852.</td><td>"Generation of Submicrometer Structures by Photolithography Using Arrays of Spherical
Microlenses", Wu, M.-H., Park, C. and Whitesides, G. M., J. Colloid Interface 5ci, 2003, 265, 304-
309. </td></tr><tr><td>851.</td><td>"Controlling Flows in Microchannels with Patterned Surface Charge and Topography", Stroock, A.
D. and Whitesides, G. M., Acc. Chem.Res., 2003, 36, 597-604.</td></tr><tr><td>850.</td><td>"Pumping Based on Transverse Electrokinetic Effects", Gitlin, I., Stroock, A. D., Ajdari, A. and
Whitesides, G. M., App/. Phys. Lett, 2003, 83, 1486-1488.</td></tr><tr><td>849.</td><td>"Formation of Chiral, Three-Dimensional Aggregates by Self-Assembly of Helical Components",
Boncheva, M., Bruzewicz, D. A. and Whitesides, G. M., Langmua; 2003, 19, 6066-6071.</td></tr><tr><td>848.</td><td>"Plasticity in Self-Assembly: Templating Generates Functionally Different Circuits from a Single
Precursor", Boncheva, M., Ferrigno, R., Bruzewicz, D. A. and Whitesides, G. M., Angew. Chem.
Int. Ed., 2003, 42, 3368.3371.</td></tr><tr><td>847.</td><td>"Self-Assembly of Gears at a Fluid/Air Interface", Ng, J. M. K., Fuerstman, M. 3., Grzybowski, B.
A., Stone, H. A. and Whitesides, G. M., .1Am. Chem. Soc., 2003, 125, 7948-7958.</td></tr><tr><td>846.</td><td>"Self-Healing Systems Having a Design Stimulated by the Vertebrate Spine", Boncheva, M. and
Whitesides, G. M., Angew. Chem. Int. Ed. Eng., 2003, 42, 2644-2647.</td></tr><tr><td>845.</td><td>"Millimeter-Scale Self-Assembly and Its Applications", Boncheva, M., Bruzewicz, D. A. and
Whitesides, G. M., Pure Apo,. Chem., 2003, 75, 621-630.</td></tr><tr><td>844.</td><td>"Solving Mazes Using Microfluidic Networks", Fuerstman, M. J., Deschatelets, P., Kane, R. S.,
Schwartz, A., Kenis, P. J. A., Deutch, 3. M. and Whitesides, G. M., Langmuir, 2003, 19, 4714-
4722. </td></tr><tr><td>843.</td><td>"Rapid Prototyping of 2D Structures with Feature Sizes Larger than 8 mm", Linder, V., Wu, H.,
Jiang, X. and Whitesides, G. M., Anal. Chem., 2003, 75, 2522-2527.</td></tr><tr><td>842.</td><td>"Fluidic Ratchet Based on Marangoni-Benard Convection", Stroock, A. D., Ismagilov, R. F., Stone,
H. A. and Whitesides, G. M., Langmuir, 2003, 19, 4358-4362.</td></tr><tr><td>841.</td><td>"Customization of Poly(dimethylsiloxane) Stamps by Micromachining using a Femtosecond-Pulsed
Laser", Wolfe, D. B., Ashcom, 3. B., Hwang, 3. C., Schaffer, C. 8., Mazur, E. and Whitesides, G.
M., Adv. Mat, 2003, 15, 62-65.</td></tr><tr><td>840.</td><td>"A Miniaturized, Parallel, Serially Diluted Immunoassay for Analyzing Multiple Antigens", Jiang, X.,
Ng, 3., Stroock, A., Dertinger, S. and Whitesides, G. M., J. Am. Chem. Sr., 2003, 125, 5294-
5295. </td></tr><tr><td>839.</td><td>"Geometric Determinants of Directional Cell Motility Revealed using Microcontact Printing", Brock,
A., Chang, E., Ho, C.-C., LeDuc, P., Jiang, X., Whitesides, G. M. and Ingber, D. E., Langmuir,
2003, 19, 1611-1617.</td></tr><tr><td>838.</td><td>"Patterning Spherical Surfaces at the Two-Hundred-Nanometer Scale Using Soft Lithography",
Paul, K. E., Prentiss, M. G. and Whitesides, G. M., Adv. Punt: Mat, 2003, 13, 259.263.</td></tr><tr><td>837.</td><td>"Electrostatic Self-Assembly of Macroscopic Crystals using Contact Electrification", Grabowski, B.
A., Winkleman, A., Wiles, J. A., Brumer, Y. and Whitesides, G. M., Nature Mater., 2003, 2, 241-
245. </td></tr><tr><td>836. </td><td>"Formation and Structure of Self-Assembled Monolayers of Alkanethiolates on Palladium", Love, 3
C., Wolfe, D. B., Haasch, R., Chabinyc, M. L., Paul, K. E., Whitesides, G. M. and Nuzzo, R. G., i</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

AM. Chem. Sac, 2003, 125, 2597-2609.

<table><tr><th>835.</th><th>"Dynamic Self-Assembly of Rings of Charged Metallic Spheres", Grzybowski, B. A., Wiles, 3. A. and
Whitesides, G. M., Phys. Rev. Lett., 2003, 90, 083903.1 - 083903.4.</th></tr><tr><td>834.</td><td>Anti-Fluorescein "Using Bifunctional Polymers Presenting Vancomydn and Fluorescein Groups to Direct
Antibodies to Self-Assembled Monolayers Presenting D-Alanine-D-Alanine Groups",
Metallo, S., Kane, R. S., Holmlin, R. E. and Whitesides, G. M., J. Am. Chem. Soc., 2003, 125,
4534-4540. </td></tr><tr><td>833.</td><td>"Adsorption of Proteins to Hydrophobic Sites on Mixed Self-Assembled Monolayers", Ostuni, E.,
Grzybowski, B. A., Mrksich, M., Roberts, C. S. and Whitesides, G. M., Langmuir, 2003, 19, 1861-
1872. </td></tr><tr><td>832.</td><td>"Self-Assembled Monolayers Exposed to Metastable Argon Beams Undergo Thiol Exchange
Reactions", Chabinyc, M. L., Love, J. C., Thywissen, J. H., Cervelli, F., Prentiss, M. G. and
Whitesides, G. M., Langmuir, 2003, 19, 2201-2205.</td></tr><tr><td>831.</td><td>"Mesoscale Self-Assembly: Capillary Interactions when Positive and Negitive Menisci have Similar
Amplitudes", Wolfe, D. B., Snead, A., Mao, C., Bowden, N. B. and Whitesides, G. M., Langmuir,
2003, 19, 2206.2214.</td></tr><tr><td>830.</td><td>"Kosmotropes Form the Basis of Protein-Resistant Surfaces", Kane, R. S., Deschatelets, P. and
Whitesides, G. M., Langmuir, 2003, 19, 2388-2391.</td></tr><tr><td>829.</td><td>"Synthesis of Free-Standing Quasi-Two-Dimensional Polymers", Stroock, A. D., Kane, R. S., Weck,
M., Metallo, S. 3. and Whitesides, G. M., Langmuk, 2003, 19, 2466-2472.</td></tr><tr><td>828.</td><td>"Electrochemical Desorption of Self-Assembled Monolayers Non-Invasively Releases Patterned
Cells from Geometrical Confinements", Jiang, X., Ferrigno, R., Mrksich, M. and Whitesides, G. M.,
J. Am. Chem. Soc, 2003, 125, 2366-2367.</td></tr><tr><td>827.</td><td>"Selective Chemical Treatment of Cellular Microdomains Using Multiple Laminar Streams",
Takayama, S., Ostuni, E., LeDuc, P., Naruse, K., Ingber, D. E. and Whitesides, G. M., Chem. &amp;
Biol., 2003, 10, 123-130.</td></tr><tr><td>826.</td><td>"Molecular Electronics with a Metal-Insulator-Metal Junction Based on Self-Assembled
Monolayers", Chabinyc, M. L, Holmlin, R. E., Haag, R., Chen, X., Ismagilov, R. F., Rampi, M. A.
and Whitesides, G. M., in ACS Symposium Series No. 844 / Molecules as Components of Electronic
Devices Chapter 3, M. Lieberman, Ed., ACS Books, Washington, DC, 2003, 16-35.</td></tr><tr><td>825.</td><td>"Significance of Charge Regulation in the Analysis of Protein Charge Ladders", Gitlin, I., Mayer, M.
and Whitesides, G. M., J. Phys. Chem. 5, 2003, 107, 1466-1472.</td></tr><tr><td>824.</td><td>"Fabrication of Complex Three-Dimensional Microchannel Systems in PDMS", Wu, H., Odom, T.
W., Chiu, D. T. and Whitesides, G. M., J. Am. Chem. Soc, 2003, .125, 554-559.</td></tr><tr><td>823.</td><td>"Directional Control of Lamellipodia Extension by Contraning Cell Shape and Orienting Cell
Tractional Forces", Parker, K. K., Brock, A. L., Brangwynne, C., Mannix, R. 3., Wang, N., Ostuni,
E., Geisse, N. A., Adams, J. C., Whitesides, G. M. and Ingber, D. E., FASEB, 2002, 16, 1195-1204.</td></tr><tr><td>822.</td><td>"Patterning Flows Using Grooved Surfaces", Strook, A. D., Dertinger, S. K., Whitesides, G. M. and
Ajdari, A., Anal. Chem., 2002, 74, 5306-5312.</td></tr><tr><td>821.</td><td>"Dissections: Self-Assembled Aggregates That Spontaneously Reconfigure Their Structures When
Their Environment Changes", Mao, C., Thalladi, V. R., Wolfe, D. B., Whitesides, S. and Whitesides,
G. M., J. Am. Chem. Soc, 2002, 124, 14508-14509.</td></tr><tr><td>820.</td><td>"Fabrication of Two-Dimensional Arrays of Microlenses and Their Applications in
Photolithography", Wu, M.-H. and Whitesides, G. M., J. Mkromech. Microeng., 2002, .12, 747.758.</td></tr><tr><td>819. </td><td>"Using Hierarchical Self-Assembly to Form Three-Dimensional Lattices of Spheres", Wu, H.,</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

Thalladi, V. R., Whitesides, S. and Whitesides, G. M., J. Am. Chem. Soc., 2002, 124, 14495-14502.

<table><tr><th>818.</th><th>"Gradients of Substrate-Bound Laminin Orient Axonal Specification of Neurons", Dertinger, S. K.
W., Jiang, X., Li, Z., Murthy, V. N. and Whitesides, G. M., PIM Nat. Acad. Sul USA, 2002, 99,
12542-12547. </th></tr><tr><td>817.</td><td>"Components for Integrated Poly(dimethylsiloxane) Microfluidic Systems", Ng, J. M. K., Gitlin, I.,
Stroock, A. D. and Whitesides, G. M., Electrophoresis, 2002, 23, 3461-3473.</td></tr><tr><td>816.</td><td>"Fabrication of Diffractive and Micro-optical Elements Using Microlens Projection Lithography",
Wu, M.-H. and Whitesides, G. M., Adv. Mat., 2002, 14, 1502-1506.</td></tr><tr><td>815.</td><td>"Use of Micropatterned Adhesive Surfaces for Control of Cell Behavior", LeDuc, P., Ostuni, E.,
Whitesides, G. M. and Ingber, D. E., in Methods in Cell Biology, E. 3. Adams, Ed., Elsevier Science
(USA), 2002, 385-402.</td></tr><tr><td>814.</td><td>"Organic Materials Science", Whitesides, G. M., Mat. Res. Soc. Bull., 2002, 27, 56-65.</td></tr><tr><td>813.</td><td>"Molecular Rectification in a Metal-Insulator-Metal Junction Based on Self-Assembled Monolayers",
Chabinyc, M. L., Chen, X., Holmlin, R. E., Jacobs, H. O., Skulason, H., Frisbie, C. D., Mujica, V.,
Ratner, M. A., Rampi, M. A. and Whitesides, G. M., J. Am. Chem. Soc., 2002, 124, 11730.11736.</td></tr><tr><td>812.</td><td>"Redox Properties of Cytochrome c Adsorbed on Self-Assembled Monolayers: A Probe for Protein
Conformation and Orientation", Chen, X., Ferrigno, R. and Whitesides, G. M., Langmuir, 2002, 18,
7009.7015. </td></tr><tr><td>811.</td><td>"Generation of Chrome Masks with Micrometer-Scale Features using Microlens Lithography", Wu,
H., Odom, T. W. and Whitesides, G. M., Adv. Mat, 2002, 14, 1213-1216.</td></tr><tr><td>810.</td><td>"Measuring the Inhibition of Adhesion of Lectins to the Surface of Erythrocytes with Optically
Controlled Collisions between Microspheres and Erythrocytes", Qian, X., Holmlin, R. E.,
Whitesides, G. M., Chen, C. Y., Schiavoni, M., Smith, S. P., Assi, F. and Prentiss, M. G., J. Phys.
Chem. B, 2002, 106, 9159-9164.</td></tr><tr><td>809.</td><td>"A Versatile Experimental Approach for Understanding Electron Transport Through Organic
Materials",Rampi, M. A. and Whitesides, G. M., Chem. Phys., 2002, 281, 373-391.</td></tr><tr><td>808.</td><td>"Neutrophil Chemotaxis in Linear and Complex Gradients of Interleukin-8 formed in a
Microfabricated Device", Jeon, N. L., Baskaran, H., Dertinger, S. K. W., Whitesides, G. M., Van de
Water, L. and Toner, M., Nature Biotechnol, 2002, 20, 826-830.</td></tr><tr><td>807.</td><td>"Chemical Force Spectroscopy in Heterogeneous Systems: Intermolecular Interactions Involving
Epoxy Polymer, Mixed Monolayers and Polar Solvents", Vezenov, D. V., Zhuk, A. V., Whitesides, G.
M. and Lieber, C. M., J. Am. Chem. Soc, 2002, 124, 10578-10588.</td></tr><tr><td>806.</td><td>"Generation of 30-50 nm Structures Using Easily Fabricated, Composite PDMS Masks", Odom, T.
W., Thalladi, V. R., Love, J. C. and Whitesides, G. M., J. Am. Chem. Svc, 2002, 124, 12112-12113.</td></tr><tr><td>805.</td><td>"Membraneless Vanadium Redox Fuel Cell Using Laminar Flow", Ferrigno, R., Stroock, A. D.,
Clark, T. D., Mayer, M. and Whitesides, G. M., J. Am. Chem. Soc., 2002, 124, 12930-12931.</td></tr><tr><td>804.</td><td>"Fabrication of Arrays of Microlenses with Controlled Profiles Using Gray-Scale Microlens Projection
Photolithography", Wu, M.-H., Park, C. and Whitesides, G. M., Langmuir, 2002, 18, 9312-9318.</td></tr><tr><td>803.</td><td>"Fabrication and Wetting Properties of Metallic Half-Shells with Sub-Micron Diameters", Love, 3.
C., Gates, B. D., Wolfe, D. B., Paul, K. E. and Whitesides, G. M., Nano Lett., 2002, 2, 891-894.</td></tr><tr><td>802.</td><td>"Simulation of Indentation Fracture in Crystalline Materials Using Mesoscale Self-Assembly",
Thalladi, V. R., Schwartz, A., Phend, J. N., Hutchinson, J. W. and Whitesides, G. M., J. Am. Chem.
Soc., 2002, 124, 9912-9917.</td></tr><tr><td>801. </td><td>"Patterning Flood Illumination Using Microlens Arrays", Wu, M.-H., Paul, K. E. and Whitesides, G.</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

M., App.( Optics, 2002, 41, 2575-2585.

<table><tr><th></th><th></th></tr><tr><td>800.</td><td>"Reduction Photolithography Using Microlens Arrays: Applications in Grayscale Photolithography",
Wu, H., Odom, T. W. and Whitesides, G. M., Anal. Chem., 2002, 74, 3267-3273.</td></tr><tr><td>799.</td><td>"Soft Lithography and Microfluidics", Kane, R., Stroock, A., Jeon, N. L., Ingber, D. E. and
Whitesides, G. M., in Optical Biosensors: Present and Future, E. F. S. Ligler; C. A. R. Taitt, Ed.,
Elsevier Science USA, 2002, 571-595.</td></tr><tr><td>798.</td><td>"Poly(dimethylsiloxane) as a Material for Fabrication of Microfluidic Devices", McDonald, J. C. and
Whitesides, G. M., Act. Chem. Res., 2002, 35, 491-499.</td></tr><tr><td>797.</td><td>"Improved Pattern Transfer in Soft Lithography using Composite Stamps", Odom, T. W., Love, J.
C., Wolfe, D. B., Paul, K. E. and Whitesides, G. M., Langmuir, 2002, 18, 5314-5320.</td></tr><tr><td>796.</td><td>"Glow Discharge in Microfluidic Chips for Visible Analog Computing", Reyes, D. R., Ghanem, M. M.,
Whitesides, G. M. and Manz, A., Lab on a Chip, 2002, 2, 113-116.</td></tr><tr><td>795.</td><td>"Mesoscale Self-Assembly: The Assembly of Micron- and Millimeter-Sized Objects Using Capillary
Forces", Bowden, N., Tien, J., Huck, W. T. S. and Whitesides, G. M., in Supramolecular
Organization and Materials Design, W. Jones and C. N. R. Rao, Eds., Cambridge University Press,
Cambridge, UK, 2002, 103-145.</td></tr><tr><td>794.</td><td>"Connectivity of Features in Microlens Array Reduction Photolithography: Generation of Different
Patterns Using a Single Photomask", Wu, H., Odom, T. W. and Whitesides, G. M., J. Am. Chem.
Soc., 2002, 124, 7288-7289.</td></tr><tr><td>793.</td><td>"Self-Assembly at all Scales", Whitesides, G. M. and Grzybowski, B. A., Science, 2002, 295, 2418-
2421. </td></tr><tr><td>792.</td><td>"Dynamic Aggregation of Chiral Spinners", Grzybowski, B. A. and Whitesides, G. M., Science,
2002, 296, 718-721.</td></tr><tr><td>791.</td><td>"Directed Dynamic Self-Assembly of Objects Rotating on Two Parallel Fluid Interfaces",
Grzybowski, B. A. and Whitesides, G. M., J. Chem. Phys., 2002, 116, 8571-8577.</td></tr><tr><td>790.</td><td>"Beyond Molecules: Self-Assembly of Mesoscopic and Macroscopic Components", Whitesides, G.
M. and Boncheva, M., PIOC. Nat. Acad. Sd. USA, 2002, 99, 4769-4774.</td></tr><tr><td>789.</td><td>"Fabrication of Frequency-Selective Surfaces Using Microlens Photolithography", Wu, M.-H., Paul,
K. E., Yang, 3. and Whitesides, G. M., Appl. Phys. Let, 2002, 80, 3500-3502.</td></tr><tr><td>788.</td><td>"Dynamics of Self-Assembly of Magnetized Disks Rotating at the Liquid-Air Interface", Grzybowski,
B. A., Stone, H. A. and Whitesides, G. M., Proc. Nat. Acad. Sri USA, 2002, 99, 4147-4151.</td></tr><tr><td>787.</td><td>'Template-Directed Self-Assembly of 10-mm-Sized Hexagonal Plates", Clark, T. D., Ferrigno, R.,
Tien, J., Paul, K. E. and Whitesides, G. M., J. Am. Chem. Sac, 2002, 124, 5419-5426.</td></tr><tr><td>786.</td><td>"Biomimetic Self-Assembly of Helical Electrical Circuits Using Orthogonal Capillary Interactions",
Gracias, D., Boncheva, M., Omoregie, 0. and Whitesides, G. M., Appl. Phys. Let, 2002, 80, 2802-
2804. </td></tr><tr><td>785.</td><td>"Fabrication of a Cylindrical Display by Patterned Assembly", Jacobs, H. 0., Tao, A. R., Schwartz,
A., Gracias, D. and Whitesides, G. M., Science, 2002, 296, 323-325.</td></tr><tr><td>784.</td><td>"Autonomous Movement and Self-Assembly", Ismagilov, R. F., Schwartz, A. and Whitesides, G.
M., Angew. Chem. Int. Ed. Eng., 2002, 41, 652-654.</td></tr><tr><td>783.</td><td>"Crystals of Crystals: Fabrication of Encapsulated and Ordered Two-Dimensional Arrays of
Microcrystals", Thalladi, V. R. and Whitesides, G. M., J. Am. ("hem. Soc, 2002, 124, 3520.3521.</td></tr><tr><td>782. </td><td>"Fabrication of Palladium-Based Microelectronic Devices by Microcontact Printing", Wolfe, D. B.,</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

Love, J. C., Paul, K. E., Chabinyc, M. L. and Whitesides, G. M., App/. Phys. Lett, 2002, so,2222- 2224.

<table><tr><th></th><th>2224. </th></tr><tr><td>781.</td><td>"Prototyping of Microfluidic Devices in Poly(dimethylsiloxane) Using Solid-Object Printing",
McDonald, 3. C., Chabinyc, M. L., Metallo, S., Anderson, 3. R., Stroock, A. D. and Whitesides, G.
M., Anal. Chem., 2002, 74, 1537-1545.</td></tr><tr><td>780.</td><td>"Self-Assembled Monolayers of Alkanethiolates on Palladium are Good Etch Resists", Love, J. C.,
Wolfe, D. B., Chabinyc, M. L., Paul, K. E. and Whitesides, G. M., J. Am. Chem. Soc, 2002, 124,
1576-1577. </td></tr><tr><td>779.</td><td>"Controlling Mammalian Cell Spreading and Cytoskeletal Arrangement with Conveniently
Fabricated Continuous Wavy Features on Poly(dimethylsiloxane)", Jiang, X., Takayama, S., Qian,
X., Ostuni, E., Wu, H., Bowden, N., LeDuc, P., Ingber, D. E. and Whitesides, G. M., Langmua;
2002, 18, 3273.3280.</td></tr><tr><td>778.</td><td>"Micropatteming Tractional Forces in Living Cells", Wang, N., Ostuni, E., Whitesides, G. M. and
Ingber, D. E., CellMotil Cytosketeton, 2002, 52, 97-106.</td></tr><tr><td>777.</td><td>"Electroforming of Copper Structures at Nanometer-Sized Gaps of Self-Assembled Monolayers on
Silver", Yang, H., Love, J. C., Arias, F. and Whitesides, G. M., Chem. Mater., 2002, 14, 1385.1390.</td></tr><tr><td>776.</td><td>"Arrays of Self-Assembled Monolayers for Studying Inhibition of Bacterial Adhesion", Qian, X.,
Metallo, S., Choi, I. S., Wu, H., Liang, M. N. and Whitesides, G. M., Anal. Chem., 2002, 74, 1805-
1810. </td></tr><tr><td>775.</td><td>"Design and Fabrication of Integrated Passive Valves and Pumps", Jeon, N. L., Chiu, D. T., Wargo,
C. J., Wu, H., Choi, I. S., Anderson, 3. R. and Whitesides, G. M., Blamed. Microdevices, 2002, 4,
117-121. </td></tr><tr><td>774.</td><td>"Combinatorial Computational Methods Give New Picomolar Ligands for a Known Enzyme",
Grzybowski, B. A., Ishchenko, A. V., Kim, C. Y., Topalov, G., Chapman, R., Christianson, D. W.,
Whitesides, G. M. and Shakhnovich, E. I., Proc. Nat. Acad. Sci. LISA, 2002, 99, 1270-1273.</td></tr><tr><td>773.</td><td>"Chaotic Mixer for Microchannels", Stroock, A. D., Dertinger, S. K. W., Ajdari, A., Mezic, I., Stone,
H. A. and Whitesides, G. M., Science, 2002, 295, 647-654.</td></tr><tr><td>772.</td><td>"Analysis by Capillary Electrophoresis of the Kinetics of Charge Ladder Formation for Bovine
Carbonic Anhydrase", Anderson, 3. R., Cherniaysky, 0., Engel, G. S., Gitlin, I., Yuditsky, L. and
Whitesides, G. M., Anal. Chem., 2002, 74, 1870-1878.</td></tr><tr><td>771.</td><td>"Biomimetic Self-Assembly of a Functional Asymmetrical Electronic Device", Boncheva, M.,
Gracias, D., Jacobs, H. 0. and Whitesides, G. M., Proc. Nat Acad. Sci. USA, 2002, 99, 4937-4940.</td></tr><tr><td>770.</td><td>"Fabrication of Micrometer-Scale, Patterned, Polyhedra by Self-Assembly", Gracias, D. H.,
Kavthekar, V., Love, J. C., Paul, K. E. and Whitesides, G. M., Adv. Mater., 2002, 14, 235-238.</td></tr><tr><td>769.</td><td>"A Prototype 2-D Capillary Electrophoresis System Fabricated in Poly(dimethylsiloxane)", Chen, X.,
Wu, H., Mao, C. and Whitesides, G. M., Anal. Chem., 2002, 74, 1772.1778.</td></tr><tr><td>768.</td><td>"Fabrication of Magnetic Microfiltration Systems Using Soft Lithography", Deng, T., Prentiss, M.
and Whitesides, G. M., Arno'. Phys. Lett, 2002, 80, 461-463.</td></tr><tr><td>767.</td><td>"Fabrication of Three-Dimensional Microfluidic Systems by Soft Lithography", Love, 3. C.,
Anderson, J. R. and Whitesides, G. M., Mat. Res. Soc. Bull., 2001, 26, 523.530.</td></tr><tr><td>766.</td><td>"Three-Dimensional Dynamic Self-Assembly of Spinning Magnetic Disks: Vortex Crystals",
Grzybowski, B. A. and Whitesides, G. M., 1 Phys. Chem. 8, 2001, 106, 1188-1194.</td></tr><tr><td>76S.</td><td>"Fabrication of a Configurable, Single-Use Microfluidic Device", McDonald, J. C., Metallo, S. and
Whitesides, G. M., Anal. Chem., 2001, 73, 5645-5650.</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

<table><tr><th>764.</th><th>"Flexible Methods for Microfluidics", Whitesides, G. M. and Stroock, A. D., Physics Today, 2001,
54, 42-48.</th></tr><tr><td>763.</td><td>"A Structurally Biased Combinatorial Approach for Discovering New Anti-Picornaviral Compounds",
Tsang, S. K., Cheh, 3., Isaacs, L., Joseph-McCarthy, D., Choi, S.-K., Pevear, D. C., Whitesides, G.
M. and Hogle, J. M., Chem. &amp; 8/01., 2001, 8, 33.45.</td></tr><tr><td>762.</td><td>'The Once and Future Nanomachine", Whitesides, G. M., Scent&amp; American, 2001, 285, 70-75.</td></tr><tr><td>761.</td><td>"Design of Three-Dimensional, Millimeter-Scale Models for Molecular Folding", Clark, T. D.,
Boncheva, M., German, J. M., Weck, M. and Whitesides, G. M., J. Am. Chem. Soc., 2001, .124, 18-
19. </td></tr><tr><td>760.</td><td>'The Art of Building Small", Whitesides, G. M. and Love, J. C., Scientific American, 2001, 285, 32-
41. </td></tr><tr><td>759.</td><td>"Topographical Micropatteming of Poly(dimethylsiloxane) using Laminar Flows of Liquids in
Capillaries", Takayama, 5., Ostuni, E., Qian, X., McDonald, J. C., Jiang, X., LeDuc, P., Wu, M. H.,
Ingber, D. E. and Whitesides, G. M., Adv. Mater., 2001, 13, 570-574.</td></tr><tr><td>758.</td><td>"Microfluidic Arrays of Fluid-Fluid Diffusional Contacts as Detection Elements and Combinatorial
Tools", Ismagilov, R. F., Ng, J. M. K., Kenis, P. 3. A. and Whitesides, G. M., Ana/. Chem., 2001, 73,
5207-5213. </td></tr><tr><td>757.</td><td>"Microscope Projection Photolithography for Rapid Prototyping of Masters with Micron-Scale
Features for Use in Soft Lithography", Love, 1 C., Wolfe, D. B., Jacobs, H. 0. and Whitesides, G.
M., Langmuir, 2001, 17, 6005.6012.</td></tr><tr><td>756.</td><td>"Self-Assembled Monolayers That Resist the Adsorption of Proteins and the Adhesion of Bacterial
and Mammalian Cells", Ostuni, E., Chapman, R. G., Liang, M. N., Meluleni, G., Pier, G., Ingber, D.
E. and Whitesides, G. M., Langmtni; 2001, 17, 6336-6343.</td></tr><tr><td>755.</td><td>"An Integrated Fluorescence Detection System in Poly(dimethylsiloxane) for Microfluidic
Applications", Chabinyc, M. L., Chiu, D. T., McDonald, J. C., Stroock, A. D., Christian, .1. F., Karger,
A. M. and Whitesides, G. M., Anal. Chem., 2001, 73, 4491.4498.</td></tr><tr><td>754.</td><td>"Pressure-driven Laminar Flow in Tangential Microchannels: An Elastomeric Microfluidic Switch",
Ismagilov, R. F., Rosmarin, D., Kenis, P. J. A., Chiu, D. T., Zhang, W., Stone, H. A. and
Whitesides, G. M., Anal. Chem., 2001, 73, 4682-4687.</td></tr><tr><td>753.</td><td>"Three-Dimensional Self-Assembly of Complex, Millimeter-Scale Structures Through Capillary
Bonding Structures", Oliver, S. R. J., Clark, T. D., Bowden, N. and Whitesides, G. M., 1 Am.
Chem. Soc., 2001, 23, 8119-8120.</td></tr><tr><td>752.</td><td>"Macroscopic Synthesis of Self-Assembled Dissipative Structures", Grzybowski, B. A. and
Whitesides, G. M., 1 Phys. Chem. B, 2001, 105, 8770-8775.</td></tr><tr><td>751.</td><td>"Competition of Intrinsic and Topographically-Imposed Patterns in BEnard-Maragoni Convection",
Ismagilov, R. F., Rosmarin, D., Gracias, D., Stroock, A. D. and Whitesides, G. M., Appl. Phys.
Lett., 2001, 79, 439-441.</td></tr><tr><td>750.</td><td>"Designing a polyvalent inhibitor of anthrax toxin", Mourez, M., Kane, R. 5., Mogridge, J., Metallo,
S., Deschatelets, P., Sellman, B. R., Whitesides, G. M. and Collier, R. 3., Nature &amp;tech., 2001, 19,
958-961. </td></tr><tr><td>749.</td><td>"A Survey of Structure-Property Relationships of Surfaces that Resist the Adsorption of Proteins",
Ostuni, E., Chapman, R. G., Holmlin, R. E., Takayama, S. and Whitesides, G. M., Langmuii; 2001,
17, 5605-5620.</td></tr><tr><td>748.</td><td>"Correlating Electron Transport and Molecular Structure in Organic Thin Films", Holmlin, R. E.,
Ismagilov, R. F., Haag, R., Mujica, V., Ratner, M. A., Rampi, M. A. and Whitesides, G. M., Angew.
Chem. Int. Ed. Engl., 2001, 40, 2316.2320.</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

<table><tr><th>747.</th><th>"Basicity of the Amino Groups of the Aminoglycoside Amikacin Using Capillary Electrophoresis and
Coupled CE-MS-MS Techniques", Kane, R. S., Glink, P. T., Chapman, R. G., McDonald, J. C.,
Jensen, P. K., Gao, H., Pasa-Tolic, L., Smith, R. D. and Whitesides, G. M., Anal. Chem., 2001, 73,
4028-4036. </th></tr><tr><td>746.</td><td>"Fabrication of Mid-Infrared Frequency-Selective Surfaces (FSS) Using Soft Lithography", Paul, K.
E., Zhu, C., Love, J. C. and Whitesides, G. M., App/. Opt, 2001, 40, 4557-4561.</td></tr><tr><td>745.</td><td>"Soft Lithography in Biology and Biochemistry", Whitesides, G. M., Ostuni, E. S., Takayama, S.,
Jiang, X. and Ingber, D. E., Ann. Rev. Blamed. Eng, 2001, 3, 335-373.</td></tr><tr><td>744.</td><td>"Manipulation of Magnetic Microbeads in Suspension Using Micromagnetic  Systems Fabricated
with Soft Lithography", Deng, T., Whitesides, G. M., Radhakrishna, M., Zabow, G. and Prentiss,
M., App!. Phys. Lett., 2001, 78, 1775.1777.</td></tr><tr><td>743.</td><td>Self-Assembled "Electron Transport through Thin Organic Films in Metal-Insulator-Metal Junctions Based on
Monolayers", Holmlin, R. E., Haag, R., Chabinyc, M. L., Ismagilov, R. F., Cohen, A. E.,
Terfort, A., Rampi, M. A. and Whitesides, G. M., J. Am. Chen. Soc., 2001, 123, 5075-5085.</td></tr><tr><td>742.</td><td>"Laminar flows: Subcellular positioning of small molecules", Takayama, S., Ostuni, E., LeDuc, P.,
Nanise, K., Ingber, D. E. and Whitesides, G. M., Nature, 2001, 411, 1016.</td></tr><tr><td>741.</td><td>"Fabrication of Micro-Chain Mail by Simultaneous, Patterned Electrodeposition on a Plane and
Multiple Cylinders", Wu, H., Whitesides, S. and Whitesides, G. M., Angew. Chem. Int. Ed. Eng.,
2001, 40, 2059-2060.</td></tr><tr><td>740.</td><td>"Meso-Scale Self-Assembly", Gracias, D. H., Choi, I., Wedc, M. and Whitesides, G. M., in New
Directions in Algorithms and Computational Robotics, B. Donald, K. Lynch and D. Rus, Eds., A. K.
Peters, Natick, MA, 2001, 1-7.</td></tr><tr><td>739.</td><td>"Submicrometer Patterning of Charge in Thin-Film Electrets", Jacobs, H. 0. and Whitesides, G. M.,
Science, 2001, 291, 1763-1766.</td></tr><tr><td>738.</td><td>"Zwitterionic SAMs that Resist Nonspecific Adsorption of Protein from Aqueous Buffer", Holmlin, R.
E., Chen, X., Chapman, R. G., Takayama, S. and Whitesides, G. M., Langmuir, 2001, 17, 2841-
2850. </td></tr><tr><td>737.</td><td>"Dynamic, Self-Assembled Aggregates of Magnetized, Millimeter-Sized Objects Rotating at the
Liquid-Air Interface: Macroscopic, Two-Dimensional Classical Artificial Atoms and Molecules",
Grzybowski, B. A., Jiang, X., Stone, H. A. and Whitesides, G. M., Phys. Rev. E, 2001, 64, 011603.</td></tr><tr><td>736.</td><td>"Self-Assembly of Microscale Objects at a Liquid/Liquid Interface through Lateral Capillary Forces",
Bowden, N., Arias, F., Deng, T. and Whitesides, G. M., Langmuir, 2001, 17, 1757-1765.</td></tr><tr><td>735.</td><td>"Selective Deposition of Proteins and Cells in Arrays of Microwells", Ostuni, E., Chen, C. S.,
Ingber, D. E. and Whitesides, G. M., Langmuir, 2001, 17, 2828-2834.</td></tr><tr><td>734.</td><td>"Fabrication of Arrays of Two-Dimensional Micropatterns Using Microspheres as Microlenses for
Projection Lithography", Wu, M. H. and Whitesides, G. M., App!. Phys. Lett., 2001, 78, 2273-2275.</td></tr><tr><td>733.</td><td>"Generation of Gradients Having Complex Shapes Using Microfluidic Networks", Dertinger, S. K.
W., Chiu, D. T., Jeon, N. L. and Whitesides, G. M., Anal. Chem, 2001, 73, 1240.1246.</td></tr><tr><td>732.</td><td>"Self-Assembly of 10-Micron-sized Objects Into Ordered Three-Dimensional Arrays", Clark, T. D.,
Tien, J., Duffy, D. C., Paul, K. and Whitesides, G. M., 2 Am. Chem. Soc., 2001, 123, 7677-7682.</td></tr><tr><td>731.</td><td>"Self-Assembled Monolayer Films: Microcontact Printing", Xia, Y. and Whitesides, G. M., in
Encydopedia of Materials: Science and Technology, A. Ulman, Ed., Elsevier/Pergamon, Oxford,
UK, 2001, 8309-8315.</td></tr><tr><td>730. </td><td>"Fabrication of Nanometer-scale Features by Controlled Isotropic Wet Chemical Etching", Love, J.</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

C., Paul, K. E. and Whitesides, G. M., Adv. Mater., 2001, 13, 604-607.

<table><tr><th>729.</th><th>"Polymeric Thin Films that Resist Adsorption of Proteins and the Adhesion of Bacteria", Chapman,
R. G., Ostuni, E., Liang, M. N., Meluleni, G., Kim, E., Yan, L, Pier, G., Warren, H. S. and
Whitesides, G. M., Langmuk, 2001, 17, 1225-1233.</th></tr><tr><td>728.</td><td>"Modeling Menisci and Capillary Forces from the Millimeter to the Micrometer Size Range",
Grzybowski, B. A., Bowden, N., Arias, F., Yang, H. and Whitesides, G. M., 2 Phys. Chem. 8., 2001,
105, 404-412.</td></tr><tr><td>727.</td><td>"Fabrication of Topologically Complex Three-Dimensional Microstructures: Metallic Microknots",
Wu, H., Brittain, S. T., Anderson, J. R., Grzybowski, B., Whitesides, S. and Whitesides, G. M., J.
Am. Chem. Soc., 2001, 122, 12691-12699.</td></tr><tr><td>726.</td><td>"Fabrication and Characterization of Microscale Sandwich Beams", Arias, F., Kenis, P. 3. A., Xu, B.,
Deng, T., Schueller, O. 3. A., Whitesides, G. M., Sugimura, Y. and Evans, A. G., 2 Mater. Res.,
2001, 16, 597-605.</td></tr><tr><td>725.</td><td>"Fabrication of High Performance Ceramic Microstructures from a Polymeric Precursor using Soft
Lithography", Yang, H., Deschatelets, P., Brittain, S. T. and Whitesides, G. M., Adv. Mat, 2001,
13,54-58. </td></tr><tr><td>724.</td><td>"Using Three-Dimensional Microfluidic Networks for Solving Computationally Hard Problems",
Chiu, D. T., Pezzoli, E., Wu, H., Stroock, A. and Whitesides, G. M., Arc. Nat. Acad. Sci. USA,
2001, 98, 2961.2966.</td></tr><tr><td>723.</td><td>"Molecule-Mimetic Chemistry and Mesoscale Self-Assembly", Bowden, N. B., Weck, M., Choi, I. S.
and Whitesides, G. M., Acc. diem. Res, 2001, 34, 231-238.</td></tr><tr><td>722.</td><td>"Fabrication of Metallic Heat Exchangers Using Sacrificial Polymer Mandrils", Arias, F., Oliver, S. R.
3., Xu, B., Holmlin, R. E. and Whitesides, G. M., J. MEMS, 2001, 10, 107-112.</td></tr><tr><td>721.</td><td>"Development of a Knowledge-Based Potential for Crystals of Small Organic Molecules: Calculation
of Energy Surfaces for C=O...H-N Hydrogen Bonds.", 8. A., Ishchenko, A. V., DeWitte, R. 5.,
Whitesides, G. M. and Shakhnovich, E. I., J. Phys. Chem. A  2001, 104, 7293.7298.</td></tr><tr><td>720.</td><td>"Fabrication and Mechanical Performance of a Mesoscale, Space-Filling Truss System", Brittain, S.
T., Sugimura, Y., Schueller, O. 3. A., Evans, A. G. and Whitesides, G. M., J. HEMS, 2001, 10, 113-
120. </td></tr><tr><td>719.</td><td>"Printing, Molding, and Near-Field Photolithographic Methods for Patterning Organic Lasers, Smart
Pixels and Simple Circuits", Rogers, 3. A., Bao, Z., Meier, M., Dodabalapur, A., Schueller, O. J. A.
and Whitesides, G. M., Synthetic Metals, 2000, 115, 5.11.</td></tr><tr><td>718.</td><td>"Measuring the Forces Involved in Polyvalent Adhesion of Uropathogenic Escherichia coli to
Mannose-Presenting Surfaces", Liang, M. N., Smith, S. P., Metallo, S., Choi, I. S., Prentiss, M. and
Whitesides, G. M., Proc. Nat. Acad. Sul USA, 2000, 97 13092-13096.</td></tr><tr><td>717.</td><td>"Elastomeric Optical Elements with Deformable Surface Topologies: Applications to Force
Measurements, Tunable Light Transmission and Light Focusing", Grzybowski, B., Qin, D., Haag, R.
and Whitesides, G. M., Sensors andActuatorsA: Physical, 2000, 86, 81.85.</td></tr><tr><td>716.</td><td>"Light-Driven Microfabrication: Assembly of Multicomponent, 3D Structures Using Optical
Tweezers", Holmlin, R. E., Schiavonni, M., Chen, C. Y., Smith, S. P., Prentiss, M. G. and
Whitesides, G. M., Angew. Chem. Int Ed. Eng., 2000, 39, 3503-3506.</td></tr><tr><td>715.</td><td>"Patterned Deposition of Cells and Proteins onto Surfaces by Using Three-Dimensional Microfluidic
Systems", Chiu, D. T., Min, N. L., Huang, S., Kane, R., Wargo, C. J., Choi, I. S., Ingber, D. E. and
Whitesides, G. M., Proc. Nat Acad. Sci. USA, 2000, 97, 2408-2413.</td></tr><tr><td>714.</td><td>"Dynamic Self-Assembly of Magnetized, Millimeter-Sized Objects Rotating at the Liquid-Air
Interface", Grzybowski, B., Stone, H. A. and Whitesides, G. M., Nature, 2000, 405, 1033-1036.</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

<table><tr><th>713.</th><th>"Microorigami: Fabrication of Small, Three-Dimensional, Metallic Structures", Brittain, S. T.,
Schueller, 0. 3. A., Wu, H., Whitesides, S. and Whitesides, G. M., J. Phys. Chem. 8., 2000, 105,
347-350. </th></tr><tr><td>712.</td><td>"Mesoscale Folding: A Physical Realization of an Abstract, 2D Lattice Model for Molecular Folding",
Choi, I. S., Wed, M., Jeon, N. L. and Whitesides, G. M., 2 Am Chem. Soc., 2000, 122, 11997-
11998. </td></tr><tr><td>711.</td><td>"Preparation of Mixed SAMs that Resist Adsorption of Proteins Using the Reaction of Amines with
a SAM that Presents Interchain Carboxylic Anhydride Groups", Chapman, R. G., Ostuni, E., Yan, L.
and Whitesides, G. M., Langmuir; 2000, 16, 6927-6936.</td></tr><tr><td>710.</td><td>"Mirrorless Lasing from Mesostructured Waveguides Patterned by Solt Lithography", Yang, P.,
Wirnsberger, G., Huang, H., Cordero, S. R., McGehee, M. D., Scott, B., Deng, T., Whitesides, G.
M., Chmelka, B. F., Buratto, S. K. and Stucky, G. D., Science, 2000, 287, 465-467.</td></tr><tr><td>709.</td><td>"Assembly of Mesoscopic Analogs of Nucleic Acids", Wedc, M., Choi, I. S., Jeon, N. L. and
Whitesides, G. M., J. Am. Chem. Soc., 2000, 122, 3546.3547.</td></tr><tr><td>708.</td><td>"Prototyping of Masks, Masters, and Stamps/Molds for Soft Lithography Using an Office Printer
and Photographic Reduction", Deng, T., Wu, H., Brittain, S. T. and Whitesides, G. M., Anal.
Chem., 2000, 72, 3176-3180.</td></tr><tr><td>707.</td><td>"Fabrication of Topologically Complex Three-Dimensional Microfluidic Systems in PDMS by Rapid
Prototyping", Anderson, 3. R., Chiu, D. T., Jackman, R. J., Cherniayskaya, 0., McDonald, J. C.,
Wu, H., Whitesides, S. H. and Whitesides, G. M., Anal. Chem., 2000, 72, 3158.3164.</td></tr><tr><td>706.</td><td>"Mesoscopic, Templated Self-Assembly at the Fluid-Fluid Interface", Choi, I. S., Weck, M., Xu, B.,
Jeon, N. L. and Whitesides, G. M., Langmuir, 2000, 16, 2997-2999.</td></tr><tr><td>705.</td><td>"Patterning Electroosmotic Flow with Patterned Surface Charge", Stroock, A. D., Weck, M., Chiu,
D. T., Huck, W. T. S., Kenis, P. 3. A., Ismagilov, R. F. and Whitesides, G. M., Phys. Rev. Lett.,
2000, 84, 3314-3317; Erratum in Phys. Rev. Left, 2001, 86, 6050.</td></tr><tr><td>704.</td><td>"Use of Microcontact Printing for Generating Selectively Grown Films of Poly(p-Phenylene
Vinylene) and Parylenes Prepared by Chemical Vapor Deposition", Vaeth, K. M., Jackman, R. 3.,
Black, A. J., Whitesides, G. M. and Jensen, K. F., Langmuit; 2000, 16, 8495-8500.</td></tr><tr><td>703.</td><td>"Experimental and Theoretical Scaling Laws for Transverse Diffusive Broadening in Two-Phase
Laminar Flows in Microchannels", Ismagilov, R. F., Stroock, A. D., Kenis, P. 3. A., Stone, H. A. and
Whitesides, G. M., Axil Phys. Lett, 2000, 76, 2376-2378.</td></tr><tr><td>702.</td><td>"Fabrication of Metallic Microstructures Using Exposed, Developed Silver Halide-Based
Photographic Film", Deng, T., Arias, F., Ismagilov, R. F., Kenis, P. 3. A. and Whitesides, G. M.,
Anal. Chem., 2000, 72, 645-651.</td></tr><tr><td>701.</td><td>"Ordering of Spontaneously Formed Buckles on Planar Surfaces", Huck, W. T. S., Bowden, N.,
Onck, P., Pardoen, T., Hutchinson, 3. W. and Whitesides, G. M., Langmuir, 2000, 16, 3497-3501.</td></tr><tr><td>700.</td><td>"Mesoscale Self-Assembly: Capillary Bonds and Negative Menisci", Bowden, N., Oliver, S. and
Whitesides, G. M., 1 Phys. Chem., 2000, 104, 2714-2724.</td></tr><tr><td>699.</td><td>"Generation of Solution and Surface Gradients Using Micro0uidic Systems", Jeon, N. L., Dertinger,
S. K. W., Chiu, D. T., Choi, I. S., Stroock, A. D. and Whitesides, G. M., Langmuir, 2000, 16, 8311-
8316. </td></tr><tr><td>698.</td><td>"Forming Electrical Networks in Three Dimensions by Self-Assembly", Gracias, D. H., Tien, J.,
Breen, T. L., Hsu, C. and Whitesides, G. M., Science, 2000, 289, 1170-1172.</td></tr><tr><td>697.</td><td>"Fabrication Inside Microchannels using Fluid Flow", Kenis, P. J. A., Ismagilov, R. F., Takayama,
S., Whitesides, G. M., U, S. and White, H. S., Act. Chem. Res., 2000, 33, 841-847.</td></tr></table>

# Publications (cont.)

## Publications 2000-Present (cont.)

<table><tr><th>696.</th><th>"Patterning Mammalian Cells Using Elastomeric Membranes", Ostuni, E., Kane, R., Chen, C. S.,
Ingber, D. E. and Whitesides, G. M., Langmuir, 2000, 16, 7811-7819.</th></tr><tr><td>695.</td><td>"Synthesis of Geometrically Well-Defined, Molecularly-Thin, Polymer Films", Huck, W. T. S.,
Stroock, A. and Whitesides, G. M., Angew. Chem. Int Ed. Engl., 2000, 39, 1058.1061.</td></tr><tr><td>694.</td><td>"Surveying for Surfaces that Resist the Adsorption of Proteins", Chapman, R. G., Ostuni, E.,
Takayama, S., Holmlin, R. E., Yan, L. and Whitesides, G. M., 1 Am. Chem. Soc., 2000, 122, 8303-
8304. </td></tr><tr><td>693.</td><td>"Self-Assembled Monolayers (SAMs) and Synthesis of Planar Micro- and Nanostructures", Yan, L.,
Huck, W. T. S. and Whitesides, G. M., in Supramolecular Polymers, A. Ciferri, Ed., MarcelDekker,
New York, 2000, 435-470.</td></tr><tr><td>692.</td><td>"Design, Synthesis, and Characterization of a High-Affinity Trivalent System Derived from
Vancomycin and L-Lys-D-Ala-D-Ala.", J., Lahiri, J., Weis, R. M. and Whitesides, G. M., J. Am.
Chem. Soc., 2000, 122, 2698-2710.</td></tr><tr><td>691.</td><td>"Fabrication of Microfluidic Systems in Poly(dimethylsiloxane)", McDonald, J. C., Duffy, D. C.,
Anderson, J. R., Chiu, D. T., Wu, H. and Whitesides, G. M., E/ectrophoresis, 2000, 21, 27-40.</td></tr><tr><td>690.</td><td>"Fabrication of GaAs/AIGaAs High Electron Mobility Transistors with 250 nm Gates Using
Conformal Phase Shift Lithography", Hu, J., Deng, T., Beck, R. G., Westervelt, R. M., Maranowski,
K. D., Gossard, A. C. and Whitesides, G. M., Sensors and Actuators A: Physical, 2000, 86, 122-
126. </td></tr><tr><td>689.</td><td>"Microfabrication of Two Layer Structures of Electrically Isolated Wires Using Self-Assembly to
Guide the Depostion of Insulating Organic Polymer", Black, A. J., Nealey, P. F., Thywissen, J. H.,
Deshpande, M., El-Zein, N., Maracas, G. N., Prentiss, M. and Whitesides, G. M., Sensors ant
ActuatorsA: Physical, 2000, 86, 96-102.</td></tr><tr><td>688.</td><td>"Self-Assembly of Hexagonal Rods Based on Capillary Forces", Oliver, S. R. J., Bowden, N. and
Whitesides, G. M., J. Coll. Int Sd., 2000, 224, 425-428.</td></tr><tr><td>687.</td><td>"Patterning of Cells and Their Environment", Takayama, S., Chapman, R. G., Kane, R. and
Whitesides, G. M., in Principles of Tissue Engineering, 2nd Ed., R. Lanza, Ed., Academic Press,
San Diego, 2000, 209-220.</td></tr><tr><td>686.</td><td>"Modeling the Kinetics of Acylation of Insulin using a Recursive Method for Solving Systems of
Coupled Differential Equations", Grzybowski, B. A., Anderson, 3. R., Colton, I., Brittain, S. T.,
Shakhnovich, E. I. and Whitesides, G. M., 8iophys. 1, 2000, 78, 652-661.</td></tr><tr><td>685.</td><td>"Surface-Initiated Ring-Opening Metathesis Polymerization on Si/SiO2", Kim, N. Y., Jeon, N. L.,
Choi, I., Takami, S., Harada, Y., Finnie, K. R., Girolami, G. S., Nuzzo, R. G., Whitesides, G. M. and
Laibinis, P., Macromolecules, 2000, 33, 2793-2795.</td></tr></table>